PROCESS FOR OPERATING A UTILITY BOILER AND METHODS THEREFOR

• US 20130040250A1
• Filed: 10/10/2012
• Published: 02/14/2013
• Est. Priority Date: 04/28/2010
• Status: Abandoned Application

• Current Assignee: Environmental Energy Services, Inc.
• Original Assignee: Environmental Energy Services, Inc.
• Inventors: Wolferseder, Thomas J.
• Application Number:
  US13/648,606
• Publication Number:
  US 20130040250A1
• Time in Patent Office: Days
• US Class Current: 431/4
• CPC Class Codes: C10L 1/10 containing additives
• CPC Class Codes: C10L 1/1216 metal compounds, e.g. hydrides, carbides
• CPC Class Codes: C10L 1/1225 halogen containing compounds
• CPC Class Codes: C10L 1/1233 oxygen containing compounds, e.g. oxides, hydroxides, acids and salts thereof
• CPC Class Codes: C10L 1/1275 sulfur, tellurium, selenium containing compounds
• CPC Class Codes: C10L 1/1291 Silicon and boron containing compounds
• CPC Class Codes: C10L 1/1881 carboxylic group attached to an aliphatic carbon atom
• CPC Class Codes: C10L 1/1886 naphthenic acid
• CPC Class Codes: C10L 1/189 having at least one carboxyl group bound to an aromatic carbon atom C10L1/1802, C10L1/1805, C10L1/1808, C10L1/1811, C10L1/1814, C10L1/1817, C10L1/1885, C10L1/1886, C10L1/1888 take precedence
• CPC Class Codes: C10L 1/2437 Sulfonic acids; Derivatives thereof, e.g. sulfonamides, sulfosuccinic acid esters
• CPC Class Codes: C10L 1/30 compounds not mentioned before (complexes)
• CPC Class Codes: C10L 10/00 Use of additives to fuels or fires for particular purposes additives for liquid carbonaceous fuels characterised by their chemical nature C10L1/10; using binders for briquetting solid fuels C10L5/10; using additives to improve the combustion of solid fuels C10L9/10
• CPC Class Codes: C10L 10/02 for reducing smoke development
• CPC Class Codes: C10L 10/04 for minimising corrosion or incrustation
• CPC Class Codes: C10L 2200/0209 Group I metals: Li, Na, K, Rb, Cs, Fr, Cu, Ag, Au
• CPC Class Codes: C10L 2200/0213 Group II metals: Be, Mg, Ca, Sr, Ba, Ra, Zn, Cd, Hg
• CPC Class Codes: C10L 2200/024 Group VIII metals: Fe, Co, Ni, Ru, Rh, Pd, Os, Ir, Pt
• CPC Class Codes: C10L 2290/58 Control or regulation of the fuel preparation of upgrading process
• CPC Class Codes: C10L 2290/60 Measuring or analysing fractions, components or impurities or process conditions during preparation or upgrading of a fuel
• CPC Class Codes: F23J 7/00 Arrangement of devices for supplying chemicals to fire
• CPC Class Codes: F23N 1/082 : using electronic means
• CPC Class Codes: F23N 2221/10 : Analysing fuel properties, e.g. density, calorific
• CPC Class Codes: F23N 5/00 : Systems for controlling combustion regulating fuel supply F23N1/00, regulating air supply or draught F23N3/00

Abstract

A process for operating a utility boiler. The process has the following steps: (a) providing fuel to the boiler; (b) providing one or more additives selected from the group consisting of (i) one or more slag control agents, (ii) one or more oxygen-generating agents, (iii) one or more acid mitigation agents, (iv) one or more fouling prevention agents, (v) one or more oxidizer agents, (vi) one or more heavy metal capturing agents, and (vii) any combination of the foregoing to the boiler or an auxiliary device thereof; (c) providing air to the boiler; (d) burning the fuel in the boiler to generate heat and an exhaust gas; (e) intermittently or continuously monitoring one or more physical and/or chemical parameters of the fuel and/or intermittently or continuously monitoring one or more emissions variables of the exhaust gas to obtain one or more values therefor; and (f) varying or maintaining the rate at which either or both of the fuel and the one or more additives are provided to the boiler based on the one or more values obtained.

Claims

1. A process for operating a utility boiler, comprising:

a) providing fuel to the boiler;

b) providing one or more additives selected from the group consisting of (i) one or more slag control agents, (ii) one or more oxygen-generating agents, (iii) one or more acid reduction agents, (iv) one or more fouling prevention agents, (v) one or more oxidizer agents, (vi) one or more heavy metal capturing agents and (vii) any combination of the foregoing to the boiler or an auxiliary device thereof;

c) providing air to the boiler;

d) burning the fuel in the boiler to generate heat and an exhaust gas and/or a flue gas; and

e) intermittently or continuously monitoring one or more physical and/or chemical parameters of the fuel and/or intermittently or continuously monitoring one or more emissions variables of the exhaust gas and/or a flue gas to obtain one or more values; and

f) varying or maintaining the rate at which the one or more additives is provided to the boiler or an auxiliary device based on the one or more values obtained.

2. The process of claim 1, wherein the one or more values are communicated in real time to a controller, and wherein the controller provides instructions based on the one or more values in real time to one or more components of the process to vary the rate at which either or both of the fuel and the one or more additives is provided to the boiler and/or its auxiliary devices.

4. The process of claim 1, wherein the one or more additives is one or more slag control agents selected from the group consisting of magnesium hydroxide, magnesium oxide, magnesium carbonate, magnesium organometallic compounds, magnesium carboxylate, magnesium salicylate, magnesium napthenate, and magnesium sulfonate.

5. The process of claim 1, wherein the one or more additives is one or more oxygen-generating agents selected from the group consisting of calcium hydroxide, calcium oxide, calcium carbonate, calcium carboxylate, calcium organometallic compounds, calcium sulfonate, iron hydroxides, iron oxides, iron carbonates, iron carboxylates, iron organometallic compounds, iron sulfonates, barium hydroxide, barium oxide, barium carbonate, barium carboxylate, barium organometallic compounds, and barium sulfonate.

6. The process of claim 1, wherein the one or more additives is added to the fuel to form a treated fuel, and wherein the treated fuel is then provided to the boiler.

7. The process of claim 1, wherein the one or more additives is provided directly to the boiler.

8. The process of claim 1, wherein the fuel is coal

9. The process of claim 1, wherein the fuel is fuel oil.

10. The process of claim 1, wherein the fuel is biomass.

11. The process of claim 2, wherein the one or more components is selected from the group consisting of a flow limiting/controlling device, a pump, a fan, or a belt speeds.

12. The process of claim 1, wherein the physical and/or chemical parameters of the fuel are monitored by a technique selected from the group consisting of one or more of prompt gamma neutron activation analysis, nuclear magnetic resonance spectroscopy, laser induced breakdown spectroscopy, mass spectroscopy;

inductively couple plasma;

microwave analyzer for moisture readings;

atomic absorption;

optical emission spectroscopy;

X-ray diffraction;

X-ray fluorescence; and

pulsed fast and thermal neutron analysis.

13. The process of claim 1, wherein the physical and/or chemical parameters of the fuel is selected from the group consisting of one or more of calorific value;

volatile matter;

ash;

moisture;

carbon/free carbon;

hydrogen;

sulfur;

sulfur dioxide;

sulfur trioxide;

sulfate compounds;

nitrogen;

oxygen (by difference);

reducing and oxidizer ash fusion temperatures; and

one or more oxides of any of silica, alumina, iron, calcium, magnesium, potassium, sodium, zinc, copper, titanium, chlorine, bromine, arsenic, mercury, cobalt, nickel, chromium, lead, and cadmium.

14. The process of claim 1, wherein further in step (e) the exhaust gas and/or a flue gas is intermittently or continuously monitored with respect to one or more emissions variables to obtain one or more additional values, wherein varying or maintaining the rate at which either or both of the fuel and the one or more additives is provided to the boiler based on the one or more additional values obtained, and wherein the one or more emissions variables is maintained within pre-determined limits.

15. The process of claim 1, wherein in step (e) the one or more physical and/or chemical parameters of the fuel is intermittently monitored.

17. The process of claim 1, wherein the physical and/or chemical parameters of the fuel is selected from the group consisting of ash;

sulfur; and

one or more oxides of any of silica, alumina, iron, calcium, magnesium, potassium, sodium, copper, titanium, chlorine, bromine, arsenic, and mercury.

18. The process of claim 1, wherein the one or more additives are provided to the boiler.

19. The process of claim 1, wherein the rate at which the one or more additives is provided to the boiler is varied or maintained based on the one or more values obtained.

3. The process of claim 3, wherein the one or more emissions variables in the exhaust gas are selected from the group consisting of opacity, particulates, NO_x, SO₂, SO₃, acid level, and Hg.

16. The process of claim 16, wherein in step (e) the one or more physical and/or chemical parameters of the fuel is intermittently monitored at a period of time elapse of five minutes or less between the end of a test and repeat of the test.