POLYCRYSTALLINE DIAMOND COMPACT INCLUDING A CARBONATE-CATALYZED POLYCRYSTALLINE DIAMOND TABLE AND APPLICATIONS THEREFOR

• US 20130043078A1
• Filed: 07/18/2012
• Published: 02/21/2013
• Est. Priority Date: 07/20/2011
• Status: Active Grant

• Current Assignee: US Synthetic Corporation (ChampionX Corporation)
• Original Assignee: US Synthetic Corporation (ChampionX Corporation)
• Inventors: Qian, Jiang, Mukhopadhyay, Debkumar, Wiggins, Jason K., Vail, Michael A., Bertagnolli, Kenneth E., McMurray, C. Eugene
• Granted Patent: US 9,273,381 B2
• Time in Patent Office: Days
• US Class Current: 175/428
• CPC Class Codes: B01J 3/06 Processes using ultra-high pressure, e.g. for the formation of diamonds; Apparatus therefor, e.g. moulds or dies B01J3/04 takes precedence
• CPC Class Codes: B22F 2005/001 Cutting tools, earth boring or grinding tool other than table ware
• CPC Class Codes: B22F 7/062 involving the connection or repairing of preformed parts
• CPC Class Codes: B24D 18/0009 using moulds or presses
• CPC Class Codes: B24D 3/10 for porous or cellular structure, e.g. for use with diamonds as abrasives
• CPC Class Codes: C22C 26/00 Alloys containing diamond or cubic or wurtzitic boron nitride, fullerenes or carbon nanotubes
• CPC Class Codes: E21B 10/54 the bit being of the rotary drag type, e.g. fork-type bits
• CPC Class Codes: E21B 10/56 Button-type inserts E21B10/52 takes precedence
• CPC Class Codes: E21B 10/567 with preformed cutting elements mounted on a distinct support, e.g. polycrystalline inserts
• CPC Class Codes: F16C 17/02 for radial load only
• CPC Class Codes: F16C 17/04 for axial load only
• CPC Class Codes: F16C 2352/00 Apparatus for drilling in general E21
• CPC Class Codes: F16C 33/043 Sliding surface consisting mainly of ceramics, cermets or hard carbon, e.g. diamond like carbon [DLC]
• CPC Class Codes: F16C 33/108 with a plurality of elements forming the bearing surfaces, e.g. bearing pads
• CPC Class Codes: F16C 33/26 made from wire coils; made from a number of discs, rings, rods, or other members
• CPC Class Codes: Y10T 408/89 Tool or Tool with support

Abstract

In an embodiment, a polycrystalline diamond compact includes a substrate and a preformed polycrystalline diamond table bonded to the substrate. The table includes bonded diamond grains defining interstitial regions. The table includes an upper surface, a back surface bonded to the substrate, and at least one lateral surface extending therebetween. The table includes a first region extending inwardly from the upper surface and the lateral surface. The first region exhibits a first interstitial region concentration and includes at least one interstitial constituent disposed therein, which may be present in at least a residual amount and includes at least one metal carbonate and/or at least one metal oxide. The table includes a second bonding region adjacent to the substrate that extends inwardly from the back surface. The second bonding region exhibits a second interstitial region concentration that is greater than the first interstitial region concentration and includes a metallic infiltrant therein.

Claims

1. A polycrystalline diamond compact, comprising:

a substrate; and

a preformed polycrystalline diamond table bonded to the substrate, the preformed polycrystalline diamond table including bonded diamond grains defining a plurality of interstitial regions, the preformed polycrystalline diamond table further including;

an upper surface;

a back surface bonded to the substrate;

at least one lateral surface extending between the upper surface and the back surface;

a first region extending inwardly from the upper surface and the at least one lateral surface, the first region exhibiting a first interstitial region concentration and including at least one interstitial constituent disposed in at least a portion of the interstitial regions thereof, the at least one interstitial constituent present in at least a residual amount, the at least one interstitial constituent including at least one metal carbonate and/or at least one metal oxide; and

a second bonding region adjacent to the substrate and extending inwardly from the back surface, the second bonding region exhibiting a second interstitial region concentration that is greater than the first interstitial region concentration and including a metallic infiltrant therein disposed in at least a portion of the interstitial regions thereof.

2. The polycrystalline diamond compact of claim 1 wherein the at least one interstitial constituent is present at the upper surface of the preformed polycrystalline diamond table in an amount of greater than 0 weight % to about 5 weight %.

3. The polycrystalline diamond compact of claim 2 wherein the amount is about 1 weight % to about 3 weight %.

4. The polycrystalline diamond compact of claim 2 wherein the amount is about 1.5 weight % to about 2.5 weight %.

5. The polycrystalline diamond compact of claim 2 wherein the amount is a residual amount.

6. The polycrystalline diamond compact of claim 1 wherein the at least one interstitial constituent is present at the back surface of the preformed polycrystalline diamond table in an amount of greater than 0 weight % to about 1.5 weight %.

7. The polycrystalline diamond compact of claim 6 wherein the amount is about 0.6 weight % to about 1.0 weight %.

8. The polycrystalline diamond compact of claim 6 wherein the amount is about 0.5 weight % to about 0.8 weight %.

9. The polycrystalline diamond compact of claim 6 wherein the amount is a residual amount.

10. The polycrystalline diamond compact of claim 1 wherein the second interstitial region concentration is about 1.2 to about 1.5 times the first interstitial region concentration.

11. The polycrystalline diamond compact of claim 1 wherein the second interstitial region concentration is about 2 to about 4 times the first interstitial region concentration.

12. The polycrystalline diamond compact of claim 1 wherein the preformed polycrystalline diamond table exhibits a gradient of interstitial region concentration, which increases from the first region toward the second bonding region.

13. The polycrystalline diamond compact of claim 1 wherein the metallic infiltrant present in the second bonding region comprises a braze alloy.

14. The polycrystalline diamond compact of claim 13 wherein the braze alloy comprises an active braze alloy.

15. The polycrystalline diamond compact of claim 1 wherein the metallic infiltrant comprises cobalt, and wherein the metallic infiltrant is included in and provided from the substrate.

16. The polycrystalline diamond compact of claim 1 wherein the at least one metal carbonate comprises one or more alkali metal carbonates, one or more alkaline earth metal carbonates, or combinations thereof;

and wherein the at least one metal oxide comprises one or more alkali metal oxides, one or more alkaline earth metal oxides, or combinations thereof.

17. A method of manufacturing a polycrystalline diamond compact, comprising:

assembling a polycrystalline diamond table with a substrate;

wherein the polycrystalline diamond table including a plurality of bonded diamond grains defining a plurality of interstitial regions;

wherein the polycrystalline diamond table includes an upper surface, a back surface, and at least one lateral surface extending between the upper surface and the back surface,;

wherein the polycrystalline diamond table further includes;

a first region extending inwardly from the upper surface and the at least one lateral surface, the first region including at least one interstitial constituent disposed in at least a portion of the interstitial regions thereof, the at least one interstitial constituent present in at least a residual amount, the at least one interstitial constituent including at least one metal carbonate and/or at least one metal oxide; and

a second bonding region adjacent to the substrate and extending inwardly from the back surface, the second bonding region exhibiting an interstitial region concentration that is greater than the first region;

infiltrating at least a portion of the interstitial regions of the second bonding region of the polycrystalline diamond table with a metallic infiltrant effective to bond the polycrystalline diamond table to the substrate.

18. The method of claim 17 wherein the at least one metal carbonate comprises one or more alkali metal carbonates, one or more alkaline earth metal carbonates, or combinations thereof;

and wherein the at least one metal oxide comprises one or more alkali metal oxides, one or more alkaline earth metal oxides, or combinations thereof.

19. The method of claim 17 wherein the at least one interstitial constituent is present at the upper surface of the preformed polycrystalline diamond table in an amount of greater than 0 to about 5 weight %.

20. The method of claim 19 wherein the amount is about 1 weight % to about 3 weight %.

21. The method of claim 19 wherein the amount is about 1.5 weight % to about 2.5 weight %.

22. The method of claim 19 wherein the amount is a residual amount.

23. The method of claim 17 wherein the at least one interstitial constituent is present at the back surface of the preformed polycrystalline diamond table in an amount of greater than 0 to about 1.5 weight %.

24. The method of claim 23 wherein the amount is about 0.6 weight % to about 1.0 weight %.

25. The method of claim 24 wherein the amount is about 0.5 weight % to about 0.8 weight %.

26. The method of claim 23 wherein the amount is a residual amount.

27. The method of claim 17 wherein the interstitial region porosity concentration of the bonding region is about 1.2 to about 1.5 times that of an interstitial region porosity concentration of the first region.

28. The method of claim 17 wherein the interstitial region porosity concentration of the bonding region is about 2 to about 4 times that of an interstitial region porosity concentration of the first region.

29. The method of claim 17 wherein the metallic infiltrant comprises a braze alloy.

30. The method of claim 17 wherein the substrate comprises the metallic infiltrant.

31. The method of claim 17 wherein the polycrystalline diamond table is fabricated by:

disposing at least one carbonate catalyst material between first and second regions each of which includes a plurality of diamond particles to thereby forming an assembly; and

subjecting the assembly to high temperature/high pressure processing effective to infiltrate the first and second regions and form first and second polycrystalline diamond tables that are bonded together.

32. The method of claim 17, prior to the act of infiltrating, further comprising heat treating the polycrystalline diamond table to at least partially convert at least some of the at least one metal carbonate to the at least one metal oxide.

33. A rotary drill bit, comprising:

a bit body configured to engage a subterranean formation; and

a plurality of polycrystalline diamond cutting elements affixed to the bit body, at least one of the polycrystalline diamond cutting elements including;

a substrate; and

a preformed polycrystalline diamond table bonded to the substrate, the preformed polycrystalline diamond table including bonded diamond grains defining a plurality of interstitial regions, the preformed polycrystalline diamond table further including;

an upper surface;

a back surface bonded to the substrate;

at least one lateral surface extending between the upper surface and the back surface;

a first region extending inwardly from the upper surface and the at least one lateral surface, the first region exhibiting a first interstitial region concentration and including at least one interstitial constituent disposed in at least a portion of the interstitial regions thereof, the at least one interstitial constituent present in at least a residual amount, the at least one interstitial constituent including at least one metal carbonate and/or at least one metal oxide; and

a second bonding region adjacent to the substrate and extending inwardly from the back surface, the second bonding region exhibiting a second interstitial region concentration that is greater than the first interstitial region concentration and including a metallic infiltrant therein disposed in at least a portion of the interstitial regions thereof.