COMPLEXES OF HERBICIDAL CARBOXYLIC ACIDS AND AMINE-CONTAINING POLYMERS OR OLIGOMERS

• US 20130045869A1
• Filed: 08/15/2012
• Published: 02/21/2013
• Est. Priority Date: 08/16/2011
• Status: Abandoned Application

• Current Assignee: Corteva Agriscience LLC (Corteva, Inc.)
• Original Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Inventors: Liu, Lei, Zhang, Hong, Tank, Holger, Ouse, David G., Gifford, James M., Zhao, Min, Kennedy, Alex
• Application Number:
  US13/586,144
• Publication Number:
  US 20130045869A1
• Time in Patent Office: Days
• US Class Current: 504/255
• CPC Class Codes: A01N 2300/00 Combinations or mixtures of active ingredients covered by classes A01N27/00 - A01N65/48 with other active or formulation relevant ingredients, e.g. specific carrier materials or surfactants, covered by classes A01N25/00 - A01N65/48
• CPC Class Codes: A01N 25/02 containing liquids as carriers, diluents or solvents
• CPC Class Codes: A01N 25/04 Dispersions, emulsions, suspoemulsions, suspension concentrates or gels foams A01N25/16
• CPC Class Codes: A01N 25/24 containing ingredients to enhance the sticking of the active ingredients
• CPC Class Codes: A01N 25/32 Ingredients for reducing the noxious effect of the active substances to organisms other than pests, e.g. toxicity reducing compositions, self-destructing compositions
• CPC Class Codes: A01N 39/02 Aryloxy-carboxylic acids; Derivatives thereof
• CPC Class Codes: A01N 39/04 Aryloxy-acetic acids; Derivatives thereof
• CPC Class Codes: A01N 43/40 six-membered rings
• CPC Class Codes: C07C 211/14 Amines containing amino groups bound to at least two aminoalkyl groups, e.g. diethylenetriamines
• CPC Class Codes: C07D 213/64 attached in position 2 or 6
• CPC Class Codes: C07D 213/73 Unsubstituted amino or imino radicals

Abstract

Complexes of herbicidal carboxylic acids and amine-containing polymers or oligomers are provided. These herbicidal complexes are useful for controlling unwanted plant growth. The herbicidal complexes have low solubility in water, low volatility relative to commercial compositions of the corresponding herbicidal carboxylic acids, and offer similar or improved herbicidal performance when compared to existing salts of the herbicidal carboxylic acids.

Claims

1. A herbicidal composition comprising a complex of a herbicidal carboxylic acid and an amine-containing polymer or oligomer.

2. The herbicidal composition of claim 1, further comprising an agriculturally acceptable adjuvant or carrier in admixture with the herbicidal composition.

3. The herbicidal composition of claim 2, wherein the herbicidal composition is an emulsifiable concentrate.

4. The herbicidal composition of claim 2, wherein the herbicidal composition is an aqueous spray solution or mixture.

5. The herbicidal composition of claim 1, wherein the herbicidal carboxylic acid is an aryloxyalkanoic acid compound of the general formula

6. The herbicidal composition of claim 1, wherein the herbicidal carboxylic acid is 2,4-D, 2,4-DB, MCPA, MCPB, mecoprop, mecoprop-P, triclopyr, or fluoroxypyr.

7. The herbicidal composition of claim 1, wherein the amine-containing polymer or oligomer is a polyethyleneimine with a molecular weight of greater than about 250 and less than about 2,000,000.

8. The herbicidal composition of claim 1, wherein the molar ratio of amine groups to carboxylic acid groups is from about 5:

1 to about 1;

5.

9. The herbicidal composition of claim 1, wherein the molar ration of amine groups to carboxylic acid groups is from about 2:

1 to about 1;

2.

10. A method of controlling undesirable vegetation comprising contacting the vegetation or the locus thereof with, or applying to the soil to prevent the emergence of vegetation, a herbicidally effective amount of the herbicidal composition of claim 2.

11. A method of reducing the volatility of a herbicidal carboxylic acid comprising adding an amine-containing polymer or oligomer to the herbicidal carboxylic acid.

12. A method of reducing the soil mobility of a herbicidal carboxylic acid comprising adding an amine-containing polymer or oligomer to the herbicidal carboxylic acid.

13. A method for reducing the eye irritating properties of aqueous herbicidal concentrates of alkylamine salts of herbicidal carboxylic acids derived from mono-, di- or trialkylamines comprising adding an amine-containing polymer or oligomer to the herbicidal carboxylic acid to form a complex of the herbicidal carboxylic acid and the amine-containing polymer or oligomer.

14. A method for reducing spray drift of a solution containing a herbicidal carboxylic acid comprising adding an amine-containing polymer or oligomer to the solution containing the herbicidal carboxylic acid to form a complex of the herbicidal carboxylic acid and the amine-containing polymer or oligomer and spraying the complex.

15. A method for improving the binding to plant surfaces of alkylamine salts of herbicidal carboxylic acids derived from mono-, di-, or trialkylamines comprising adding an amine-containing polymer or oligomer to a solution containing the herbicidal carboxylic acid to form a complex of the herbicidal carboxylic acid and the amine-containing polymer or oligomer and applying the complex to the plant surfaces.