NITRIDE SEMICONDUCTOR DEVICE

• US 20130056707A1
• Filed: 10/24/2012
• Published: 03/07/2013
• Est. Priority Date: 07/07/2000
• Status: Active Grant

• Current Assignee: Nichia Corporation
• Original Assignee: Nichia Corporation
• Inventors: KOZAKI, Tokuya
• Granted Patent: US 8,698,126 B2
• Time in Patent Office: Days
• US Class Current: 257/14
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: H01L 33/06 within the light emitting region, e.g. quantum confinement structure or tunnel barrier
• CPC Class Codes: H01L 33/24 of the light emitting region, e.g. non-planar junction
• CPC Class Codes: H01L 33/32 containing nitrogen
• CPC Class Codes: H01S 2304/12 Pendeo epitaxial lateral overgrowth [ELOG], e.g. for growing GaN based blue laser diodes
• CPC Class Codes: H01S 5/18308 having a special structure for lateral current or light confinement
• CPC Class Codes: H01S 5/18369 based on dielectric materials
• CPC Class Codes: H01S 5/2009 by using electron barrier layers
• CPC Class Codes: H01S 5/22 having a ridge or stripe structure
• CPC Class Codes: H01S 5/305 characterised by the doping materials used in the laser structure
• CPC Class Codes: H01S 5/3054 p-doping
• CPC Class Codes: H01S 5/3086 doping of the active layer
• CPC Class Codes: H01S 5/3407 characterised by special barrier layers
• CPC Class Codes: H01S 5/3415 containing details related to carrier capture times into wells or barriers
• CPC Class Codes: H01S 5/343 in AIIIBV compounds, e.g. AlGaAs-laser , InP-based laser
• CPC Class Codes: H01S 5/34333 with a well layer based on Ga(In)N or Ga(In)P, e.g. blue laser

Abstract

In the nitride semiconductor device of the present invention, an active layer 12 is sandwiched between a p-type nitride semiconductor layer 11 and an n-type nitride semiconductor layer 13. The active layer 12 has, at least, a barrier layer 2a having an n-type impurity, a well layer 1a made of a nitride semiconductor that includes In and a barrier layer 2c that has a p-type impurity, or that has been grown without being doped. An appropriate injection of carriers into the active layer 12 becomes possible by arranging the barrier layer 2c nearest to the p-type layer side.

Claims

1. A nitride semiconductor device wherein an active layer is sandwiched between p-type nitride semiconductor layers and n-type nitride semiconductor layers, wherein said p-type nitride semiconductor layers has an electrons confining layer adjoining said active layer and made of nitride semiconductor that includes Al;

and said active layer has a quantum well structure including at least one well layer made of nitride semiconductor that includes In and barrier layers made of nitride semiconductor, wherein a first barrier layer arranged in the nearest position to said p-type nitride semiconductor layer among said barrier layers substantially does not have an n-type impurity, while a second barrier layer that is different from said first barrier layer has an n-type impurity, and wherein the distance dB from the electrons confining layer to the nearest well layer is not less than 100 Å and

has the first barrier layer within the distance dB.

2. The nitride semiconductor device according to claim 1, wherein the film thickness of said first barrier is greater than the film thickness of said second barrier layer.

3. The nitride semiconductor device according to claim 1, wherein said active layer has L (L≧

2) barrier layers so that the barrier layer arranged in a position nearest to said n-type nitride semiconductor layer is denoted as barrier layer B₁ and the i-th barrier layer (i=1, 2, 3, . . . L) counted from the barrier layer B₁ toward said p-type nitride semiconductor layer is denoted as barrier layer B_i and barrier layers 8, from i=1 to i=n (1<

n<

L) include an n-type impurity.

4. The nitride semiconductor device according to claim 1, wherein the entire barrier layers other than said first barrier layer include an n-type impurity,

5. The nitride semiconductor device according to claim 1, wherein said first barrier layer is arranged in the outermost position in said active layer.

6. The nitride semiconductor device according to claim 1, wherein said second barrier layer is arranged in the outermost position close to said n-type nitride semiconductor layer within said active layer.

7. The nitride semiconductor device according to claim 6, wherein the film thickness of said first barrier layer is approximately the same as the film thickness of said second barrier layer.

8. The nitride semiconductor device according to claim 7, wherein said active layer has 2 or more well layers and has a third barrier layer between the well layers;

and the film thickness of said third barrier layer is smaller than the film thickness of said first barrier layer and said second barrier layer,

9. The nitride semiconductor device according to claim 1, wherein at least one well layer within said active layer has a film thickness of not less than 40 Å

.

10. The nitride semiconductor device according to claim 1, wherein said first barrier layer has a p-type impurity.

11. The nitride semiconductor device according to claim 1, wherein said first barrier layer includes a p-type impurity in the range of no less than 5×

10¹⁶ cm<sup>−

3</sup> and no more than 1×

10¹⁹ cm<sup>−

3</sup>.

12. The nitride semiconductor device according to claim 1, wherein said first barrier layer is p-type or i-type,

13. The nitride semiconductor device according to claim 12, wherein said first barrier layer has been grown without being doped with an impurity and includes a p-type impurity through diffusion from said p-type nitride semiconductor layer.

14. The nitride semiconductor device according to claim 1, wherein said n-type nitride semiconductor layer, said active layer and said p-type nitride semiconductor layer are layered in sequence.

15. The nitride semiconductor device according to claim 1, wherein said p-type nitride semiconductor layer has an upper clad layer made of a nitride semiconductor that includes Al of which the average mixed crystal ratio x is in the range of 0≦

0.05;

said n-type nitride semiconductor layer has a lower clad layer made of a nitride semiconductor that includes Al of which the average mixed crystal ratio x is in the range of 0≦

0.05; and

the nitride semiconductor device has a laser device structure.

16. The nitride semiconductor device according to claim 1, wherein said electrons confinement layer is provided so as to contact a barrier layer nearest to said p-type nitride semiconductor layer and has been grown being doped with a p-type impurity of which concentration is higher than that of said barrier layer in said active layer.

17. The nitride semiconductor device according to claim 1, wherein the number of well layers in said active layer is from 1 to 3.

18. The nitride semiconductor device according to claim 1, in said active layer said second barrier layer is arranged between well layers and the film thickness ratio Rt ([film thickness of a well layer]/[film thickness of a barrier layer]) of said well layer to the second barrier layer is in the range of 0.5≦

RT≦

3.

19. The nitride semiconductor device according to claim 1, wherein the film thickness dw of said well layer is in the range of 40 Å

1≦

dw 1≦

100 Å

while the film thickness of db of said second barrier layer is in the range of db≧

40 Å

.

20. The nitride semiconductor device according to claim 1, wherein said p-type nitride semiconductor layer has an upper clad made of a nitride semiconductor that includes Al and said n-type nitride semiconductor has a lower clad layer made of a nitride semiconductor, wherein the average mixed crystal ratio of Al in the upper clad layer is greater than that of the lower clad layer.