INK SET FOR CONTINUOUS INKJET PRINTING

• US 20130068131A1
• Filed: 09/16/2011
• Published: 03/21/2013
• Est. Priority Date: 09/16/2011
• Status: Active Grant

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Jeanmaire, David Louis, Bermel, Alexandra DiLauro, Lindstrom, Brian L., Nelson, David John, Sowinski, Allan Francis, Griffin, Todd Russell
• Granted Patent: US 8,784,549 B2
• Time in Patent Office: Days
• US Class Current: 106/31.89
• CPC Class Codes: C09D 11/322 Pigment inks
• CPC Class Codes: C09D 11/38 characterised by non-macromolecular additives other than solvents, pigments or dyes
• CPC Class Codes: C09D 11/40 Ink-sets specially adapted for multi-colour inkjet printing

Abstract

An aqueous inkjet ink set for use in continuous inkjet printing comprising at least one cyan ink, at least one yellow ink, at least one magenta ink, and at least one black ink, wherein each ink of the ink set comprises dispersed pigment particles and at least one surfactant selected to provide a 10-ms dynamic surface tension of less than 54 mN/m for each ink. The invention relates to continuous ink jet printing of aqueous pigmented ink compositions recycled from main ink supply reservoirs, employing a printer with drop ejectors and a drop deflector and non-printing drop catchers capable of returning unprinted ink to the fluid delivery systems following the capture of non-printing drops. The pigmented ink jet ink compositions provide for particularly suitable fluid properties on the drop catcher face that minimize printing defects that can occur during drop deflection during the printing of high dynamic range images at high speed.

Claims

1. An aqueous ink set for continuous inkjet printing comprising at least one cyan ink, at least one yellow ink, at least one magenta ink, and at least one black ink, wherein each ink of the ink set comprises dispersed pigment particles and at least one surfactant selected to provide a 10-ms dynamic surface tension of less than 54 mN/m for each ink, and wherein each of the inks are comprised of less than 10 wt % of humectant and co-solvent and have a static surface tension of at least 35 mN/m.

2. The inkjet ink set of claim 1 wherein each ink of the ink set comprises at least one surfactant selected to provide a 10-ins dynamic surface tension of less than or equal to 53 mN/m.

3. The inkjet ink set of claim 1 wherein each ink of the ink set comprises at least one surfactant selected to provide a 10-ms dynamic surface tension of less than or equal to 51 mN/m.

4. The inkjet ink set of claim 1 wherein each ink of the ink set comprises at least one surfactant selected to provide a 10-ms dynamic surface tension of less than or equal to 50 mN/m.

8. The inkjet ink set of claim 1 wherein each of the inks comprise at least one surfactant selected to provide a 10-ms dynamic surface tension of less than or equal to 51 mN/m.

9. The inkjet ink set of claim 1 wherein each of the inks are comprised of less than or equal to 8 wt % of humectant and co-solvent.

10. The inkjet ink set of claim 9 wherein each of the inks comprise at least one surfactant selected to provide a 10-ms dynamic surface tension of less than or equal to 51 mN/m.

11. The inkjet ink set of claim 1 wherein the pigment particles in each of said cyan, yellow, magenta, and black inks have a median volume-weighted particle size of less than about 90 nm.

12. The inkjet ink set of claim 1 wherein the pigment particles in each of said cyan, yellow, magenta, and black inks have 95^th percentile volume-weighted particle size diameter of less than about 150 nm.

13. The inkjet ink set of claim 1 wherein the said cyan, yellow, magenta, and black inks each have a dynamic fluid viscosity of less than about 2.0 mPa-s.

14. The inkjet ink set of claim 1 wherein the said cyan, yellow, magenta, and black inks are each comprised of one or more acetylenic diol surface active compounds to modify fluid dynamic surface tension.

15. The inkjet ink set of claim 1 wherein the said cyan, yellow, magenta, and black pigment particles are dispersed with a polymeric dispersant or are self-dispersing pigment particles without the need for a dispersant.

16. The inkjet ink set of claim 15, wherein at least one of the cyan, yellow, magenta, and black inks comprises a water soluble homopolymer or co-polymer additive distinct from any dispersant used to disperse the pigment particles, and wherein the polymer additive is present in an amount of from 0.05% to 5% by weight effective to stabilize the ink composition against particle aggregation caused by pumping the ink composition through a continuous ink jet printing fluid system.

17. The inkjet ink set of claim 15, wherein each of the cyan, yellow, magenta, and black inks comprises a water soluble homopolymer or co-polymer additive distinct from any dispersant used to disperse the pigment particles, and wherein the polymer additive is present in an amount of from 0.05% to 5% by weight effective to stabilize the ink composition against particle aggregation caused by pumping the ink composition through a continuous ink jet printing fluid system.

18. The inkjet ink set of claim 1 wherein at least one of the cyan, yellow, magenta and black inks comprises pigment particles dispersed with a polymeric, amphiphilic dispersant.

19. The inkjet ink set of claim 18, wherein polymeric dispersant comprises at least one hydrophilic monomer that is an acrylic acid or methacrylic acid monomer, and at least one monomer comprised of a hydrophobic methacrylate or acrylate monomer containing an aliphatic chain having greater than or equal to 12 carbons.

20. The inkjet ink set of claim 1 wherein each of the cyan, yellow, magenta and black inks comprises pigment particles dispersed with a polymeric, amphiphilic dispersant.

5-7. -7. (canceled)