PROCESS FOR PROCESSING A LIGNOCELLULOSIC MATERIAL

• US 20130071900A1
• Filed: 09/21/2012
• Published: 03/21/2013
• Est. Priority Date: 09/21/2011
• Status: Abandoned Application

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: MACKAY, Munro, VAN DER HEIDE, Evert
• Application Number:
  US13/624,308
• Publication Number:
  US 20130071900A1
• Time in Patent Office: Days
• US Class Current: 435/157
• CPC Class Codes: C12P 19/02 Monosaccharides 2-ketogulonic acid C12P7/60
• CPC Class Codes: C12P 19/14 produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase , e.g. by cellulase, hemicellulase
• CPC Class Codes: C12P 2201/00 Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis
• CPC Class Codes: C12P 2203/00 Fermentation products obtained from optionally pretreated or hydrolyzed cellulosic or lignocellulosic material as the carbon source
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: C12P 7/16 Butanols
• CPC Class Codes: D21C 3/04 with acids, acid salts or acid anhydrides D21C3/003 and D21C3/222 take precedence
• CPC Class Codes: D21C 5/00 Other processes for obtaining cellulose, e.g. cooking cotton linters obtaining fibres for spinning D01C; Processes characterised by the choice of cellulose-containing starting materials
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

Calcium-containing lignocellulosic material is converted at a temperature in the range from equal to or more than 120° C. to equal to or less than 210° C. with an aqueous acid solution containing one or more inorganic acids and having a pH in the range from equal to or more than 1.8 to equal to or less than 4.0 to produce a mixture, containing pretreated lignocellulosic material and aqueous acid solution, having an overall pH in the range from equal to or more than 3.0 to equal to or less than 4.5. The process allows reduction in the formation of insoluble salts.

Claims

1. A method for processing a lignocellulosic material comprising the steps of

a) contacting a lignocellulosic material at a temperature in the range from equal to or more than 120°

C. to equal to or less than 210°

C. with an aqueous acid solution containing one or more inorganic acids and having a pH in the range from equal to or more than 1.8 to equal to or less than 4.0 to produce a mixture containing pretreated lignocellulosic material and aqueous acid solution, having an overall pH in the range from equal to or more than 3.0 to equal to or less than 4.5; and

b) contacting at least a portion of the mixture produced in step a) with a base to produce a neutralized mixture containing neutralized pretreated lignocellulosic material and one or more insoluble salts.

4. The method of claim 1 wherein the lignocellulosic material is a lignocellulosic material containing equal to or more than 100 ppmw of calcium, based on the total weight of lignocellulosic material on a dry basis.

6. The method of claim 1 wherein step a) is carried out in the essential absence of an external base.

7. The method of claim 1 wherein the aqueous acid solution is an aqueous acid solution of one or more inorganic acid(s), which aqueous acid solution contains essentially no organic acid(s).

8. The method of claim 1 wherein the aqueous acid solution is an aqueous acid solution of sulphuric acid.

9. The method of claim 1 wherein the aqueous acid solution is an aqueous acid solution that comprises in the range from equal to or more than 0.00001 wt % to equal to or less than 0.08 wt % sulphuric acid, based on the total weight of the aqueous acid solution.

10. The method of claim 1 wherein the pretreated lignocellulosic material produced in step a) contains a total amount of calcium equal to or more than 70 wt %, of the total amount of calcium in the lignocellulosic material used as a feed to step a).

12. The method of claim 1 further comprising a desalting step.

13. The process according to method of claim 12 wherein the desalting step comprises electrodialysis of a product containing one or more insoluble salts to produce a concentrated salt solution;

and removing and/or recovering insoluble salts from the concentrated salt solution by means of crystallization.

14. The method of claim 12 wherein the desalting step comprises anaerobic fermentation of a product containing the one or more insoluble salts to produce a desalting residue containing the insoluble salts;

and recovering the insoluble salts from the residue.

15. The method of claim 12 wherein the desalting step comprises contacting of a product containing the one or more insoluble salts with one or more ion-exchange resins to produce a concentrated salt solution;

and removing and/or retrieving the insoluble salts from the concentrated salt solution by means of crystallization.

16. The method of claim 12 wherein the desalting step comprises:

(I) removing water from the fermentation broth produced in step d) and/or one or more distillate fraction(s) and/or one or more residue fraction(s) obtained in optional step e) by means of evaporation to produce a concentrated product;

(II) burning the concentrated product produced in step (I) to produce ashes; and

(III) removing and/or retrieving alkali metal salts and/or alkali metal earth salts from the ashes.

2. A process for the production of at least one alkanol comprising the steps of:

a) contacting a lignocellulosic material at a temperature in the range from equal to or more than 120°

C. to equal to or less than 210°

C. with an aqueous acid solution containing one or more inorganic acids and having a pH in the range from equal to or more than 1.8 to equal to or less than 4.0 to produce a mixture containing pretreated lignocellulosic material and aqueous acid solution, having an overall pH in the range from equal to or more than 3.0 to equal to or less than 4.5;

b) optionally contacting at least a portion of the mixture produced in step a) with a base to produce a neutralized mixture containing neutralized pretreated lignocellulosic material and one or more insoluble salts;

c) hydrolyzing at least a portion of the pretreated lignocellulosic material produced in step a) and/or at least a portion of the neutralized pretreated lignocellulosic material produced in step b) to produce a hydrolysis product; and

d) fermenting at least a portion of the hydrolysis product produced in step c) to produce a fermentation broth comprising at least one alkanol.

3. The process of claim 2 further comprising step e) recovering the alkanol from the fermentation broth produced in step d).

5. The process of claim 2 wherein the lignocellulosic material is a lignocellulosic material containing equal to or more than 100 ppmw of calcium, based on the total weight of lignocellulosic material on a dry basis.

11. The process of claim 2 wherein the aqueous acid solution is an aqueous acid solution of sulphuric acid.

17. A method for processing a lignocellulosic material comprising the steps of:

a) contacting the lignocellulosic material at a temperature in the range from equal to or more than 120°

C. to equal to or less than 210°

C. with an aqueous acid solution containing one or more inorganic acids and having a pH in the range from equal to or more than 1.8 to equal to or less than 4.0 to produce a mixture containing pretreated lignocellulosic material and aqueous acid solution;

b) leaching basic compounds from the lignocellulosic material to adjust the overall pH of the mixture to a pH in the range from equal to or more than 3.0 to equal to or less than 4.5; and

c) contacting at least a portion of the mixture produced in step a) with a base to produce a neutralized mixture containing neutralized pretreated lignocellulosic material and one or more insoluble salts.

18. The method of claim 17 wherein the aqueous acid solution is an aqueous acid solution of sulphuric acid.

19. The method of claim 17 wherein the lignocellulosic material is a lignocellulosic material containing equal to or more than 100 ppmw of calcium, based on the total weight of lignocellulosic material on a dry basis.

20. A process for processing a lignocellulosic material comprising the steps of

a) contacting a lignocellulosic material at a temperature in the range from equal to or more than 120°

C. to equal to or less than 210°

C. with an aqueous acid solution containing one or more inorganic acids and having a pH in the range from equal to or more than 1.8 to equal to or less than 4.0 to produce a mixture containing pretreated lignocellulosic material and aqueous acid solution, having an overall pH in the range from equal to or more than 3.0 to equal to or less than 4.5; and

b) neutralizing the mixture produced in step a) to produce a neutralized mixture having a higher pH than the mixture produced in step a).