METHOD FOR HEATING A FEEDSTOCK

• US 20130071903A1
• Filed: 09/20/2012
• Published: 03/21/2013
• Est. Priority Date: 09/20/2011
• Status: Abandoned Application

• Current Assignee: Iogen Energy Corporation (Iogen Corporation)
• Original Assignee: Iogen Energy Corporation (Iogen Corporation)
• Inventors: Rowland, Stephen A., van der Meulen, Torbjorn
• Application Number:
  US13/623,207
• Publication Number:
  US 20130071903A1
• Time in Patent Office: Days
• US Class Current: 435/162
• CPC Class Codes: C08H 8/00 Macromolecular compounds derived from lignocellulosic materials pretreatment thereof B27N
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N
• CPC Class Codes: C12P 19/02 Monosaccharides 2-ketogulonic acid C12P7/60
• CPC Class Codes: C12P 2201/00 Pretreatment of cellulosic or lignocellulosic material for subsequent enzymatic treatment or hydrolysis
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: C13K 1/02 obtained by saccharification of cellulosic materials manufacture of fodder A23K10/32
• CPC Class Codes: C13K 13/002 Xylose
• CPC Class Codes: C13K 13/007 Separation of sugars provided for in subclass C13K C13K3/00 takes precedence
• CPC Class Codes: D21C 1/02 with water or steam
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

The present invention provides a method for producing a pretreated or hydrolyzed lignocellulosic feedstock. The method comprises feeding a lignocellulosic feedstock to a plug formation device and forming a feedstock plug therein. The plug or segments thereof are fed into an elongate chamber that comprises steam addition means for direct steam addition and a rotating shaft mounted co-axially within the chamber having one or more disintegrating elements mounted on it. Disintegrated feedstock particles are produced in the elongate chamber by the disintegrating elements. The disintegrated feedstock particles are heated by contact with the steam introduced through the steam addition means. The disintegrated feedstock particles are then treated in a reactor to produce the pretreated or hydrolyzed lignocellulosic feedstock. Further provided is a feedstock composition comprising disintegrated feedstock particles. Also provided are methods for reducing erosion on equipment by maintaining the discharge consistency from the plug formation device below 35 wt %.

Claims

1. A method for producing a pretreated or hydrolyzed lignocellulosic feedstock comprising:

(i) feeding a lignocellulosic feedstock to a plug formation device and forming a feedstock plug therein;

(ii) feeding the plug or segments thereof into an elongate chamber having at least a portion thereof that is cylindrical, said chamber having steam addition means for direct steam addition and a rotating shaft mounted therein having one or more disintegrating elements arranged thereon;

(iii) producing disintegrated feedstock particles in said elongate chamber by said disintegrating elements;

(iv) heating the disintegrated feedstock particles by contacting the particles with steam introduced through said steam addition means, wherein the operating pressure in the chamber is at least about 90 psia; and

thereafter

(v) pretreating or hydrolyzing the disintegrated feedstock particles in a reactor to produce the pretreated or hydrolyzed lignocellulosic feedstock.

2. The method of claim 1, wherein the lignocellulosic feedstock is in the form of a slurry and is fed to a dewatering device, to produce a dewatered feedstock and, wherein, the dewatered feedstock is then fed to the plug formation device.

3. The method of claim 1, wherein the feedstock is pressurized and then fed to a combined dewatering and plug formation device and wherein the pressure of the feedstock at the inlet of the device is greater than about 45 psia.

4. The method of claim 3, wherein the disintegrating elements are arranged on said shaft so as to sweep the inner surface of at least a region of the chamber.

5. The method of claim 4, wherein the disintegrating elements continuously axially sweep the inner surface of at least a region of the chamber.

6. The method of claim 5, wherein the steam addition means comprises inlets for direct steam injection disposed along the length of the chamber.

7. The method of claim 6, wherein the chamber does not contain an indirect heating jacket.

8. The method of claim 7, wherein pretreating or hydrolyzing comprises the addition of chemical to the disintegrated feedstock particles.

9. The method of claim 8, wherein the chemical is acid or alkali.

10. The method of claim 9, wherein the distance between the inner surface of the chamber and the outer edge of the disintegrating element that is closest to the inner surface is less than about 10 percent of the inside diameter of the chamber.

11. The method of claim 10, wherein the speed of the outer edge of the disintegrating element that is closest to the inner surface of the chamber is about 200 m/min to about 1000 m/min.

12. The method of claim 11, wherein the speed is about 450 m/min to about 800 m/min.

13. A method for producing a pretreated or hydrolyzed lignocellulosic feedstock comprising:

(i) feeding a lignocellulosic feedstock to a plug formation device and forming a feedstock plug therein;

(ii) feeding the plug or segments thereof from the plug formation device into an elongate chamber having at least a portion thereof that is cylindrical, said chamber having steam addition means for direct steam addition and a rotating shaft mounted therein having one or more disintegrating elements arranged thereon, wherein the disintegrating elements are arranged on said shaft so as to sweep the inner surface of at least a region of the chamber;

(iii) producing disintegrated feedstock particles in said elongate chamber by said disintegrating elements;

(iv) heating the disintegrated feedstock by contacting the particles with steam introduced through said steam addition means, wherein the operating pressure in the chamber is at least about 90 psia; and

thereafter

(v) pretreating or hydrolyzing the disintegrated feedstock particles in a pretreatment reactor to produce the pretreated or hydrolyzed lignocellulosic feedstock.

14. A lignocellulosic feedstock composition comprising:

(i) disintegrated lignocellulosic feedstock particles;

(ii) about 15 to about 35 wt % undissolved solids, wherein the undissolved solids comprise between about 20 and about 60 wt % cellulose and between about 10 and about 30 wt % xylan; and

(iii) a mineral or organic acid;

wherein said feedstock particles are not primarily derived from wood chips or pulp, and wherein the pH of the feedstock composition is between about 0.5 and about 4.5.

15. The lignocellulosic feedstock composition of claim 14, wherein the temperature of the composition is between about 100°

C. and about 280°

C.

16. The lignocellulosic feedstock composition of claim 15, wherein the lignocellulosic feedstock is bagasse or sugar cane straw.

17. The lignocellulosic feedstock composition of claim 16, wherein the lignocellulosic feedstock composition comprises about 15 wt % to about 30 wt % undissolved solids.

18. A method comprising pretreating the lignocellulosic feedstock composition of claim 15.

19. A pretreated lignocellulosic feedstock composition produced according to the method of claim 18, wherein at least 70% of the cellulose in the pretreated lignocellulosic feedstock is converted to glucose, as measured when hydrolyzed with Trichoderma reesei cellulase enzymes, and wherein the pretreated lignocellulosic feedstock is produced from sugar cane bagasse or sugar cane straw.

20. A method for producing an alcohol from a lignocellulosic feedstock comprising:

(i) feeding a lignocellulosic feedstock in the form of a slurry to a plug formation device and forming a feedstock plug therein, wherein the plug or segments thereof exiting the plug formation device have an undissolved dry solids content between about 20 wt % and about 35 wt %;

(ii) pretreating the lignocellulosic feedstock after step (i) to produce a pretreated lignocellulosic feedstock having an undissolved dry solids content of between about 15 and 25 wt %;

(iii) enzymatically hydrolyzing the pretreated lignocellulosic feedstock to produce a solution comprising at least glucose; and

(iv) fermenting at least the glucose to produce the alcohol,

wherein the lignocellulosic feedstock is selected from cultivated crops, sugar processing residues and agricultural residues having an ash content of greater than 0.5% (w/w).

21. The method of claim 20, wherein the slurry fed to the plug formation device is a soaked feedstock slurry.

22. The method of claim 21, wherein the lignocellulosic feedstock is sugar cane bagasse or sugar cane straw.

23. The method of claim 20, 21 or 22, claim 21, wherein the lignocellulosic feedstock has an ash content of between 1.5% and 15% (w/w).

27. The method of claim 23, wherein the lignocellulosic feedstock is not leached or washed prior to step (i) in order to remove greater than 50 wt % of the ash.

24. A method for producing a pretreated or hydrolyzed lignocellulosic feedstock comprising:

(i) soaking a lignocellulosic feedstock with an aqueous solution to produce a soaked lignocellulosic feedstock, wherein said lignocellulosic feedstock does not primarily contain wood chips or pulp;

(ii) feeding the soaked lignocellulosic feedstock to a plug formation device and forming a feedstock plug therein, wherein the plug or segments thereof exiting the plug formation device have an undissolved dry solids content between about 20 wt % and about 35 wt %;

(iii) disintegrating the plug or segments thereof to produce disintegrated feedstock particles and heating the disintegrated feedstock particles; and

thereafter

(iv) pretreating or hydrolyzing the disintegrated feedstock particles in a reactor to produce the pretreated or hydrolyzed lignocellulosic feedstock.

25. The method of claim 24, wherein the soaked feedstock is partially dewatered prior to being fed to the plug formation device.

26. The method of claim 24, wherein the soaked feedstock is partially dewatered in a pressurized screw press prior to plug formation.