PESTICIDAL COMPOSITIONS

• US 20130072382A1
• Filed: 11/14/2012
• Published: 03/21/2013
• Est. Priority Date: 05/05/2009
• Status: Active Grant

• Current Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Original Assignee: Dow Agrosciences LLC (Corteva, Inc.)
• Inventors: Trullinger, Tony K., Hunter, Ricky, Garizi, Negar, Yap, Maurice C. H., Buysse, Ann M., Pernich, Dan, Johnson, Timothy C., Bryan, Kristy, Deamicis, Carl, Zhang, Yu, Niyaz, Noormohamed M., McLeod, CaSandra Lee, Ross, Ronald Jr., Zhu, Yuanming, Johnson, Peter Lee, Eckelbarger, Joseph D., Parker, Marshall H.
• Granted Patent: US 9,006,446 B2
• Time in Patent Office: Days
• US Class Current: 504/116.1
• CPC Class Codes: A01N 43/40 six-membered rings
• CPC Class Codes: A01N 43/78 1,3-Thiazoles; Hydrogenated 1,3-thiazoles
• CPC Class Codes: C07D 417/04 directly linked by a ring-member-to-ring-member bond
• CPC Class Codes: C07D 417/14 containing three or more hetero rings

Abstract

This document discloses molecules having the following formula (“Formula I”):

Claims

1. A molecule having the following formula (“

Formula I”

);

4. A molecule according to claim 1 or 2 in the form of a pesticidally acceptable acid addition salt, salt derivative, or solvate.

5. A molecule according to claim 1 or 2 having at least one ²H.

6. A molecule according to claim 1 or 2 having at least one ¹⁴C.

7. A molecule according to claim 1 or 2 that is a resolved stereoisomer.

8. A composition comprising a molecule according to claim 1 or 2 and at least one member of the Insecticide Group, Acaricide Group, Nematicide Group, Fungicide Group, or Herbicide Group.

9. A composition comprising a molecule according to claim 1 or 2 and at least one biopesticide.

10. A composition comprising a molecule according to claim 1 or 2 and at least one of the following compounds:

(a) 3-(4-chloro-2,6-dimethylphenyl)-4-hydroxy-8-oxa-1-azaspiro[4,5]dec-3-en-2-one;

(b) 3-(4′

-chloro-2,4-dimethyl[1,1′

-biphenyl]-3-yl)-4-hydroxy-8-oxa-1-azaspiro[4,5]dec-3-en-2-one;

(c) 4-[[(6-chloro-3-pyridinyl)methyl]methylamino]-2(5H)-furanone;

(d) 4-[[(6-chloro-3-pyridinyl)methyl]cyclopropylamino]-2(5H)-furanone;

(e) 3-chloro-N2-[(1S)-1-methyl-2-(methylsulfonyl)ethyl]-N1-[2-methyl-4-[1,2,2,2-tetrafluoro-1-(trifluoromethyl)ethyl]phenyl]-1,2-benzenedicarboxamide;

(f) 2-cyano-N-ethyl-4-fluoro-3-methoxy-benenesulfonamide;

(g) 2-cyano-N-ethyl-3-methoxy-benzene sulfonamide;

(h) 2-cyano-3-difluoromethoxy-N-ethyl-4-fluoro-benzene sulfonamide;

(i) 2-cyano-3-fluoromethoxy-N-ethyl-benzenesulfonamide;

(j) 2-cyano-6-fluoro-3-methoxy-N,N-dimethyl-benzenesulfonamide;

(k) 2-cyano-N-ethyl-6-fluoro-3-methoxy-N-methyl-benzenesulfonamide;

(l) 2-cyano-3-difluoromethoxy-N,N-dimethylbenzenesulfon-amide;

(m) 3-(difluoromethyl)-N-[2-(3,3-dimethylbutyl)phenyl]-1-methyl-1H-pyrazole-4-carboxamide;

(n) N-ethyl-2,2-dimethylpropionamide-2-(2,6-dichloro-α

,α

,α

-trifluoro-p-tolyl)hydrazone;

(o) N-ethyl-2,2-dichloro-1-methylcyclopropane-carboxamide-2-(2,6-dichloro-α

,α

,α

-trifluoro-p-tolyl)hydrazone nicotine;

(p) O-{(E-)-[2-(4-chloro-phenyl)-2-cyano-1-(2-trifluoromethylphenyl)-vinyl]}S-methyl thiocarbonate;

(q) (E)-N1-[(2-chloro-1,3-thiazol-5-ylmethyl)]-N2-cyano-N1-methylacetamidine;

(r) 1-(6-chloropyridin-3-ylmethyl)-7-methyl-8-nitro-1,2,3,5,6,7-hexahydro-imidazo[1,2-a]pyridin-5-ol;

(s) 4-[4-chlorophenyl-(2-butylidine-hydrazono)methyl)]phenyl mesylate;

or

(t) N-Ethyl-2,2-dichloro-1-methylcyclopropanecarboxamide-2-(2,6-dichloro-alpha,alpha,alpha-trifluoro-p-tolyl)hydrazone.

2. A molecule having the following formula (“

Formula I”

);

3. A molecule according to claim 2 wherein

(a) X is CR8;

(b) R1 is H;

(c) R2 is H;

(d) R3 is H;

(e) R4 is C₁ or CH₃;

(f) R5 is H or unsubstituted C₁-C₆ alkyl;

(g) R6 is O;

(h) R7 is (unsubstituted C₁-C₆ alkyl)S(O)_n(unsubstituted C₁-C₆ alkyl), (unsubstituted C₁-C₆ alkyl)S(O)_n(unsubstituted C₁-C₆ alkenyl), O(unsubstituted C₁-C₆ alkyl), (C₁-C₆ alkyl);

(i) R8 is H or F; and

(k) n is 0, 1, or 2.