PRESSURE-SENSITIVE ADHESIVE COMPOSITION FOR OPTICAL FILMS AND PRESSURE-SENSITIVE ADHESION TYPE OPTICAL FILM

• US 20130079468A1
• Filed: 06/03/2011
• Published: 03/28/2013
• Est. Priority Date: 06/04/2010
• Status: Active Grant

• Current Assignee: Kuraray Company Limited
• Original Assignee: Kuraray Company Limited
• Inventors: Morishita, Yoshihiro, Kanemura, Hideaki, Oshita, Shinya, Kawasaki, Masahiko
• Granted Patent: US 9,175,197 B2
• Time in Patent Office: Days
• US Class Current: 525/89
• CPC Class Codes: C08F 297/026 polymerising acrylic acid, methacrylic acid or derivatives thereof
• CPC Class Codes: C08L 2205/02 containing two or more polymers of the same C08L -group
• CPC Class Codes: C08L 53/00 Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
• CPC Class Codes: C09J 153/00 Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
• CPC Class Codes: C09J 2203/318 for the production of liquid crystal displays
• CPC Class Codes: C09J 2301/312 parameters being the characterizing feature
• CPC Class Codes: C09J 2453/00 Presence of block copolymer
• CPC Class Codes: C09J 7/22 Plastics; Metallised plastics
• CPC Class Codes: C09J 7/38 Pressure-sensitive adhesives [PSA]
• CPC Class Codes: C09J 7/387 Block-copolymers
• CPC Class Codes: G02B 1/14 Protective coatings, e.g. hard coatings
• CPC Class Codes: G02B 5/3033 in the form of a thin sheet or foil, e.g. Polaroid

Abstract

There is provided a pressure-sensitive adhesive composition for optical films, which is excellent in heat resistance, weathering resistance and bleed resistance, which has an excellent balance of pressure-sensitive adhesion properties, such as adhesive strength, cohesive force and tack, the tack of which can be controlled, which is excellent in initial reworkability when it is used for applying an optical film to an adherend or applying a protective film to an optical film, and which further exhibits excellent adhesive durability by virtue of rise of adhesive strength when such a film as above in the applied state is kept over a long period of time after application or especially when the film in the applied state is exposed to high temperatures or moist heat. A pressure-sensitive adhesive composition containing a specific acrylic diblock copolymer (I) and a specific acrylic triblock copolymer (II) in a specific proportion and a pressure-sensitive adhesive for optical films using the pressure-sensitive adhesive composition as a base are produced.

Claims

1. A pressure-sensitive adhesive composition comprising:

(I) an acrylic diblock copolymer of formula (1);

A-B 

 

(1),

wherein;

A is a methacrylic acid alkyl ester polymer block; and

B is an acrylic acid alkyl ester polymer block,

wherein the content of the polymer block B is 10 to 55% by mass, based on a total mass of the acrylic diblock copolymer (I), and

wherein the acrylic diblock copolymer (I) has a weight-average molecular weight (Mw) in a range from 9,000 to 300,000, and a molecular weight distribution (Mw/Mn) in a range from 1.0 to 1.5; and

(II) an acrylic triblock copolymer of formula (2);

C1-D-C2 

 

(2),

wherein;

C1 and C2 are each independently a methacrylic acid alkyl ester polymer block having a glass transition temperature of not lower than 100°

C.; and

D is an acrylic acid alkyl ester polymer block having a glass transition temperature of not higher than −

20°

C.,

wherein the content of the polymer block D is 82 to 95% by mass, based on a total mass of the acrylic triblock copolymer (II), and

wherein the acrylic triblock copolymer (I) has a weight-average molecular weight (Mw) in a range from 50,000 to 300,000, and a molecular weight distribution (Mw/Mn) in a range from 1.0 to 1.5,

wherein a mass ratio of the acrylic diblock copolymer (I) to the acrylic triblock copolymer (II), (I)/(II), is in the range of 70/30 to 20/80.

2. The pressure-sensitive adhesive composition of claim 1, wherein the mass ratio of the acrylic diblock copolymer (I) to the acrylic triblock copolymer (II), (I)/(II), is in the range of 70/30 to 30/70.

3. The pressure-sensitive adhesive composition of claim 1, wherein the mass ratio of the acrylic diblock copolymer (I) to the acrylic triblock copolymer (II), (I)/(II), is in the range of 70/30 to 41/59.

4. The pressure-sensitive adhesive composition of claim 1, wherein the content of the polymer block B in the acrylic diblock copolymer (I) is 10 to 49% by mass.

5. The pressure-sensitive adhesive composition of claim 1, having a microphase separation structure comprising a rigid polymer phase comprising the polymer block A of the acrylic diblock copolymer (I) and the polymer block C1 and the polymer block C2 of the acrylic triblock copolymer and a soft polymer phase comprising the polymer block B of the acrylic diblock copolymer (I) and the polymer block D of the acrylic triblock copolymer (II),

wherein the rigid polymer phase and the soft polymer phase together form a continuous structure.

6. A pressure-sensitive adhesion optical film, comprising a pressure-sensitive adhesive layer comprising the pressure-sensitive adhesive composition of claim 1.

7. A protective film, comprising a pressure-sensitive adhesive layer comprising the pressure-sensitive adhesive composition of claim 1.

8. The pressure-sensitive adhesion optical film of claim 6, wherein a ratio of change in adhesive strength of the pressure-sensitive adhesion optical film to an adherend, as calculated from formula (3), is not less than 200%:

[(180°

peel strength after 24 hours at 90°

C.)−

(180°

peel strength after 24 hours at 23°

C.)]÷

(180°

peel strength after 24 hours at 23°

C.)×

100[%] 

 

(3).

9. The protective film of claim 7, wherein a ratio of change in adhesive strength of the protective film to an adherend, as calculated from formula (3), is not less than 200%:

[(180°

peel strength after 24 hours at 90°

C.)−

(180°

peel strength after 24 hours at 23°

C.)]÷

(180°

peel strength after 24 hours at 23°

C.)×

100[%] 

 

(3).

10. An image display device, comprising the pressure-sensitive adhesion optical film of claim 6.

11. An image display device, comprising the protective film of claim 7.

12. The pressure-sensitive adhesive composition of claim 1, wherein the content of the polymer block B in the acrylic diblock copolymer (I) is 18 to 35% by mass.

13. The pressure-sensitive adhesive composition of claim 1, wherein the content of the polymer block A in the acrylic diblock copolymer (I) is 82 to 65% by mass.

14. The pressure-sensitive adhesive composition of claim 1, wherein the weight-average molecular weight of the acrylic diblock copolymer (I) is in a range from 18,000 to 200,000.

15. The pressure-sensitive adhesive composition of claim 1, wherein the weight-average molecular weight of the acrylic diblock copolymer (I) is in a range from 30,000 to 150,000.

16. The pressure-sensitive adhesive composition of claim 1, wherein the molecular weight distribution (Mw/Mn) of the acrylic diblock copolymer (I) is in a range from 1.0 to 1.4.

17. The pressure-sensitive adhesive composition of claim 1, wherein the molecular weight distribution (Mw/Mn) of the acrylic diblock copolymer (I) is in a range from 1.0 to 1.3.

18. The pressure-sensitive adhesive composition of claim 1, wherein the content of the polymer block D in the acrylic triblock copolymer (II) is 82 to 90% by mass.

19. The pressure-sensitive adhesive composition of claim 1, wherein the weight-average molecular weight of the acrylic triblock copolymer (II) is in a range from 70,000 to 250,000.

20. The pressure-sensitive adhesive composition of claim 1, wherein the molecular weight distribution (Mw/Mn) of the acrylic triblock copolymer (II) is in a range from 1.0 to 1.4.