Polymeric Composites Having Oriented Nanomaterials and Methods of Making the Same

• US 20130090405A1
• Filed: 10/11/2012
• Published: 04/11/2013
• Est. Priority Date: 10/11/2011
• Status: Active Grant

• Current Assignee: Yale University
• Original Assignee: Yale University
• Inventors: Elimelech, Menachem, Mauter, Meagan, Osuji, Chinedum
• Granted Patent: US 8,748,504 B2
• Time in Patent Office: Days
• US Class Current: 522/71
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C08F 2/24 with the aid of emulsifying agents
• CPC Class Codes: C08F 2/44 Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
• CPC Class Codes: C08F 2/48 by ultraviolet or visible light
• CPC Class Codes: C08K 2201/01 Magnetic additives
• CPC Class Codes: C08K 7/00 Use of ingredients characterised by shape

Abstract

The present invention relates to the development and fabrication of thin-film polymer nanocomposites containing vertically aligned nanomaterials, such as single-walled carbon nanotubes (SWNTs). In certain embodiments, the present invention utilizes liquid crystal mesophases of hexagonally packed cylindrical micelles that orient with their long axes parallel to an applied magnetic field, thereby directing the alignment of the nanomaterials, such as SWNTs, sequestered in the micellar cores. In certain embodiments, the mesophase may be a stable, single-phase material containing monomers that can be polymerized after nanotube alignment to form the nanocomposite polymer.

Claims

1. A method of aligning a nanomaterial in a polymeric film, comprising the steps of:

adding at least one nanomaterial into a mesophase comprising at least one surfactant and at least one monomer;

applying a magnetic field to the mesophase, wherein the at least one surfactant and at least one nanomaterial at least partially align in response to the magnetic field; and

polymerizing the mesophase to form a film containing the at least partially aligned surfactant and nanomaterial.

2. The method of claim 1, wherein the mesophase further comprises a crosslinker.

3. The method of claim 1, wherein the mesophase further comprises a photoinitiator.

4. The method of claim 3, wherein the monomer is polymerized by exposing the mesophase to UV light.

5. The method of claim 1, wherein the at least one surfactant is dodecyltrimethylammonium bromide (DTAB).

6. The method of claim 1, wherein the at least one monomer is hydroxyethylmethacrylate (HEMA).

7. The method of claim 1, wherein the nanomaterial is a single walled carbon nanotube.

8. The method of claim 2, wherein the crosslinker is poly(ethylene glycol)-400 dimethacrylate.

9. The method of claim 3, wherein the photoinitiator is Darocur TPO.

10. The method of claim 1, further comprising:

raising the temperature of the mesophase such that the at least one surfactant is in a disordered state prior to applying the magnetic field to the mesophase; and

controlling the rate of cooling of the mesophase as the surfactant returns to an ordered state while the magnetic field is applied.

11. The method of claim 1, wherein the nanomaterial is mixed in a solution comprising a dispersing agent prior to adding the nanomaterial to the mesophase.

12. The method of claim 11, wherein the dispersing agent is sodium taurodeoxycholate (TDOC).

13. A polymeric film formed by the method of claim 1.

14. The method of claim 5, wherein the amount of DTAB in the mesophase is between 30-60%.

15. The method of claim 6, wherein the amount of HEMA in the mesophase is between 10-30%.

16. The method of claim 1, wherein the at least partial alignment of the at least one surfactant and nanomaterial is directed by a magnetic field strength of less than 6 Tesla (T).

17. A nanocomposite, comprising:

at least one nanomaterial;

at least one surfactant;

at least one monomer;

at least one crosslinker; and

at least one photoinitiator;

wherein the at least one nanomaterial and surfactant are at least partially aligned via exposure to a magnetic field; and

wherein the at least one monomer is polymerized via exposure to UV light after the at least one nanomaterial and surfactant are at least partially aligned.

18. The nanocomposite of claim 17, wherein the at least one nanomaterial is a single walled carbon nanotube, the at least one surfactant is dodecyltrimethylammonium bromide (DTAB), the at least one monomer is hydroxyethylmethacrylate (HEMA), the at least one crosslinker is poly(ethylene glycol)-400 dimethacrylate, and the at least one photoinitiator is Darocur TPO.

19. A method of fabricating a nanocomposite, comprising the steps of:

adding at least one nanomaterial into a mesophase comprising dodecyltrimethylammonium bromide (DTAB), hydroxyethylmethacrylate (HEMA), poly(ethylene glycol)-400 dimethacrylate and Darocur TPO,

raising the temperature of the mesophase such that the mesophase is in a disordered state;

applying a magnetic field having a strength of less than 6 Tesla to the mesophase, wherein the DTAB at least partially aligns in response to the magnetic field;

controlling the rate of cooling of the mesophase as it returns to an ordered state; and

polymerizing the mesophase to form a polymeric film containing the at least one nanomaterial.

20. The method of claim 19, wherein the at least one nanomaterial is a single walled carbon nanotube.