Fabrication of High Energy Density Battery

• US 20130106029A1
• Filed: 10/26/2012
• Published: 05/02/2013
• Est. Priority Date: 10/27/2011
• Status: Abandoned Application

• Current Assignee: Sapurast Research LLC
• Original Assignee: Infinite Power Solutions, Inc. (Apple Inc.)
• Inventors: Snyder, Shawn W., Neudecker, Bernd J., LaGuardia, Alexandra Z., Lytle, Damon E.
• Application Number:
  US13/661,619
• Publication Number:
  US 20130106029A1
• Time in Patent Office: Days
• US Class Current: 264/571
• CPC Class Codes: H01M 10/052 Li-accumulators
• CPC Class Codes: H01M 10/0562 Solid materials
• CPC Class Codes: H01M 10/399 Cells with molten salts
• CPC Class Codes: H01M 2300/0045 Room temperature molten salts comprising at least one organic ion
• CPC Class Codes: H01M 4/043 involving compressing or compaction
• CPC Class Codes: H01M 4/0471 involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis
• CPC Class Codes: H01M 4/139 Processes of manufacture
• CPC Class Codes: H01M 6/40 Printed batteries , e.g. thin film batteries
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A method for making an electrochemical cell includes, for example, providing a cathode powder; and pressing the cathode powder at a pressure of more than 500 bar and less than 10000 bar, resulting in a pressed cathode body with a pressed porosity of more than 5 vol % and less than 60 vol %.

Claims

1. A method for making an electrochemical cell, comprising:

providing a cathode powder; and

pressing the cathode powder at a pressure of more than 500 bar and less than 10000 bar, resulting in a pressed cathode body with a pressed porosity of more than 5 vol % and less than 60 vol %.

2. The method of claim 1, wherein said cathode powder is pressed at room temperature.

3. The method of claim 1, wherein said cathode powder is pressed at temperatures higher than 50°

C.

4. The method of claim 1, wherein said cathode powder includes only electrochemically active, positive electrode material.

5. The method of claim 1, wherein said cathode powder comprises binder material.

6. The method of claim 5, wherein said binder is, after pressing of said positive cathode powder, subjected to a heat treatment at less than 50°

C. below the melting point or decomposition point of said binder.

7. The method of claim 5, wherein said binder comprises a material from the group of:

Poly(vinylidene fluoride);

poly(vinylidene fluoride—

co-hexafluoropropylene);

poly(ethylene glycol) dimethyl ether,;

poly(vinyl alcohol);

carboxymethylcellulose;

diacetyl cellulose;

poly(vinyl chloride);

carboxylated poly(vinyl chloride);

poly(vinyl fluoride);

ethylene-oxide containing polymer;

poly(vinyl pyrrolidone), poly(urethane);

poly(tetrafluoroethylene);

styrene-butadiene rubber;

acrylated styrene-butadiene rubber;

nylon;

surlyn; and

polyvinyl butyral resin.

8. The method of claim 1, wherein at least 50% of the mass of said cathode powder consists of particles that are less than 20 μ

m along their main axis.

9. The method of claim 8, further comprising particle sizing accomplished by ball-milling of a parent cathode powder wherein at least 50% of said parent cathode powder'"'"'s mass includes particles that are substantially smaller than 20 μ

m along their main axis.

10. The method of claim 1, further comprising soaking a liquid electrolyte into the pores of said pressed cathode body after said pressing.

11. The method of claim 10, further comprising supplying lithium ion conductivity to said cathode by said liquid electrolyte.

12. The method of claim 11, wherein said lithium ion conductivity is between about 10⁻

3 S/cm and about 10<sup>−

5</sup> S/cm.

13. The method of claim 10, wherein said soaking is performed in a vacuum.

14. The method of claim 10, wherein said soaked liquid electrolyte is held in place by said cathode via capillary action so that said liquid electrolyte does not escape said cathode by gravity action.

15. The method of claim 10, wherein said liquid electrolyte is a molten organic salt containing at least one dissolved lithium containing salt.

16. The method of claim 15, wherein said molten organic salt comprises:

at least one cation selected from the group;

pyrrolidinium, pyrrolidinium derivatives, imidazolium, imidazolium derivatives, phosphonium, phosphonium derivatives, organic ammonium, organic ammonium derivatives, choline, choline derivatives, pyrazolium, pyrazolium derivatives, pyridinium, pyridinium derivatives, piperidinium, piperidinium derivatives, morpholinium, morpholinium derivatives, sulfonium, and sulfonium derivatives; and

at least one anion selected from the group;

hexafluorophosphate, hexafluoroantimonate, tetrafluoroborate, bis(trifluoromethylsulfonyl)imide, bis(fluorosulfonyl)imide, chloride, bromide, iodide, dicyanamide, acetate, methylcarbonate, methylsulfate, nitrate, tetrachloroaluminate, thiocyanate, trifluoromethanesulfonate, hydrogen carbonate, dibutylphosphate; and

wherein said dissolved lithium containing salt comprises lithium cations and anions from the group;

hexafluorophosphate, hexafluoroantimonate, tetrafluoroborate, bis(trifluoromethylsulfonyl)imide, bis(fluorosulfonyl)imide, chloride, bromide, iodide, dicyanamide, acetate, methylcarbonate, methylsulfate, nitrate, tetrachloroaluminate, thiocyanate, trifluoromethanesulfonate, hydrogen carbonate, and dibutylphosphate.

17. The method of claim 1, wherein said electrochemical cell further comprising an electrolyte layer wherein a first side of said electrolyte layer is in intimate contact across said pressed cathode body.

18. The method of claim 17, further comprising fabricating said electrolyte layer by pressing against said positive cathode powder before said pressed cathode body is created.

19. The method of claim 18 comprising, wherein said electrolyte layer comprises:

materials selected from the group of electronically insulating materials;

metal oxides, metal nitrides, metal sulfides, metal fluorides, metal chlorides, metal bromides, metal iodides, borates, carbonates, silicates, germanates, nitrates, phosphates, arsenates, sulfates, selenates, oxyfluorides, oxychlorides, oxybromides, oxyiodides, oxynitrides, carbides, carbonitrides, poly(vinylidene fluoride), poly(tetrafluoroethylene), polyacrylates, polyethylene, polypropylene, polyester, polyamides, polyimides, polyethers, polycarbonates, polysulfones, and silicones; and

further comprising a molten organic salt with dissolved lithium salt, comprising;

at least one cation from the group of;

pyrrolidinium, pyrrolidinium derivatives, imidazolium, imidazolium derivatives, phosphonium, phosphonium derivatives, organic ammonium, organic ammonium derivatives, choline, choline derivatives, pyrazolium, pyrazolium derivatives, pyridinium, pyridinium derivatives, piperidinium, piperidinium derivatives, morpholinium, morpholinium derivatives, sulfonium, and sulfonium derivatives;

and at least one anion from the group;

hexafluorophosphate, hexafluoroantimonate, tetrafluoroborate, bis(trifluoromethylsulfonyl)imide, bis(fluorosulfonyl)imide, chloride, bromide, iodide, dicyanamide, acetate, methylcarbonate, methylsulfate, nitrate, tetrachloroaluminate, thiocyanate, trifluoromethanesulfonate, hydrogen carbonate, dibutylphosphate; and

wherein said dissolved lithium containing salt comprises lithium cations and at least one anion from the group;

hexafluorophosphate, hexafluoroantimonate, tetrafluoroborate, bis(trifluoromethylsulfonyl)imide, bis(fluorosulfonyl)imide, chloride, bromide, iodide, dicyanamide, acetate, methylcarbonate, methylsulfate, nitrate, tetrachloroaluminate, thiocyanate, trifluoromethanesulfonate, hydrogen carbonate, and dibutylphosphate.

20. The method of claim 17, wherein a second side of said electrolyte layer is fabricated in intimate contact across said second side of said electrolyte with a negative anode layer.

21. The method of claim 20, further comprising fabricating said negative anode layer by pressing against said second side of said electrolyte layer.

22. The method of claim 20, wherein said anode layer comprises a material from the group:

metallic lithium, metal or metallic alloy that does not alloy with metallic lithium or does only form a solid solution with metallic lithium, and lithium ion anode material that is capable of simultaneously storing lithium ions and electrons.

23. The method of claim 22, wherein said anode layer material further comprises a material from the group:

lithium-aluminum alloy, lithium-silicon alloy, lithium-tin alloy, lithium-zinc alloy, lithium-gallium alloy, lithium-indium alloy, lithium-germanium alloy, lithium-phosphorus alloy, lithium-arsenic alloy, lithium-antimony alloy, and lithium-bismuth alloy.

24. The method of claim 23, further comprising fabricating said lithium ion anode material by ball-milling, further comprising priming the walls of the ball-mill vessel with a film of metallic lithium powder.

25. The method of claim 17, further comprising soaking of a liquid electrolyte into the pores of said pressed cathode body and said electrolyte layer after said electrolyte layer has been attached to said pressed cathode body.

26. The method of claim 20, further comprising soaking of a liquid electrolyte into the pores of said pressed cathode body, into the pores of said electrolyte layer, and into the pores of said negative anode layer after said negative anode layer has been attached to said electrolyte layer.

27. The method of claim 1, wherein said positive cathode powder comprises a material from the group:

LiCoO₂, LiNiO₂, LiMnO₂, Li₂MnO₃, LiMn₂O₄, LiV₂O₄, LiFePO₄, MnO₂, V2O5, Ag₂V₄O₁₁, CFx (0.5<

x<

4), and any derivatives and combinations thereof.

28. The method of claim 8, wherein said main axis of said cathode powder particles is the longest distance across said particle.

29. The method of claim 1 wherein said cathode powder contains solid state electrolyte material.

30. The method of claim 29, wherein the energy density of said electrochemical cell is increased by increasing the lithium ion conductivity in said cathode and reducing said porosity to 5 vol %.

31. The method of claim 20, wherein said electrolyte layer is not in contact with said pressed cathode body.

32. The method of claim 31, further comprising soaking of a liquid electrolyte into the pores of said anode layer and said electrolyte layer.