COATED POROUS MATERIALS

• US 20130109262A1
• Filed: 05/11/2011
• Published: 05/02/2013
• Est. Priority Date: 06/01/2010
• Status: Abandoned Application

• Current Assignee: 3M Innovative Properties Company (3M Company)
• Original Assignee: 3M Innovative Properties Company (3M Company)
• Inventors: Zhou, Jinsheng
• Application Number:
  US13/699,405
• Publication Number:
  US 20130109262A1
• Time in Patent Office: Days
• US Class Current: 442/118
• CPC Class Codes: B01D 2323/02 Hydrophilization
• CPC Class Codes: B01D 2323/28 Pore treatments
• CPC Class Codes: B01D 2323/30 Cross-linking
• CPC Class Codes: B01D 2323/345 UV-treatment
• CPC Class Codes: B01D 2325/36 Hydrophilic membranes
• CPC Class Codes: B01D 67/0088 Physical treatment with compounds, e.g. swelling, coating or impregnation
• CPC Class Codes: B01D 69/1212 Coextruded layers
• CPC Class Codes: B01D 69/1213 Laminated layers
• CPC Class Codes: B01D 69/1216 Three or more layers
• CPC Class Codes: B01D 71/261 Polyethylene
• CPC Class Codes: B01D 71/262 Polypropylene
• CPC Class Codes: B01D 71/76 Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74 rubbers in general B01D71/24
• CPC Class Codes: B01J 20/28033 Membrane, sheet, cloth, pad, lamellar or mat
• CPC Class Codes: B01J 20/28038 Membranes or mats made from fibers or filaments
• CPC Class Codes: C09D 5/00 Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced electrically insulating plastics, resins or waxes H01B3/30; Filling pastes
• CPC Class Codes: Y10T 428/24273 including aperture
• CPC Class Codes: Y10T 442/2484 Coating or impregnation is water absorbency-increasing or hydrophilicity-increasing or hydrophilicity-imparting

Abstract

A coated porous material and a method for making the same. The coated porous material includes a porous substrate having a plurality of pores. A hydrophilic coating including, in a single layer, ethylene vinyl alcohol copolymer and at least one crosslinked polymer, is present on a plurality of inner pore walls. The method includes: (a) providing a porous substrate; (b) applying a coatable composition to at least a portion of the inner pore walls of the porous substrate, the coatable composition made of ethylene vinyl alcohol copolymer, at least one polymerizable compound and solvent; (c) removing at least a portion of the solvent from the coatable composition to dry the coatable composition; (d) saturating the porous substrate and the coatable composition with a rewetting solution; and (e) polymerizing the polymerizable compound to form the hydrophilic coating on the pore walls and to provide the coated porous material.

Claims

1. A coated porous material comprising:

a) a porous substrate comprising a plurality of pores extending through the substrate from a first major surface to a second major surface, each pore comprising an inner pore wall defining the internal dimension of the pore; and

b) a hydrophilic coating on a plurality of the pore walls, the hydrophilic coating comprising ethylene vinyl alcohol copolymer and at least one crosslinked polymer in a single layer;

wherein the hydrophilic coating comprises an interpenetrating polymer network of ethylene vinyl alcohol copolymer and the crosslinked polymer.

2. The coated porous material of claim 1 wherein the porous substrate is a membrane comprising at least one polymer material.

4. The coated porous material of claim 2 wherein the polymer material is selected from the group consisting of ethylene chlorotrifluoroethylene, polytetrafluoroethylene, polysulfone, poly(ether)sulfone, polyolefins, polyvinylidene fluoride, polyamide, cellulose ester and combinations of two or more of the foregoing.

5. The coated porous material of claim 1 wherein the porous substrate comprises material selected from the group consisting of nonwoven material, woven material, knitted material.

6. The coated porous material of claim 1 wherein the at least one crosslinked polymer is derived from monomers selected from the group consisting of polyethylene glycol diacrylate, polyethylene glycol dimethacrylate and combinations thereof.

7. The coated porous material of claim 6 wherein the monomers are of a molecular weight greater than about 400.

8. The coated porous material of claim 6 wherein the at least one crosslinked polymer is derived from a reaction between one or more of the monomers and at least one crosslinking agent.

3. (canceled)

9. (canceled)

10. A process for the preparation of a coated porous material, the process comprising:

(a) providing a porous substrate comprising a plurality of pores extending through the substrate from a first major surface to a second major surface, each pore comprising an inner pore wall defining the internal dimension of the pore;

(b) applying a coatable composition to at least a portion of the inner pore walls of the porous substrate, the coatable composition comprising ethylene vinyl alcohol copolymer, at least one polymerizable compound and solvent;

(c) removing at least a portion of the solvent from the coatable composition to dry the coatable composition;

(d) saturating the porous substrate and the coatable composition with a rewetting solution; and

(e) polymerizing the polymerizable compound to form a hydrophilic coating on the pore walls and to provide the coated porous material, the hydrophilic coating comprising both the ethylene vinyl alcohol copolymer and a crosslinked polymer in a single layer;

wherein the step (e) of polymerizing the polymerizable compound results in the hydrophilic coating comprising both the ethylene vinyl alcohol copolymer and a crosslinked polymer in an interpenetrating polymer network.

11. The process of claim 10 further comprising partially polymerizing the polymerizable compound in the coatable composition either before or after the step (b) of applying the coatable composition to at least a portion of the inner pore walls:

12. The process of claim 11 wherein the step of partially polymerizing the polymerizable compound comprises thermally initiating a polymerization reaction in the coatable composition to partially polymerize the polymerizable compound before the step (b) of applying the coatable composition to at least a portion of the inner pore walls.

13. The process of claim 11 wherein the step of partially polymerizing the polymerizable compound comprises photo-initiating a polymerization reaction in the coatable composition to partially polymerize the polymerizable compound after the step (b) of applying the coatable composition to at least a portion of the inner pore walls.

14. The process of claim 10, further comprising preparing the coatable composition prior to coating the pore walls therewith, the coatable composition prepared by combining the ethylene vinyl alcohol copolymer and the at least one polymerizable compound in a solvent.

15. The process of claim 14 wherein the at least one polymerizable compound comprises monomer selected from polyethylene glycol diacrylate, polyethylene glycol dimethacrylate and combinations thereof.

16. The process of claim 14 wherein the at least one monomer is initially of a molecular weight greater than about 400.

20. The process of claim 10 wherein the coatable composition further comprises at least one crosslinking agent and photoinitiator and wherein removing at least a portion of the solvent from the coatable composition and the porous substrate to dry the coatable composition is accomplished by evaporating the solvent.

21. The process of claim 20 wherein the rewetting solution comprises a solution of sodium chloride, and step (e) of polymerizing the polymerizable compound comprises photo-polymerizing the at least one polymerizable compound using ultraviolet radiation.

22. The process of claim 20 wherein the photoinitiator comprises a reactive material comprising 2-[4-(2-hydroxy-2-methylpropanoyl)phenoxy]ethyl-2-methyl-2-N-propenoylamino propanoate.

24. The process of claim 10 wherein the porous substrate is a membrane.

25. The process of claim 24 wherein the membrane comprises material selected from the group consisting of poly(ether)sulfone, polyolefins, polyvinylidene fluoride, polyamide, cellulose ester and combinations of two or more of the foregoing.

26. The process of claim 10 wherein the porous substrate comprises fibrous material selected from the group consisting of nonwoven material, woven material and knitted material.

17. (canceled)

18. (canceled)

19. (canceled)

23. (canceled)

27. (canceled)