Self-Degrading High Temperature Stable Gel for Downhole Applications

• US 20130118744A1
• Filed: 12/21/2012
• Published: 05/16/2013
• Est. Priority Date: 11/16/2011
• Status: Abandoned Application

• Current Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Original Assignee: Halliburton Energy Services Incorporated (Halliburton Company)
• Inventors: Deville, Jay P., GAMAGE, Pubudu H.
• Application Number:
  US13/725,968
• Publication Number:
  US 20130118744A1
• Time in Patent Office: Days
• US Class Current: 166/293
• CPC Class Codes: C09K 8/00 Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
• CPC Class Codes: C09K 8/5083 obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C09K 8/512 containing cross-linking agents
• CPC Class Codes: C09K 8/685 containing cross-linking agents
• CPC Class Codes: C09K 8/882 obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: C09K 8/887 containing cross-linking agents
• CPC Class Codes: E21B 33/13 Methods or devices for cementing, for plugging holes, crevices or the like

Abstract

A method of treating a subterranean formation including providing a treatment fluid comprising an aqueous carrier fluid, a crosslinking agent, a pH-adjusting agent, and a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or any salt thereof, where the treatment fluid does not include any gel stabilizers, or only minimal amounts of gel stabilizers. The treatment fluid is introduced into a subterranean formation and is allowed to form a gel in the subterranean formation. The gel is broken, without using an external breaker, after the gel has been in the subterranean formation for at least about one day.

Claims

1. A method comprising:

providing a treatment fluid comprising an aqueous carrier fluid, a crosslinking agent, a pH-adjusting agent, and a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or any salt thereof, with the proviso that the treatment fluid does not include any gel stabilizers;

introducing the treatment fluid into a subterranean formation;

allowing the treatment fluid to form a gel in the subterranean formation; and

allowing the gel to break, without using an external breaker, after the gel has been in the subterranean formation for at least about one day.

2. The method of claim 1, wherein the subterranean formation is at a temperature ranging between about 275°

F. and about 350°

F.

3. The method of claim 1, wherein the gel comprises a crosslinked gel that, after formation, at least partially blocks the flow of formation fluids from at least a portion of the subterranean formation.

4. The method of claim 1, wherein the gel comprises a crosslinked gel that, after formation, substantially blocks the flow of formation fluids from the subterranean formation.

5. The method of claim 1, wherein the aqueous carrier fluid is present in the amount of from about 85% to about 98.4% by volume of the treatment fluid.

6. The method of claim 1, wherein the crosslinking agent is present in the amount of from about 0.1% to about 5% by volume of the treatment fluid.

7. The method of claim 1, wherein the terpolymer is present in the amount of from about 1% to about 10% by volume of the treatment fluid.

8. The method of claim 1, wherein the pH-adjusting agent is present in the amount of from about 0.5% to about 5% by volume of the treatment fluid.

9. A method comprising:

providing a treatment fluid comprising an aqueous carrier fluid, a crosslinking agent, a pH-adjusting agent, a gel stabilizer present in the amount of less than about 0.05% by volume of the treatment fluid, and a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or any salt thereof;

introducing the treatment fluid into a subterranean formation;

allowing the treatment fluid to form a crosslinked gel in the subterranean formation that, after formation, at least partially blocks the flow of formation fluids from at least a portion of the subterranean formation; and

allowing the crosslinked gel to break, without using an external breaker, after it has been in the subterranean formation for at least about one day.

10. The method of claim 9, wherein the gel comprises a crosslinked gel that, after formation, substantially blocks the flow of formation fluids from the subterranean formation.

11. The method of claim 9, wherein the gel stabilizer is present in the amount of about 0% by volume of the treatment fluid.

12. The method of claim 9, wherein the subterranean formation is at a temperature ranging between about 175°

F. and about 350°

F.

13. The method of claim 9, wherein the treatment fluid has a pH ranging between about 1 and about 5.

14. The method of claim 9, wherein the aqueous carrier fluid is present in the amount of from about 85% to about 98.4% by volume of the treatment fluid, the crosslinking agent is present in the amount of from about 0.1% to about 5% by volume of the treatment fluid, the terpolymer is present in the amount of from about 1% to about 10% by volume of the treatment fluid, and the pH-adjusting agent is present in the amount of from about 0.5% to about 5% by volume of the treatment fluid.

15. The method of claim 9, wherein the crosslinked gels keep their integrity for at least about 3 days when used in a subterranean formation having a temperature of up to about 350°

F.

16. The method of claim 9, wherein the crosslinked gels keep their integrity for at least about 6 days when used in a subterranean formation having a temperature of up to about 320°

F.

17. The method of claim 9, wherein the crosslinked gels essentially fully degrade in at least about 6 days when used in a subterranean formation having a temperature of up to about 350°

F.

18. A treatment fluid comprising:

an aqueous carrier fluid present in the amount of from about 85% to about 98.4% by volume of the treatment fluid;

a terpolymer that comprises 2-acrylamido-2-methylpropanesulfonic acid, acrylamide, and acrylic acid monomer units, or any salt thereof, present in the amount of from about 1% to about 10% by volume of the treatment fluid;

a crosslinking agent capable of crosslinking the terpolymer, present in the amount of from about 0.1% to about 5% by volume of the treatment fluid;

a pH-adjusting agent present in the amount of from about 0.5% to about 5% by volume of the treatment fluid, and

a gel stabilizer present in the amount of less than about 0.05% by volume of the treatment fluid.

19. The treatment fluid of claim 18, wherein the treatment fluid can undergo gellation at a temperature ranging between about 275°

F. and about 350°

F.

20. The treatment fluid of claim 18, wherein the amount of gel stabilizer is about 0% by volume of the treatment fluid.