Process For Producing Ethanol From Impure Methanol

• US 20130172633A1
• Filed: 08/23/2012
• Published: 07/04/2013
• Est. Priority Date: 12/29/2011
• Status: Abandoned Application

• Current Assignee: Celanese International Corporation (Celanese Corporation)
• Original Assignee: Celanese International Corporation (Celanese Corporation)
• Inventors: Scates, Mark O., Zink, James H.
• Application Number:
  US13/592,829
• Publication Number:
  US 20130172633A1
• Time in Patent Office: Days
• US Class Current: 568/885
• CPC Class Codes: C07C 29/149 with hydrogen or hydrogen-containing gases
• CPC Class Codes: C07C 31/08 Ethanol
• CPC Class Codes: C07C 51/12 on an oxygen-containing group in organic compounds, e.g. alcohols
• CPC Class Codes: C07C 53/08 Acetic acid pyroligneous acid C10C; preparation of vinegar C12J
• CPC Class Codes: Y02P 20/582 Recycling of unreacted starting or intermediate materials

Abstract

In a first embodiment, the present invention relates to a process for producing ethanol. The process comprises the step of contacting a carbon monoxide feed and an impure methanol feed in a reactor under conditions effective to produce a crude acetic acid product. The impure methanol feed comprises more than 0.15 wt. % of impurities. The process further comprises the step of separating the crude acetic acid product to form an intermediate acetic acid product and at least one derivative stream. The intermediate acetic acid product may comprise acetic acid and at least one of the impurities from the impure methanol feed. The process further comprises the step of hydrogenating at least a portion of the intermediate acetic acid product to produce a crude ethanol product. The hydrogenation is preferably conducted over a catalyst.

Claims

1. A process for producing ethanol, comprising the steps of:

(a) contacting in a reactor under conditions effective to produce a crude acetic acid product;

(i) a carbon monoxide feed; and

(ii) an impure methanol feed comprising more than 0.15 wt. % of impurities;

(b) separating the crude acetic acid product to form an intermediate acetic acid product comprising acetic acid; and

(c) hydrogenating at least a portion of the intermediate acetic acid product over a catalyst and under conditions effective to produce a crude ethanol product.

2. The process of claim 1, wherein the impure methanol feed comprises impurities selected from the group consisting of organic impurities, chlorine-containing compounds, sulfur-containing compounds, and nitrogen-containing compounds.

3. The process of claim 1, wherein the impure methanol feed comprises impurities that are hydrocarbons having more than two carbon atoms and not being selected from the group consisting of methyl acetate, dimethyl ether, or methyl formate.

4. The process of claim 1, wherein the intermediate acetic acid product further comprises at least one of the impurities from the impure methanol feed.

5. The process of claim 1, wherein the intermediate acetic acid product further comprises by-products formed in step (a).

6. The process of claim 5, wherein the by-products comprise by-products derived from the impurities.

7. The process of claim 1, wherein the intermediate acetic acid product further comprises water in an amount from 0.15 wt. % to 25 wt. %.

8. The process of claim 1, wherein the intermediate acetic acid product further comprises water in an amount less than 1500 wppm.

9. The process of claim 1, wherein the intermediate acetic acid product comprises from 0.01 to 10 wt. % methyl acetate.

10. The process of claim 1, wherein the crude ethanol product comprises from 5 wt. % to 72 wt. % ethanol and from 5 wt. % to 40 wt. % water.

11. The process of claim 1, wherein the carbon monoxide feed comprises from 10 wt % to 99.99 wt % carbon monoxide.

12. The process of claim 1, wherein the carbon monoxide feed comprises from 10 wt % to 99.5 wt % carbon monoxide.

13. The process of claim 1, further comprises the step of purifying the intermediate acetic acid product to yield a purified acetic acid product.

14. The process of claim 13, wherein step (c) is performed in a reaction zone and wherein the purified acetic acid product is fed directly to the reaction zone without removing substantially any water therefrom.

15. The process of claim 1, wherein at least one of the methanol, the carbon monoxide, and hydrogen for the hydrogenating step is derived from syngas, and wherein the syngas is derived from a carbon source selected from the group consisting of natural gas, oil, petroleum, coal, biomass, and combinations thereof.

16. The process of claim 1, wherein the intermediate acetic acid product is a sidedraw from a light ends column of a carbonylation process.

17. The process of claim 1, further comprising the steps of:

separating in a first column at least a portion of the crude ethanol product into a first distillate comprising ethanol, water and ethyl acetate, and a first residue comprising acetic acid;

separating in a second column at least a portion of the first distillate into a second distillate comprising ethyl acetate and a second residue comprising ethanol and water;

separating in a third column at least a portion of the second residue into a third distillate comprising ethanol and residual water and a third residue comprising separated water; and

dehydrating at least a portion of the third distillate to form the anhydrous ethanol composition comprising, as formed, less than 1 wt. % water, based on the total weight of the anhydrous ethanol composition.

18. The process of claim 1, further comprising the steps of:

separating at least a portion of the crude ethanol product in a first distillation column to yield a first residue comprising acetic acid and a first distillate comprising ethanol, ethyl acetate, and water;

removing water from at least a portion of the first distillate to yield an ethanol mixture stream comprising less than 10 wt. % water; and

separating a portion of the ethanol mixture stream in a second distillation column to yield a second residue comprising ethanol and a second distillate comprising ethyl acetate.

19. The process of claim 1, further comprising the steps of:

separating a portion of the crude ethanol product in a first distillation column to yield a first distillate comprising ethyl acetate and acetaldehyde, and a first residue comprising ethanol, ethyl acetate, acetic acid and water;

separating a portion of the first residue in a second distillation column to yield a second residue comprising acetic acid and water and a second distillate comprising ethanol and ethyl acetate; and

separating a portion of the second distillate in a third distillation column to yield a third residue comprising ethanol and a third distillate comprising ethyl acetate.