ESTIMATING AND DISPLAYING MOLECULAR SIZE INFORMATION OF A SUBSTANCE

• US 20130187648A1
• Filed: 01/24/2012
• Published: 07/25/2013
• Est. Priority Date: 01/24/2012
• Status: Active Grant

• Current Assignee: Schlumberger Technology Corporation (SLB)
• Original Assignee: Denise E. Freed, Yi-Qiao Song
• Inventors: FREED, DENISE E., SONG, YI-QIAO, ZIELINSKI, LUKASZ J., DONALDSON, MARCUS
• Granted Patent: US 9,201,158 B2
• Time in Patent Office: Days
• US Class Current: 324/303
• CPC Class Codes: G01N 24/081 Making measurements of geologic samples, e.g. measurements of moisture, pH, porosity, permeability, tortuosity or viscosity
• CPC Class Codes: G01R 33/448 Relaxometry, i.e. quantification of relaxation times or spin density G01R33/50 takes precedence
• CPC Class Codes: G01V 3/32 operating with electron or nuclear magnetic resonance

Abstract

Estimating and displaying information about the size of molecules within a substance from nuclear magnetic resonance (NMR) maps and/or logs. Methods include utilizing a relationship between the molecular size (e.g., mean chain length), and either a moment of diffusion or a relaxation distribution, to create a scale on a two-dimensional map. In one case, applying the relationship between the molecular size, and either a moment of diffusion or a relaxation distribution, to one-dimensional diffusion or relaxation distributions for the purpose of estimating the mean chain length of molecules within the substance. In another case, a method includes determining mean chain lengths of molecules within a substance and providing a one-dimensional NMR log showing the mean chain lengths at a plurality of depths. In some cases, the NMR log includes actuatable regions for examining two-dimensional NMR maps or chain length distributions of the substance corresponding with distinct depths of the substance.

Claims

1. A method comprising:

determining a mean chain length scale on a nuclear magnetic resonance (NMR) map of molecules within a substance; and

generating a size estimate of the molecules within the substance using the mean chain-length scale and the NMR map.

2. The method of claim 1, further comprising plotting the NMR map along with the mean chain-length scale.

3. The method of claim 2, further comprising providing the NMR map along with the mean chain-length scale for display.

4. The method of claim 3, wherein the mean chain length scale is visually perceivable on the NMR map.

5. The method of claim 1, wherein the NMR map includes a two-dimensional (2D) map.

6. The method of claim 5, wherein the 2D map includes at least one of a diffusion-relaxation or a relaxation-relaxation map.

7. The method of claim 1, wherein the NMR map includes a one-dimensional (1D) distribution plot.

8. The method of claim 1, wherein the NMR map is based upon data about the substance obtained during one of a logging-while-drilling (LWD) or a wireline drilling application.

9. The method of claim 1, wherein the substance includes at least one of:

an oil, a gas or an oil-based mud.

10. The method of claim 1, wherein the size estimate of the molecules is selected from the group consisting of:

a mean chain length of the molecules, a hydrodynamic radius of the molecules and a hydrocarbon number of the molecules.

11. A method comprising:

determining a molecular size of molecules within a substance based upon nuclear magnetic resonance (NMR) signals for the substance in-situ;

generating a plot of the molecular size of the molecules within the substance as a function of a depth of the substance; and

providing the plot for display.

12. The method of claim 11, wherein the determining of the molecular size of the molecules within the substance includes calculating the molecular size from at least one of a diffusion measurement or a relaxation measurement of the substance using the NMR signals.

13. The method of claim 12, further comprising determining a fluid volume within the substance from the at least one of the diffusion measurement or the relaxation measurement.

14. The method of claim 13, wherein an intensity of the plot varies based upon the fluid volume of the substance at a corresponding depth.

15. The method of claim 11, wherein the NMR signals include NMR signals corresponding to at least one of:

an oil, a gas or an oil-based mud, and wherein the determining includes determining a mean chain-length of the molecules within at least one of;

the oil, the gas or the oil-based mud.

16. The method of claim 11, further comprising:

obtaining the NMR signals during one of a logging-while-drilling (LWR) or a wireline drilling process; and

providing the plot for display during the one of the LWR or the wireline drilling process.

17. The method of claim 11, wherein the substance includes a crude oil.

18. The method of claim 17, wherein the substance further includes at least one of gas, water or oil-based mud.

19. The method of claim 18, further comprising separating NMR signals relating to the oil from NMR signals relating to the gas and the water before determining the molecular size of molecules within the oil using the NMR signals relating to the oil.

20. The method of claim 19, wherein the separating of the NMR signals relating to the oil and the NMR signals relating to the gas and the water is performed using an NMR map.

21. The method of claim 11, wherein the molecular size of the molecules is selected from the group consisting of:

a mean chain length of the molecules, a chain length distribution of the molecules, a binned molecular size distribution of the molecules, a hydrodynamic radius of the molecules and a hydrocarbon number of the molecules.

22. A method for determining a characteristic of a substance in-situ, the method comprising:

obtaining nuclear magnetic resonance (NMR) signals about the substance;

calculating a mean chain-length of molecules within the substance based upon the NMR signals; and

providing a one-dimensional (1D) nuclear magnetic resonance (NMR) log representing a calculated mean chain length of the molecules within the substance at a plurality of depths of the substance, and

wherein the one-dimensional NMR log includes an actuatable region at each of the plurality of depths for providing at least one of a two-dimensional (2D) NMR map of the substance or a chain length distribution of the substance at the each of the plurality of depths.

23. The method of claim 22, further comprising displaying the at least one of the 2D NMR map or the chain length distribution of the substance at the selected depth in response to actuation of the actuatable region at the selected depth.

24. The method of claim 22, wherein the obtaining includes detecting the NMR signals during one of a logging-while-drilling (LWD) or a wireline drilling application.

25. The method of claim 24, wherein the NMR signals include NMR signals from at least one of:

an oil, a gas or an oil-based mud.

26. The method of claim 25, wherein the calculating includes calculating the mean chain length of the molecules for the at least one of the oil, the gas or the oil-based mud.

27. The method of claim 22, wherein the actuatable region includes at least one of an actuatable button or an icon for initiating the providing of the at least one of the two-dimensional (2D) NMR map or the chain length distribution.

28. The method of claim 22, wherein the 2D NMR map includes a mean chain length scale for generating a size estimate of the molecules within the substance.