Method for Identifying an Object

• US 20130193346A1
• Filed: 02/09/2011
• Published: 08/01/2013
• Est. Priority Date: 02/10/2010
• Status: Abandoned Application

• Current Assignee: Tailorlux GmbH
• Original Assignee: Tailorlux GmbH
• Inventors: Uhlich, Dominik, Bettentrup, Helga, Jstel, Thomas, Deitermann, Alex, Rtter, Sebastian
• Application Number:
  US13/578,285
• Publication Number:
  US 20130193346A1
• Time in Patent Office: Days
• US Class Current: 250/459.1
• CPC Class Codes: C09K 11/08 containing inorganic luminescent materials
• CPC Class Codes: C09K 11/7733 with alkali or alkaline earth metals
• CPC Class Codes: C09K 11/7751 Vanadates; Chromates; Molybdates; Tungstates
• CPC Class Codes: C09K 11/7764 Aluminates; Silicates
• CPC Class Codes: C09K 11/7773 with alkali or alkaline earth metal
• CPC Class Codes: C09K 11/7774 Aluminates
• CPC Class Codes: C09K 11/778 Borates
• CPC Class Codes: C09K 11/7792 Aluminates
• CPC Class Codes: G01N 2021/6441 with two or more labels
• CPC Class Codes: G01N 21/64 Fluorescence; Phosphorescence
• CPC Class Codes: G07D 7/003 using security elements using digital security elements G07D7/004
• CPC Class Codes: G07D 7/1205 Testing spectral properties

Abstract

The invention relates to a method for identifying an object, wherein said object has a security element, which contains one or more inorganic luminescent pigments, wherein the method comprises the steps of producing an emission spectrum of the luminescent pigment and comparing the obtained emission spectrum with the spectrum specified for the security element. The invention further relates to a security element, by means of which it is possible to determine the authenticity of a product in a simple manner.

Claims

1. Method for identifying an object, wherein the object comprises a security element which contains one or several inorganic luminescent pigments, whose emission spectrum/emission spectra change as a function of the energy of the exciting electromagnetic radiation, the temperature, the time after action of the excitation pulse or the ambient pressure, the method comprising the steps of

generating at least 2 emission spectra of the luminescent pigment, wherein these spectra can be obtained with excitation pulses that are different from each other and/or as a function of the time, i.e., time intervals from action of the excitation pulse and/or change of the ambient pressure,

comparing the obtained emission spectra with spectra predetermined for the luminescent pigment.

4. Method according to claim 1, wherein the luminescent pigment is an inorganic solid state compound, that contains one or several luminescent ions from the group of In⁺, Sn²⁺, Pb²⁺, Sb³⁺, Bi³⁺, Ce³⁺, Ce⁴⁺, Pr³⁺, Nd³⁺, Sm²⁺, Sm³⁺, Eu²⁺, Eu³⁺, Gd³⁺, Tb³⁺, Dy³⁺, Ho³⁺, Er³⁺, Tm²⁺, Tm³⁺, Yb²⁺, Yb³⁺, Ti³⁺, V²⁺, V³⁺, V⁴⁺, Cr³⁺, Mn²⁺, Mn³⁺, Mn⁴⁺, Fe³⁺, Fe⁴⁺, Fe⁵⁺, Co³⁺, Co⁴⁺, Ni²⁺, Cu⁺, Ru²⁺, Ru³⁺, Pd²⁺, Ag⁺, Ir³⁺, Pt²⁺ and Au⁺.

5. Method according to claim 1, wherein the luminescent pigment is a binary, ternary or quaternary halogenide, oxide, oxyhalogenide, sulfide, oxysulfide, sulfate, oxysulfate, selenide, nitride, oxynitnde, nitrate, oxynitrate, phosphide, phosphate, carbonate, silicate, oxysilicate, vanadate, molybdate, tungstenate, germanate or oxygermanate of the elements Li, Na, K, Rb, Mg, Ca, Sr, Sc, Y, La, Ti, Zr, Hf, Nb, Ta, Zn, Gd, Lu, Al, Ga and In.

6. Method according to claim 1, wherein the inorganic luminescent pigment is introduced into a UV-transparent matrix.

7. Method according to claim 6, wherein the UV-transparent matrix is a photonic matrix, such as an inverse opal.

8. Method according to claim 1. wherein the luminescent pigment has a mean particle size between 1 nm and 1,000 μ

m.

9. Method according to claim 1, wherein the change of the emission spectrum of the security element is based on the modulation of the excitation energy and/or a temporally modulated excitation or emission and/or a thermally modulated excitation or emission and/or a pressure-modulated excitation or emission of the luminescent pigments.

10. Method according to claim 1, based on one or several combinations of the modulated excitation or emission by the emission spectrum, by temporally, thermally, pressure-based or excitation energy-based modulated excitation or emission of luminescent pigments.

2. (canceled)

3. (canceled)

11. Security element with concealed or open security feature for its identification, which contains one or several inorganic luminescent pigments, wherein for each luminescent pigment at least one emission spectrum can be generated as a function of the spectral excitation energy, the temperature, the time after action of the excitation pulse or the ambient pressure, wherein at least two emission spectra different from each other are generated.

12. Security element according to claim 11 in which at least two luminescent pigments are used.

13. Use of the security element according to claim 11 for the identification of products.

14. Use according to claim 13, wherein the products are plastics, building materials, rubber materials, color varnishes, raw paper materials, specialty glasses, ceramic products and ceramic materials, explosives, adhesives, papers including documents of value and security documents such a banknotes and securities, credit cards, cash cards, identification cards, passport documents, charge cards, documents, stamps, tickets, audio and video media, packaging, cast metal, aluminum, chemicals, glass, textiles, synthetic and natural fibers, fabrics and laid fabrics (nonwovens), wood, surface coatings, ceramics, plants and animals, as well as products made therefrom, including fibers, leather, fabrics and laid fabrics, electronics, composite materials, fuels and oils, sinter materials, cosmetics, pharmaceutical products and devices.

15. Device for identifying an object which comprises

means for generating an excitation pulse,

a detector for recording an emission spectrum.

16. Device according to claim 15, wherein it has means for reproducing the emission spectrum.

17. Device according to claim 15, wherein it has means for comparing the recorded emission spectrum with a predetermined spectrum.

18. Device according to claim 15, wherein it is connected with a device which has means for reproducing the emission spectrum and/or means for comparing the recorded emission spectrum with a predetermined spectrum.