METHOD OF MAKING COATED ARTICLE INCLUDING ANTI-REFLECTION COATING WITH DOUBLE COATING LAYERS INCLUDING MESOPOROUS MATERIALS, AND PRODUCTS CONTAINING THE SAME

• US 20130194668A1
• Filed: 12/13/2012
• Published: 08/01/2013
• Est. Priority Date: 01/30/2012
• Status: Abandoned Application

• Current Assignee: Guardian Glass LLC (KOCH Industries Incorporated)
• Original Assignee: Guardian Industries Corporation (KOCH Industries Incorporated)
• Inventors: LIANG, Liang, BLACKER, Richard, LEWIS, Mark A., KALYANKAR, Nikhil, LE, Minh Huu
• Application Number:
  US13/713,811
• Publication Number:
  US 20130194668A1
• Time in Patent Office: Days
• US Class Current: 359/586
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: B82Y 40/00 Manufacture or treatment of nanostructures
• CPC Class Codes: C03C 1/008 for the production of films or coatings
• CPC Class Codes: C03C 17/22 with other inorganic material C03C17/34, C03C17/44 take precedence
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2217/213 SiO2
• CPC Class Codes: C03C 2217/425 consisting of a porous layer
• CPC Class Codes: C03C 2217/452 Glass
• CPC Class Codes: C03C 2217/465 having a specific shape
• CPC Class Codes: C03C 2217/478 Silica
• CPC Class Codes: C03C 2217/73 Anti-reflective coatings with specific characteristics
• CPC Class Codes: C03C 2217/732 made of a single layer
• CPC Class Codes: C03C 2217/91 Coatings containing at least one layer having a composition gradient through its thickness
• CPC Class Codes: C03C 2218/113 by sol-gel processes
• CPC Class Codes: C03C 2218/116 by spin-coating, centrifugation
• CPC Class Codes: G02B 1/115 Multilayers
• CPC Class Codes: G02B 2207/107 Porous materials, e.g. for reducing the refractive index
• CPC Class Codes: Y10S 977/773 Nanoparticle, i.e. structure having three dimensions of 100 nm or less

Abstract

Certain examples relate to a method of making an antireflective (AR) coating supported by a glass substrate. The anti-reflection coating may include porous metal oxide(s) and/or silica, and may be produced using a sol-gel process. The pores may be formed and/or tuned in each layer respectively in such a manner that the coating ultimately may comprise a porous matrix, graded with respect to porosity. The gradient in porosity may be achieved by forming first and second layers using one or more of (a) nanoparticles of different shapes and/or sizes, (b) porous nanoparticles having varying pore sizes, and/or (c) compounds/materials of various types, sizes, and shapes that may ultimately be removed from the coating post-deposition (e.g., carbon structures, micelles, etc., removed through combustion, calcination, ozonolysis, solvent-extraction, etc.), leaving spaces where the removed materials were previously located.

Claims

1. A method of making an anti-reflection coating, the method comprising:

forming a first intermediate layer on a glass substrate by wet-applying a sol comprising at least silica and a surfactant on a glass substrate;

initially heating the glass substrate with the first intermediate layer thereon to a first temperature, and subsequently heating the glass substrate with the first intermediate layer thereon to a second temperature, wherein the second temperature is higher than the first temperature;

forming a second intermediate layer by wet-applying a sol comprising nanoparticles over and contacting the first intermediate layer; and

curing the first and second intermediate layers so as to form an anti-reflection coating comprising at least first and second layers having first and second porosities from the first and second intermediate layers, respectively,

wherein the second porosity is greater than the first porosity.

2. The method of claim 1, wherein the porosity of the first layer arises from vacancies left by micelles that are removed during the initial and/or subsequent heating.

3. The method of claim 1, wherein the porosity of the second layer arises from spaces between the nanoparticles.

4. The method of claim 1, wherein the nanoparticles comprise silica nanoparticles.

5. The method of claim 4, wherein the silica nanoparticles have an elongated shape.

6. The method of claim 5, wherein the elongated silica nanoparticles have a diameter of from about 4 to 15 nm and a length of from about 40 to 100 nm.

7. The method of claim 1, wherein the surfactant is a cationic surfactant.

8. The method of claim 7, wherein the cationic surfactant comprises cetyltrimethylammonium chloride (CTAC).

9. The method of claim 1, wherein the nanoparticles comprise elongated silica nanoparticles having a diameter of from about 4 to 15 nm and a length of from about 40 to 100 nm, and the surfactant is a cationic surfactant comprising cetyltrimethylammonium chloride (CTAC).

10. The method of claim 1, wherein the surfactant is a non-ionic polymer surfactant.

11. The method of claim 10, wherein the non-ionic polymer surfactant comprises polyethylene-polypropylene-polyethylene.

12. The method of claim 1, wherein the nanoparticles comprise elongated silica nanoparticles having a diameter of from about 4 to 15 nm and a length of from about 40 to 100 nm, and the surfactant is a non-ionic polymer surfactant comprising polyethylene-polypropylene-polyethylene.

13. The method of claim 9, wherein a refractive index of the first layer is from about 1.39 to 1.49, and a refractive index of the second layer is from about 1.27 to 1.37.

14. The method of claim 12, wherein a refractive index of the first layer is from about 1.39 to 1.49, and a refractive index of the second layer is from about 1.27 to 1.37.

15. The method of claim 13, wherein the refractive index of the first layer is from about 1.42 to 1.46, and the refractive index of the second layer is from about 1.30 to 1.35.

16. The method of claim 14, wherein the refractive index of the first layer is from about 1.42 to 1.46, and the refractive index of the second layer is from about 1.30 to 1.35.

17. The method of claim 1, wherein an average broadband (400-1200 nm) Tqe % gain as compared to an uncoated glass substrate is at least about 3.0%.

18. The method of claim 17, wherein the Tqe % gain as compared to an uncoated glass substrate is at least about 3.2%.

19. The method of claim 18, wherein the Tqe % gain as compared to an uncoated glass substrate is at least about 3.4%.

20. The method of claim 9, wherein an average broadband (400-1200 nm) Tqe % gain as compared to an uncoated glass substrate is at least about 3.3%.

21. The method of claim 12, wherein an average broadband (400-1200 nm) Tqe % gain as compared to an uncoated glass substrate is at least about 3.3%.

22. A coated article comprising:

a glass substrate; and

an anti-reflection coating disposed over the glass substrate, the anti-reflection coating comprising first and second layers, the first layer having a first porosity and the second layer having a second porosity,

wherein the first layer comprises mesoporous silica, and has a refractive index of from about 1.39 to 1.49, and the second layer comprises elongated nanoparticles comprising silica and has a refractive index of from about 1.27 to 1.37,

wherein the second porosity is greater than the first porosity, and

wherein an average broadband (400-1200 nm) Tqe % gain as compared to an uncoated glass substrate is at least about 3.0%.