THERMALLY CONDUCTIVE AND DIMENSIONALLY STABLE LIQUID CRYSTALLINE POLYMER COMPOSITION

• US 20130200297A1
• Filed: 02/18/2011
• Published: 08/08/2013
• Est. Priority Date: 02/25/2010
• Status: Abandoned Application

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Saga, Yuji
• Application Number:
  US13/579,720
• Publication Number:
  US 20130200297A1
• Time in Patent Office: Days
• US Class Current: 252/74
• CPC Class Codes: C09K 19/3809 Polyesters; Polyester derivatives, e.g. polyamides
• CPC Class Codes: C09K 19/52 characterised by components which are not liquid crystals, e.g. additives with special physical aspect: solvents, solid particles
• CPC Class Codes: C09K 5/14 Solid materials, e.g. powdery or granular
• CPC Class Codes: H05K 7/20481 characterised by the material composition exhibiting specific thermal properties

Abstract

A thermally conductive polymer composition is disclosed including liquid crystalline polymer; graphite, talc and low aspect fibrous filler. The composition has a thermal conductivity of at least about 3 W/m·K.

Claims

1. A thermally conductive polymer composition, comprising:

(a) less than 44 weight percent of at least one liquid crystalline polymer;

(b) about 10 to about 40 weight percent of graphite flake,

(c) about 10 to about 35 weight percent of talc having an average particle size between 10 μ

m and 100 μ

m,

(d) about 6 to about 25 weight percent of fibrous filler having an aspect ratio of between 3 and 20,

wherein the ratio of (b) to (c) is between 30 to 70 and 80 to 20 by weight percent, and wherein the weight percentages are based on the total volume of the composition, and wherein the composition has a thermal conductivity of at least about 3 W/m·

K.

2. The composition of claim 1, wherein fibrous filler (d) is at least one selected from the group consisting of glass fibers, wallastonites, titanium oxide fiber, alumina fibers, boron fibers, potassium titanate whiskers, calcium titanate whiskers, aluminum borate whiskers and zinc oxide whiskers, magnesium sulfate whiskers, sepiolite whiskers, xonotolite fibers, and silicon nitride fibers.

3. The composition of claim 1, wherein fibrous filler (d) is glass fibers.

4. The composition of claim 1, wherein the graphite flake (b) has an average particle size of 30 μ

m at least.

5. The composition of claim 1, wherein the graphite flake (b) has an average particle size of 50 μ

m at least.

6. The composition of claim 1, wherein the liquid crystalline polymer (a) is comprising one derived from:

(1) diacid residues consisting essentially of;

about 3.8 to 20 mole percent terephthalic acid (T) residues, and about 15 to 31 mole percent 2,6-naphthalenedicarboxylic acid(N);

(2) diol residues consisting essentially of;

about 25 to 40 mole percent hydroquinone (HQ) residues; and

about 20 to 51 mole percent p-hydroxybenzoic acid (PHB) residues, wherein the T/T+N molar ratio is from about 15;

85 and 50;

50, the moles of HQ are equal to the sum of the moles of T+N, and the total of the residues'"'"' mole percentages is equal to 100.

7. An article comprising the composition of claim 1.

8. The article of claim 7 in the form of an optical pickup base in optical disc devices.