GLASS-CERAMIC WHICH IS AT LEAST PARTLY PROVIDED WITH A HARD MATERIAL LAYER

• US 20130209762A1
• Filed: 08/16/2012
• Published: 08/15/2013
• Est. Priority Date: 08/19/2011
• Status: Abandoned Application

• Current Assignee: Schott AG (Carl-Zeiss-Stiftung)
• Original Assignee: Schott AG (Carl-Zeiss-Stiftung)
• Inventors: DAMM, Thorsten, HACK, Hrabanus, HENN, Christian
• Application Number:
  US13/587,282
• Publication Number:
  US 20130209762A1
• Time in Patent Office: Days
• US Class Current: 428/212
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 17/225 Nitrides
• CPC Class Codes: C03C 17/3435 comprising a nitride, oxynitride, boronitride or carbonitride
• CPC Class Codes: C03C 2217/45 Inorganic continuous phases
• CPC Class Codes: C03C 2217/475 Inorganic materials
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree

Abstract

Glass-ceramic is provided that is at least partly provided with a hard material layer to protect against external mechanical influences. The hard material layer contains at least two phases, which are present side by side and are mixed with one another. The at least two phases include at least one nanocrystalline phase and one amorphous phase. The hard material layer has a hardness of at least 26 GPa and a layer thickness of at least 0.5 μm. The hard material layer is chemically resistant in the temperature range from 200° C. to 1000° C. The coefficient of thermal expansion (α) of the glass-ceramic does not differ by more than +/−20% from the coefficient of thermal expansion (α) of the hard material layer.

Claims

1. A glass-ceramic comprising:

a hard material layer that protects against external mechanical influences at least partially provided on the glass-ceramic,

wherein the hard material layer comprises at least two phases that are present side by side and are mixed with one another, the at least two phases comprising at least one nanocrystalline phase and one amorphous phase,

wherein the hard material layer has a hardness of at least 26 GPa and a layer thickness of at least 0.5 μ

m, is chemically resistant in the temperature range from 200°

C. to 1000°

C., and has a coefficient of thermal expansion (α

) that does not differ by more than +/−

20% from a coefficient of thermal expansion (α

) of the glass-ceramic.

2. The glass-ceramic according to claim 1, wherein the nanocrystalline phase has an average grain size of less than 1000 nm.

3. The glass-ceramic according to claim 2, wherein the average grain size is between 1 nm to 50 nm.

4. The glass-ceramic according to claim 1, wherein the amorphous phase substantially surrounds the nanocrystalline phase.

5. The glass-ceramic according to claim 1, wherein the hard material layer has a light transmission in the wavelength range from 380 nm to 780 nm of at least 80% at a layer thickness of 1.0 μ

m.

6. The glass-ceramic according to claim 1, wherein the nanocrystalline phase and/or the amorphous phase comprises a material selected from the group consisting of a nitridic compound, an oxidic compound, aluminium nitride, aluminium oxide, silicon nitride, silicon oxide, boron nitride, boron oxide, zirconium nitride, zirconium oxide, titanium nitride, titanium oxide, and combinations thereof.

7. The glass-ceramic according to claim 1, wherein the hard material layer further comprises an antireflection layer.

8. The glass-ceramic according to claim 1, wherein the hard material layer is part of an antireflection layer.

9. The glass-ceramic according to claim 1, wherein the glass-ceramic is a cooking surface, a viewing window, a chimney viewing window, a protective plate, or a covering plate.

10. The glass-ceramic according to claim 1, wherein the glass-ceramic is a lithium-aluminium silicate glass-ceramic.

11. The glass-ceramic according to claim 1, wherein the hard material layer has a hardness of at least 28 GPa.

12. The glass-ceramic according to claim 1, wherein the hard material layer has a hardness between 30 GPa to 50 GPa.

13. The glass-ceramic according to claim 1, wherein the hard material layer has a layer thickness of between 1.0 μ

m to 10 μ

m.

14. The glass-ceramic according to claim 1, further comprising at least one bonding or barrier layer arranged between glass-ceramic and hard material layer.

15. The glass-ceramic according to claim 1, wherein the hard material layer has a refractive index (n_D) that is above a refractive index (n_D) of the glass-ceramic.

16. The glass-ceramic according to claim 1, wherein the hard material layer has a proportion of nanocrystalline phase that greater than the amorphous phase.

17. The glass-ceramic according to claim 16, wherein the hard material layer has a proportion of nanocrystalline phase that is more than 50 mol % greater than the amorphous phase.

18. The glass-ceramic according to claim 16, wherein the hard material layer has a proportion of nanocrystalline phase that is more than 85 mol % greater than the amorphous phase.

19. The glass-ceramic according to claim 1, wherein the hard material layer has a light transmission in the wavelength range from 1 μ

m to 20 μ

m of at least 50%.

20. The glass-ceramic according to claim 19, wherein the light transmission in the wavelength range from 1 μ

m to 20 μ

m is at least 80%.

21. The glass-ceramic according to claim 1, wherein the nanocrystalline phase comprises more than two materials.

22. The glass-ceramic according to claim 1, wherein the amorphous phase comprises more than two materials.

23. The glass-ceramic according to claim 1, wherein the nanocrystalline phase consists essentially of aluminium nitride and the amorphous phase consists essentially of silicon nitride, and wherein at least one of the two phases contains oxygen ions in addition to nitride ions.