Process of Preparing Composite Structures

• US 20130213563A1
• Filed: 03/20/2013
• Published: 08/22/2013
• Est. Priority Date: 09/08/2008
• Status: Abandoned Application

• Current Assignee: Solenis Technologies LP (Innovative Water Care, LLC)
• Original Assignee: Hercules Incorporated (Ashland Global Holdings, Inc.)
• Inventors: Spraul, Bryan K., Allen, Anthony J.
• Application Number:
  US13/847,685
• Publication Number:
  US 20130213563A1
• Time in Patent Office: Days
• US Class Current: 156/160
• CPC Class Codes: B29C 65/02 by heating, with or without pressure
• CPC Class Codes: C08G 73/028 Polyamidoamines
• CPC Class Codes: C08G 73/0286 Preparatory process from polyamidoamines and epihalohydrins
• CPC Class Codes: C08L 2666/20 Macromolecular compounds having nitrogen in the main chain according to C08L75/00 - C08L79/00; Derivatives thereof
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: C08L 79/02 Polyamines
• CPC Class Codes: C08L 89/00 Compositions of proteins; Compositions of derivatives thereof foodstuff preparations A23J3/00
• CPC Class Codes: C09J 179/02 Polyamines
• CPC Class Codes: C09J 189/00 Adhesives based on proteins; Adhesives based on derivatives thereof

Abstract

The present invention relates to a process of making composite structures comprising applying an adhesive composition comprising a protein component, an azetidinium functionalized polymer component and a viscosity modifying component to one or more substrates.

Claims

1. A process of preparing a composite structure comprising:

applying to one or more substrates an adhesive composition comprising a) a protein component, b) an azetidinium functionalized polymer selected from the group consisting of amine-epichlorohydrin polymer and polyamidoamine-epichlorohydrin polymer, and c) one or more viscosity-modifying components; and

heating and pressing two or more of the substrates together to form the composite structure;

wherein the composition has a pH of from about 4.5 to less than 7.5;

a Brookfield viscosity of between about 1,000 cps and about 200,000 cps; and

a solids content of from about 5% to about 75%.

2. The process of claim 1, wherein the substrate is made of a lignocellulosic material, an inorganic material, glass wool, glass fiber or a combination of lignocellulosic material and inorganic material;

and

3. The process of claim 2, wherein the lignocellulosic material is selected from the group consisting of wood fibers, wood flakes, wood strands, wood chips, wood particles, pulp wood, wood wastes, wood bark, saw dust, paper, chips, cellulose-containing fibers of annual plants, granulated biomasses, recycled synthetic rubber, recycled natural rubber, recycled wood fiber, waste fibers, the grinding dust of the boards produced, and mixtures thereof.

4. The process of claim 1, wherein the composite structure is a particleboard (PB), oriented strand board (OSB), chip board, flake board, high density fiberboard or medium density fiberboard.

5. The process of claim 1, wherein the adhesive composition is applied to the substrate by roller coating, knife coating, extrusion, curtain coating, foam coaters and spray coaters.

6. The process of claim 1, wherein the protein source is selected from the group consisting of casein, blood meal, feather meal, keratin, gelatin, collagen, gluten, wheat gluten or protein, whey protein, zein or corn protein, rapeseed meal, sunflower meal and soy protein.

7. The process of claim 6, wherein the protein component has a protein dispersibility index of 20 or more.

8. The process of claim 7, wherein the protein component has a protein dispersibility index of 70 or more.

9. The process of claim 6, wherein the azetidinium functionalized polymer is polyamidoamine-epichlorohydfin polymer.

10. The process of claim 1, wherein the viscosity-modifying component is one or more viscosity-modifying components selected from the group consisting of sulfite salts, bisulfite salts, metabisulfite salts, thiols, and bisulfite adducts of aldehydes.

11. The process of claim 10, wherein the sulfite, bisulfite and metabisulfite salts are selected from the group consisting of sodium sulfite, potassium sulfite, lithium sulfite, ammonium sulfite, sodium bisulfite, potassium bisulfite, lithium bisulfite, ammonium bisulfite, sodium metabisulfite, potassium metabisulfite, lithium metabisulfite, ammonium metabisulfite and sodium bisulfite/sodium metabisulfite.

12. The process of claim 10, wherein the viscosity-modifying component is selected from sodium bisulfite and sodium bisulfite/sodium metabisulfite.

13. The process of claim 10, wherein the viscosity-modifying component is a thiol selected from the group consisting of cysteine, 2-mercaptoethanol, dithiothreitol, and dithioerythritol, methanethiol, ethanethiol, 1-propanethiol, 1-butanethiol, 1-pentanethiol, 1-octanethiol, 2-propanethiol, 2-methyl-1-propanethiol, cyclohexyl mercaptan, allyl mercaptans, ethanedithiol, 1,3-propanedithiol, 1,4-butanedithiol, 2,3-butanedithiol, 1,5-pentanedithiol, 1,5-hexanedithiol, dithiothreitol, dithioerythritol, hydroxythiols and thioethers.

14. The process of claim 13, wherein the hydroxythiols are selected from the group consisting of ethanedithiol, 1,3-propanedithiol, 1,4-butanedithiol, 2,3-butanedithiol, 1,5-pentanedithiol, 1,5-hexanedithiol, dithiothreitol and dithioerythritol.

15. The process of claim 10, wherein the thioethers is 1-mercaptoethylether.

16. The process of claim 1 wherein the amount of viscosity-modifying additive is from 1 part modifier to 100,000 parts protein to 1 part modifier to 10 parts protein.

17. The process of claim 1 wherein the pH of the composition is between 5 and 7.

18. The process of claim 1 wherein the total solids content of the composition is from about 25% to about 65%.

19. The process of claim 18, wherein the total solids content of the composition is from about 30% to about 60%.

20. The process of claim 1, wherein the composition comprises a soy protein having a protein dispersibility index of 20 or more;

a polyamidoamine-epichlorohydrin polymer; and

sodium metabisulfite, sodium bisulfite or sodium sulfite.