HIGH STRENGTH EXTRUDED THERMOPLASTIC POLYMER FOAM

• US 20130266766A1
• Filed: 12/14/2011
• Published: 10/10/2013
• Est. Priority Date: 12/27/2010
• Status: Active Grant

• Current Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Original Assignee: Dow Global Technologies LLC (Dow, Inc.)
• Inventors: Sagnard, Alain, Vo, Van-Chau, Gordon-Duffy, John
• Granted Patent: US 9,228,070 B2
• Time in Patent Office: Days
• US Class Current: 428/159
• CPC Class Codes: B29C 44/20 for articles of indefinite length
• CPC Class Codes: B29C 44/505 extruding the compound through a flat die in general B29C48/03
• CPC Class Codes: C08J 2201/03 Extrusion of the foamable blend
• CPC Class Codes: C08J 2203/06 CO2, N2 or noble gases
• CPC Class Codes: C08J 2203/14 Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
• CPC Class Codes: C08J 2203/142 Halogenated saturated hydrocarbons, e.g. H3C-CF3
• CPC Class Codes: C08J 2300/22 Thermoplastic resins
• CPC Class Codes: C08J 2325/06 Polystyrene
• CPC Class Codes: C08J 9/00 Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof mechanical aspects of shaping of plastics or substances in a plastic state for the production of porous or cellular articles B29C
• CPC Class Codes: C08J 9/04 using blowing gases generated by a previously added blowing agent
• CPC Class Codes: C08J 9/122 Hydrogen, oxygen, CO2, nitrogen or noble gases
• CPC Class Codes: C08J 9/141 Hydrocarbons
• CPC Class Codes: C08J 9/146 only fluorine as halogen atoms
• CPC Class Codes: Y10T 428/24504 Component comprises a polymer [e.g., rubber, etc.]

Abstract

Prepare extruded thermoplastic polymer foam by preparing a foamable polymer mixture containing thermoplastic polymer and blowing agent at a mixing pressure, cooling the foamable polymer mixture and extruding it through a foaming die at a die pressure at least 90 bars lower than the mixing pressure and out through a die opening having cross sectional dimensions of 2.5 millimeter or more and a cross sectional area of at least 700 square millimeters at a flow rate greater than 500 kilograms per hour and allow it to expand into a polymer foam between shaping elements while restraining the extrusion rate with a restraining device so as to form polymer foam having 96 volume percent or less void volume, anisotropic cell size, a thickness of 50 millimeter or greater, compressive and tensile moduli in the thickness dimension greater than 35 mega pascals and an average shear modulus greater than 16 mega pascals.

Claims

1. An extrusion foam process, the process comprising preparing at a mixing pressure a foamable polymer mixture comprising a thermoplastic polymer and a blowing agent, cooling the foamable polymer mixture and extruding it in an extrusion direction through a foaming die at a die pressure and out of the foaming die through a die opening at a flow rate into an atmosphere of low enough pressure to allow the foamable polymer mixture to expand into a polymer foam while traveling in the extrusion direction at an extrusion rate, the extrusion foam process being further characterized by:

a. the die pressure being at least 90 bars lower than the mixing pressure;

b. all cross sectional dimensions of the die opening being at least 2.5 millimeters and the cross sectional area of the die opening being at least 700 square millimeters;

c. the flow rate of the foamable polymer mixture through the die opening being greater than 500 kilograms per hour;

d. the foamable polymer mixture expands between restraining elements positioned immediately after the foaming die;

e. a device positioned after the restraining elements that restrains the extrusion rate of the polymer foam relative to its unrestrained extrusion rate;

and wherein the polymer foam characterized by having a continuous thermoplastic polymer matrix defining cells therein, a void volume of 96 volume percent or less based on total polymer foam volume, a cell size dimensional ratio in the polymer foam thickness dimension to its width and length dimension that is greater than one, and a thickness of 50 millimeters or more, a compressive modulus and tensile modulus in the thickness dimension that is greater than 35 mega pascals and an average shear modulus between its thickness/width and thickness/length dimensions that is greater than sixteen mega pascals.

2. The process of claim 1, further characterized by the temperature difference between the die and foamable polymer mixture within the die being less than six degrees Celsius.

3. The process of claim 1, further characterized by the pressure difference between the mixing pressure and die pressure being at least 100 bars.

4. The process of claim 1, further characterized by the foamable polymer mixture comprising a blowing agent selected from carbon dioxide, butane isomers, and 1,1,1,2-tetrafluoroethane.

5. The process of claim 4, further characterized by the foamable polymer mixture comprising at least 0.08 moles of blowing agent per hundred grams of thermoplastic polymer.

6. The process of claim 1, further characterized by the foamable polymer mixture comprising polystyrene.

7. The process of claim 6, further characterized by the polystyrene having a weight-averaged molecular weight of 140,000 grams per mole or more.

8. The process of claim 6, further characterized by the foamable polymer mixture comprising carbon dioxide at a concentration in a range of 0.5 to 5 weight-percent based on the thermoplastic polymer in the foamable polymer mixture and the foaming die being at a temperature in a range between 105 and 120 degrees Celsius.

9. An extruded thermoplastic polymer foam comprising a continuous thermoplastic polymer matrix defining cells therein and characterized by having a void volume of 96 percent or less based on total polymer foam volume, a cell size dimensional ratio in the polymer foam thickness dimension to any orthogonal polymer foam dimension that is greater than one;

a thickness of 50 millimeters or more;

a compressive modulus and tensile modulus in the thickness dimension that is greater than 35 mega pascals and an average shear modulus between thickness/width and thickness/length dimensions that is greater than 16 mega pascals.

10. The extruded thermoplastic polymer foam of claim 9, further characterized by the thermoplastic polymer matrix comprising at least 90 weight-percent polystyrene homopolymer based on total thermoplastic polymer matrix weight.

11. The extruded thermoplastic polymer foam of claim 9, further characterized by having a concentration of residual and bound crosslinking additive that is less than five weight-percent based on total thermoplastic polymer weight.

12. The extruded thermoplastic polymer foam of claim 9, further characterized as having at least one additional polymer foam laminated to it.