Water Purification Using Energy from a Steam-Hydrocarbon Reforming Process

• US 20130309163A1
• Filed: 04/08/2013
• Published: 11/21/2013
• Est. Priority Date: 05/18/2012
• Status: Active Grant

• Current Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Original Assignee: Air Products and Chemicals Incorporated (Linde Plc)
• Inventors: Peng, Xiang-Dong, Herb, Blaine Edward, Klingenberg, Eric Howard, Miller, Derek, Achilles, Geoffrey Colling
• Granted Patent: US 8,709,287 B2
• Time in Patent Office: Days
• US Class Current: 423/650
• CPC Class Codes: B01D 1/0058 Use of waste energy from other processes or sources, e.g. combustion gas for water treatment C02F1/16
• CPC Class Codes: B01D 1/26 Multiple-effect evaporating
• CPC Class Codes: C01B 2203/0233 the reforming step being a steam reforming step
• CPC Class Codes: C01B 2203/0283 containing a CO-shift step, i.e. a water gas shift step
• CPC Class Codes: C01B 2203/043 Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
• CPC Class Codes: C01B 2203/0495 the impurity being water
• CPC Class Codes: C01B 2203/0816 Heating by flames
• CPC Class Codes: C01B 2203/0827 at least part of the fuel being a recycle stream
• CPC Class Codes: C01B 2203/0883 by indirect heat exchange
• CPC Class Codes: C01B 3/24 of hydrocarbons
• CPC Class Codes: C01B 3/26 using catalysts
• CPC Class Codes: C01B 3/384 the catalyst being continuously externally heated
• CPC Class Codes: C02F 1/06 Flash evaporation
• CPC Class Codes: Y02W 10/37 using solar energy

Abstract

A process for producing a H₂-containing product gas and purified water from an integrated catalytic steam-hydrocarbon reforming and thermal water purification process. Raw water, such as salt water, is heated by indirect heat transfer with reformate from the catalytic steam reforming process for purifying raw water in one of a multiple effect distillation process and a multi-stage flash process.

Claims

1. A process for producing a H₂-containing product gas and for producing purified water, the process comprising:

(a) introducing a reformer feed gas mixture into a plurality of catalyst-containing reformer tubes in a reformer furnace, reacting the reformer feed gas mixture in a reforming reaction under reaction conditions effective to form a reformate comprising H₂, CO, CH₄, and H₂O, and withdrawing the reformate from the plurality of catalyst-containing reformer tubes;

(b) heating saturated boiler feed water from a steam drum by indirect heat transfer with the reformate withdrawn from the plurality of catalyst-containing reformer tubes in a first heat exchanger thereby forming high pressure steam having a pressure ranging from 1.5 to 12.5 MPa (absolute), wherein the reformer feed gas mixture comprises the high pressure steam;

(c) heating boiler feed water by indirect heat transfer with the reformate from the first heat exchanger in a second heat exchanger and introducing the heated boiler feed water into the steam drum;

(d) reacting the reformate from the second heat exchanger in the presence of a shift catalyst under reaction conditions effective to form additional hydrogen in the reformate;

(e) heating raw water by indirect heat transfer with the reformate from step (d) thereby heating the raw water for purification thereof by a thermal water purification process to produce purified water, and thereby cooling the reformate stream;

(f) heating make-up water by indirect heat transfer with the reformate from step (e) in a third heat exchanger thereby cooling the reformate to a temperature ranging from 25°

C. to 65°

C.;

(g) separating the reformate from step (f) to produce the H₂-containing product and a by-product gas; and

(h) combusting a fuel with an oxidant gas in the reformer furnace external to the plurality of catalyst-containing reformer tubes under conditions effective to combust the fuel to form a combustion product gas and generate heat to supply energy for reacting the reformer feed gas mixture inside the plurality of catalyst-containing reformer tubes, and withdrawing a combustion product gas from the reformer furnace.

3. The process of claim 1 wherein the thermal water purification process is one of a multiple effect distillation process and a multi-stage flash process.

4. The process of claim 1 wherein the make-up water comprises the purified water.

5. The process of claim 1 wherein the make-up water consists of the purified water.

6. The process of claim 5 wherein the make-up water consists of the purified water without treating by filtration, demineralization, or deaeration.

7. The process of claim 1 wherein the step of heating raw water by indirect heat transfer comprises:

heating a working fluid by indirect heat transfer with the reformate from step (d), and heating the raw water by indirect heat transfer with the working fluid.

8. The process of claim 7 wherein the working fluid is water, wherein the working fluid water is evaporated to form a first stream of steam having a pressure ranging from 15.2 kPa to 304 kPa (absolute) when heated by the reformate from step (d), and wherein the first stream of steam is condensed when heating the raw water.

9. The process of claim 8 wherein 0.05<

X<

1.2, where X is the ratio of the mass flow rate of the first stream of steam to the mass flow rate of the make-up water.

10. The process of claim 8 wherein:

the water is evaporated to form a second stream of steam having a pressure ranging from 280 kPa to 608 kPa;

the reformate from step (d) heats the second stream of steam prior to heating the first stream of steam;

the second stream of steam is expanded in a steam turbine to generate shaft work prior to heating the raw water; and

the second stream of steam is condensed when heating the raw water.

11. The process of claim 1 wherein the step of heating raw water does not include heating of an intermediate working fluid.

12. The process of claim 1 wherein the reformate is separated by pressure swing adsorption in the step (g) to produce the H₂-containing product and the by-product gas.

13. The process of claim 1 wherein the fuel combusted in step (h) comprises the by-product gas.

14. The process of claim 1 further comprising:

heating the boiler feed water by indirect heat transfer with the reformate from step (d) prior to heating the raw water by indirect heat transfer with the reformate from step (d) wherein the boiler feed water is heated by the reformate from step (d) before being heated in step (c); and

heating a hydrocarbon feedstock by indirect heat transfer with the reformate from step (e), wherein the reformer feed gas mixture comprises the hydrocarbon feedstock.

15. The process of claim 1 further comprising:

expanding a portion of the high pressure steam in a steam turbine to generate shaft work;

heating the raw water by indirect heat transfer with the expanded steam from the steam turbine thereby heating the raw water for purification thereof in the thermal water purification process.

16. The process of claim 1 wherein the raw water comprises process condensate from a steam methane reforming process.

17. The process of claim 1 wherein the raw water comprises at least one of river water, stream water, lake water, municipal recycled water, industrial recycled water, and groundwater.

2. The process of aspect 1 wherein the raw water comprises salt water, the thermal water purification process is a desalination process, and the purified water is desalinated water.