PROCESS FOR SEPARATION AND RECOVERY OF CUTTINGS, EMULSION AND SLURRY COMPONENTS

• US 20130331632A1
• Filed: 05/29/2013
• Published: 12/12/2013
• Est. Priority Date: 05/29/2012
• Status: Abandoned Application

• Current Assignee: C&E Reclamation, Inc.
• Original Assignee: C&E Reclamation, Inc.
• Inventors: Drake, Ronald N.
• Application Number:
  US13/904,750
• Publication Number:
  US 20130331632A1
• Time in Patent Office: Days
• US Class Current: 585/802
• CPC Class Codes: B01D 3/009 in combination with chemical reactions
• CPC Class Codes: C10G 1/02 by distillation
• CPC Class Codes: C10G 70/00 Working-up undefined normally gaseous mixtures obtained by processes covered by groups C10G9/00, C10G11/00, C10G15/00, C10G47/00, C10G51/00
• CPC Class Codes: F26B 17/20 the axis of rotation being horizontal or slightly inclined
• CPC Class Codes: F26B 2200/18 Sludges, e.g. sewage, waste, industrial processes, cooling towers
• CPC Class Codes: F26B 3/0923 by mechanical means, e.g. vibrated plate, stirrer
• CPC Class Codes: F26B 3/20 the heat source being a heated surface , e.g. a moving belt or conveyorF26B3/22 takes precedence

Abstract

This disclosure describes systems, methods, and apparatus for separating and purifying components from mixtures and emulsions containing hydrocarbons, water, salt, and mineral solids. Key unit operations are thermal desorbing, hot filtering, direct contact condensing, solids leaching, evaporating, and salt precipitating. Preferred embodiments of the process and system use process-generated fuel, leach water, and hot combustion gas to conduct thermal desorption, solids leaching, and salt precipitating. Use of process generated streams for key unit operations greatly reduces the need for purchased utilities and contributes both to process efficiency and economy.

Claims

1. A method for treating oilfield wastes comprising:

separating an oilfield waste feed into a first vapor stream and a first solids stream via thermal desorption, the first vapor stream comprising hydrocarbon vapor, water vapor, and solid fines, the first solids stream comprising salts and solids having a larger average mass than the solid fines; and

separating the solid fines from the first vapor stream to produce a second vapor stream and a second solids stream, the second vapor stream comprising hydrocarbon and water vapors and being substantially free of solids.

2. The method of claim 1, further comprising:

condensing the second vapor stream to form a first liquids stream comprising liquid hydrocarbons and liquid water;

separating the first liquids stream into a first clean liquid water stream and a clean liquid hydrocarbon stream;

leaching the first and second solids streams with water to produce a clean solids stream and aqueous brine;

evaporating the aqueous brine to produce a precipitated salt stream and a water vapor stream; and

condensing the water vapor stream to produce a second clean water stream and a clean off-gas stream.

3. The method of claim 1, wherein at least a portion of the liquid hydrocarbon stream is used to generate heat for the thermal desorption.

4. The method of claim 1, further comprising steam stripping of desorbed solids from or in the thermal desorption.

5. The method of claim 1, wherein the leaching is performed using at least a portion of the first and/or second clean water streams.

6. The method of claim 1, wherein off-gas from the thermal desorption provides at least a portion of heat used in the evaporation of the aqueous brine.

7. The method of claim 6, wherein at least a portion of the heat for the evaporation of the aqueous brine is transferred to the aqueous brine via direct contact of the off-gas with the aqueous brine.

8. A system for treating oilfield wastes comprising:

a thermal desorber, receiving waste feed and producing a first stream of hydrocarbon and water vapors that contain some solid fines and a second stream of mineral and salt solids that are substantially free of hydrocarbons and moisture;

a hot vapor filter, receiving said first stream of hydrocarbon and water vapors that contain some solid fines, and generating a solids-free vapor stream and a stream of solid fines;

a vapor condenser, receiving the solids-free vapor stream, and generating a mixed liquids stream comprising hydrocarbons and water;

a liquids separator, receiving the mixed liquids stream, and generating a liquid hydrocarbon stream and a first liquid water stream;

a solids leacher, receiving said second stream of mineral and salt solids from the thermal desorber and receiving said stream of solid fines from the hot vapor filter, and generating a stream of salt-free damp solids, and a stream of salt brine;

a salt crystallizer, receiving the stream of salt brine, and generating damp salt cake and water vapor; and

a water vapor condenser, receiving the water vapor, and generating a second liquid water stream.

9. A system comprising:

a thermal desorber receiving an oilfield waste feed and applying thermal energy to the oilfield waste feed in order to vaporize liquid components in the oilfield waste feed thus generating a first vapor stream and a solids stream, the solids stream including a first portion of solids in the oilfield waste feed; and

a hot filter receiving the first vapor stream and filtering the first vapor stream in order to remove a second portion of solids from the first vapor stream thus generating a second vapor stream and a second solids stream,

an average particle mass of the second solids stream being smaller than an average particle mass of the first solids stream.

10. The system of claim 9, wherein the thermal desorber is a thermal screw submerged in a fluidized bed combustor.

11. The system of claim 10, wherein a media in the fluidized bed combustor is maintained above a vaporization temperature of vapors in the first vapor stream.

12. The system of claim 11, wherein the media is a catalyst for combustion of a clean organic produced by the system.

13. The system of claim 9, wherein the first vapor stream includes organic vapor, water vapor, and fine particulate solids.

14. The system of claim 9, wherein the first and second solids streams are provided to means for solids processing that further process the first and second solids streams and generate clean solids, dry salt, clean water, and clean off-gas.

15. The system of claim 14, wherein hot off-gas from the thermal desorber is provided to the solids processing means to aid in generating the dry salt.

16. The system of claim 15, wherein at least a portion of the clean water is recycled to aid in generating the clean solids.

17. The system of claim 15, wherein the second vapor stream is provided to vapor processing means that further process the second vapor stream and generate clean liquid organics and clean water.

18. The system of claim 17, wherein at least some of the clean liquid organics are combusted to generate thermal energy used in the thermal desorber.

19. The system of claim 18, wherein at least some of the clean liquid organics are used as fuel for the fluidized bed combustor.

20. The system of claim 9, wherein the hot filter is a moving bed granular filter.

21. The system of claim 20, wherein a media of the hot filter is selected from the group consisting of:

sand, alumina, zeolite, graphite, and dolomite.

22. The system of claim 9, wherein a media in the hot filter is maintained above a vaporization temperature of vapors in the first vapor stream.