SYSTEM AND METHOD FOR CAPTURING CARBON DIOXIDE FROM SHIFTED SYNGAS

• US 20140026572A1
• Filed: 07/25/2012
• Published: 01/30/2014
• Est. Priority Date: 07/25/2012
• Status: Abandoned Application

• Current Assignee: General Electric Company
• Original Assignee: General Electric Company
• Inventors: Anand, Ashok Kumar, Reddy, Thirumala Reddy Nagarjuna
• Application Number:
  US13/557,604
• Publication Number:
  US 20140026572A1
• Time in Patent Office: Days
• US Class Current: 60/643
• CPC Class Codes: B01D 2256/16 Hydrogen
• CPC Class Codes: B01D 2256/20 Carbon monoxide
• CPC Class Codes: B01D 2257/504 Carbon dioxide
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 20/16 Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
• CPC Class Codes: Y02E 20/18 Integrated gasification combined cycle [IGCC], e.g. combined with carbon capture and storage [CCS]

Abstract

A system for capturing carbon dioxide from a shifted syngas is disclosed. The system may generally include a solid sorbent configured to absorb carbon dioxide at a first temperature and release carbon dioxide at a second temperature. In addition, the system may include an absorption chamber configured to receive the shifted syngas at the first temperature and a regeneration chamber separate from the absorption chamber. The regeneration chamber may be maintained at the second temperature. The solid sorbent may be cycled between the absorption chamber and the regeneration chamber such that carbon dioxide from the shifted syngas is absorbed within the absorption chamber to produce a decarbonized fuel gas and released within the regeneration chamber to produce a carbon dioxide stream.

Claims

1. A system for capturing carbon dioxide from a shifted syngas, the system comprising:

a solid sorbent configured to absorb carbon dioxide at a first temperature and release carbon dioxide at a second temperature;

an absorption chamber configured to receive the shifted syngas at the first temperature; and

a regeneration chamber separate from the absorption chamber, the regeneration chamber being maintained at the second temperature,

wherein the solid sorbent is cycled between the absorption chamber and the regeneration chamber such that carbon dioxide from the shifted syngas is absorbed within the absorption chamber to produce a decarbonized fuel gas and released within the regeneration chamber to produce a carbon dioxide stream.

2. The system of claim 1, wherein the solid sorbent comprises a high temperature ceramic catalyst.

3. The system of claim 2, wherein the high temperature ceramic catalyst comprises at least one of lithium silicate, calcium oxide or magnesium oxide.

4. The system of claim 1, wherein the first temperature ranges from about 800°

F. to about 1300°

F.

5. The system of claim 1, wherein the second temperature ranges from about 1350°

F. to about 1500°

F.

6. The system of claim 1, wherein the solid sorbent is placed in beds configured to be cycled between the absorption chamber and the regeneration chamber.

7. A power plant comprising:

a gasifier configured to produce a raw syngas;

a shift reactor downstream of the gasifier, the shift reactor configured to convert the raw syngas into a shifted syngas including hydrogen and carbon dioxide; and

a carbon dioxide capture system downstream of the shift reactor, the carbon dioxide capture system comprising;

a solid sorbent configured to absorb carbon dioxide at a first temperature and release carbon dioxide at a second temperature;

an absorption chamber configured to receive the shifted syngas at the first temperature; and

a regeneration chamber separate from the absorption chamber, the regeneration chamber being maintained at the second temperature,

wherein the solid sorbent is cycled between the absorption chamber and the regeneration chamber such that carbon dioxide from the shifted syngas is absorbed within the absorption chamber to produce a decarbonized fuel gas and released within the regeneration chamber to produce a carbon dioxide stream.

8. The power plant of claim 7, further comprising a heater positioned downstream of the shift reactor and upstream of the carbon dioxide capture system, the heater configured to heat the shifted gas to the first temperature.

9. The power plant of claim 8, wherein at least one of the decarbonized fuel gas exiting the absorption chamber or the carbon dioxide stream exiting the regeneration chamber is directed through a portion of the heater.

10. The power plant of claim 7, wherein the decarbonized fuel gas exiting the absorption chamber is directed to a power production system.

11. The power plant of claim 10, wherein the power production system comprises a combined cycle power system.

12. The power plant claim 7, wherein the solid sorbent comprises a high temperature ceramic catalyst.

13. The power plant of claim 12, wherein the high temperature ceramic catalyst comprises at least one of lithium silicate, calcium oxide or magnesium oxide.

14. The power plant of claim 7, wherein the first temperature ranges from about 800°

F. to about 1300°

F.

15. The power plant of claim 7, wherein the second temperature ranges from about 1350°

F. to about 1500°

F.

16. The power plant of claim 7, wherein the solid sorbent is placed in beds configured to be cycled between the absorption chamber and the regeneration chamber.

17. The power plant of claim 7, further comprising a burner associated with the regeneration chamber, the burner being configured to maintain the regeneration chamber at the second temperature.

18. A method for capturing carbon dioxide from a shifted syngas, the method comprising:

cycling a solid sorbent between an absorption chamber and a regeneration chamber, the solid sorbent being configured to absorb carbon dioxide at a first temperature and release carbon dioxide at a second temperature;

supplying shifted syngas into the absorption chamber at the first temperature such that the solid sorbent absorbs carbon dioxide from the shifted syngas as the solid sorbent is cycled through the absorption chamber to produce a decarbonized fuel gas; and

heating the solid sorbent to the second temperature as the solid sorbent is cycled through the regeneration chamber such that the solid sorbent releases the carbon dioxide to produce a carbon dioxide stream.

19. The method of claim 18, further comprising heating the shifted syngas to the first temperature with a heater positioned upstream of the absorption chamber.

20. The method of claim 19, further comprising directing at least one of the decarbonized fuel gas or the carbon dioxide stream through the heater.