NBPT solution for preparing urease inhibited urea fertilizers prepared from N-alkyl; N, N-alkyl; and N-alkyl-N-alkoxy amino alcohols

• US 20140037570A1
• Filed: 08/02/2012
• Published: 02/06/2014
• Est. Priority Date: 08/02/2012
• Status: Abandoned Application

• Current Assignee: Whitehurst Associates, Inc.
• Original Assignee: Whitehurst Associates, Inc.
• Inventors: Whitehurst, Garnett B., Whitehurst, Brooks M.
• Application Number:
  US13/507,848
• Publication Number:
  US 20140037570A1
• Time in Patent Office: Days
• US Class Current: 424/76.6
• CPC Class Codes: C05C 9/005 Post-treatment
• CPC Class Codes: C05G 3/90 for affecting the nitrification of ammonium compounds or urea in the soil
• CPC Class Codes: C07F 9/224 Phosphorus triamides
• CPC Class Codes: Y02P 60/21 Dinitrogen oxide [N2O], e.g. using aquaponics, hydroponics or efficiency measures

Abstract

Solutions are prepared by dissolving N-(n-butyl)-thiophosphoric triamide (NBPT) in one or more N-alkyl amino alcohols, N,N-dialkyl amino alcohols, N-alkyl-N-alkoxy amino alcohols, and mixtures thereof. The solutions may be used in urea fertilizers to reduce nitrogen volatilization, or to reduce the odor of animal waste. Methods of preparing urea fertilizers and the resultant products are also described.

Claims

1. A solution for use in reducing nitrogen volatilization comprising N-(n-butyl)-thiophosphoric triamide (NBPT) dissolved in one or more N-alkyl amino alcohols, N,N-dialkyl amino alcohols, N-alkyl-N-alkoxy amino alcohols, and mixtures thereof.

2. The solution of claim 1, wherein said N-alkyl amino alcohols and N,N-dialkyl amino alcohols have the formula:

3. The solution of claim 1, wherein said N-alkyl-N-alkoxy amino alcohols have the formula:

4. The solution of claim 1, wherein said N-alkyl amino alcohol is selected from the group consisting of N-methylethanolamine (NMEA), N-ethylethanolamine, N-propylethanolamine, N-isopropylethanolamine, N-butylethanolamine, N-sec-butylethanolamine, N-isobutylethanolamine and N-tert-butylethanolamine, N-methyldiethanolamine (MDEA), N-ethyldiethanolamine, N-propyldiethanolamine, N-isopropyldiethanolamine, N-butyldiethanolamine, N-sec-butyldiethanolamine, N-isobutyldiethanolamine, and N-tert-butyldiethanolamine.

5. The solution of claim 1, wherein said N,N-dialkyl amino alcohol is selected from the group consisting of N,N-dimethylethanolamine (DMEA), N,N-diethylethanolamine (DEEA), N,N-dipropylethanolamine, N,N-diisopropylethanolamine, N,N-dibutylethanolamine, N,N-disecbutylethanolamine, N,N-diisobuytlethanolamine and N—

N-tert-butylethanolamine.

6. The solution of claim 1, wherein said N-alkyl-N-alkoxy amino alcohol is selected from the group consisting of 2-((2(2-hydroxyethoxy)ethyl)(methyl)amino)ethanol (MHEEA), 2-(ethyl(2-(2-hydroxyethoxy)ethyl)amino)ethanol, 2-((2-(2-hydroxyethoxy)ethyl)(propyl)amino)ethanol, 3-(ethyl(3-(3-hydroxypropoxy)propyl)amino)propan-1-ol and 3-((3-hydroxypropoxy)propyl)(methyl)amino)propan-1-ol.

7. The solution of claim 1, wherein said solution includes from about 0.5% NBPT to about 40% NBPT.

8. The solution of claim 1, wherein said solution is pH adjusted to a pH of from 7 to 10.

9. The solution of claim 1, further including a co-solvent.

10. The solution of claim 1, further including a denitrification inhibitor.

11. The solution of claim 10, wherein said denitrification inhibitor is selected from the group consisting of dicyandiamide (DCD or 2-cyanoguanidine), DMPP (3,4-dimethylpyrazole phosphate), and nitrapyrin (2-chloro-6-(trichloromethyl)pyridine).

12. The solution of claim 1, wherein said NBPT is dissolved in a mixture of N-methyldiethanolamine (MDEA) and 2-((2(2-hydroxyethoxy)ethyl)(methyl)amino)ethanol (MHEEA).

13. A solution of claim 1, wherein the NBPT is dissolved in a mixture of an N-alkyl, N,N-dialkyl, or N-alkyl-N-alkoxy amino alcohol which additionally contains triethanolamine, diethanolamine and mixtures thereof.

14. A solution of claim 13 in which the pH is adjusted from 7 to 10.

15. A solution of claim 13 wherein the NBP is dissolved in a mixture of N-methyldiethanolamine (MDEA) and 2-((2(2-hydroxyethoxy)ethyl)(methyl)amino)ethanol (MHEEA) and triethanolamine or diethanolamine and mixtures thereof.

16. A method of reducing the nitrogen volatility of a urea fertilizer comprising combining said fertilizer with N-(n-butyl)-thiophosphoric triamide (NBPT) dissolved in one or more N-alkyl amino alcohols, N,N-dialkyl amino alcohols, N-alkyl-N-alkoxy amino alcohols, and mixtures thereof.

17. The method of claim 16, wherein said fertilizer is in aqueous solution.

18. The method of claim 16, wherein said fertilizer is granular and said solution is coated onto said granules.

19. The method of claim 16, wherein said NBPT comprises from about 0.005% to about 0.25% by weight of the combined fertilizer and solution.

20. The method of claim 16, wherein said N-alkyl amino alcohols and N,N-dialkyl amino alcohols have the formula:

21. The method of claim 16, wherein said N-alkyl-N-alkoxy amino alcohols have the formula:

22. The method of claim 16, wherein said N-alkyl substituted amino alcohol is selected from the group consisting of N-methylethanolamine (NMEA), N-ethylethanolamine, N-propylethanolamine, N-isopropylethanolamine, N-butylethanolamine, N-sec-butylethanolamine, N-isobutylethanolamine and N-tert-butylethanolamine, N-methyldiethanolamine (MDEA), N-ethyldiethanolamine, N-propyldiethanolamine, N-isopropyldiethanolamine, N-butyldiethanolamine, N-sec-butyldiethanolamine, N-isobutyldiethanolamine, and N-tert-butyldiethanolamine.

23. The method of claim 16, wherein said N,N-dialkyl substituted amino alcohol is selected from the group consisting of N,N-dimethylethanolamine (DMEA), N,N-diethylethanolamine (DEEA), N,N-dipropylethanolamine, N,N-diisopropylethanolamine, N,N-dibutylethanolamine, N,N-disecbutylethanolamine, N,N-diisobuytlethanolamine and N—

N-tert-butylethanolamine.

24. The method of claim 16, wherein said N-alkyl-N-alkoxy amino alcohol is selected from the group consisting of 2-((2(2-hydroxyethoxy)ethyl)(methyl)amino)ethanol (MHEEA), 2-(ethyl(2-(2-hydroxyethoxy)ethyl)amino)ethanol, 2-((2-(2-hydroxyethoxy)ethyl)(propyl)amino)ethanol, 3-(ethyl(3-(3-hydroxypropoxy)propyl)amino)propan-1-ol and 3-((3-hydroxypropoxy)propyl)(methyl)amino)propan-1-ol.

25. The method of claim 16, wherein said solution includes from about 0.5% NBPT to about 40% NBPT.

26. The method of claim 16, wherein said solution is pH adjusted to a pH of from 7 to 10.

27. The method of claim 16, further including adding a co-solvent.

28. The method of claim 16, further including adding a denitrification inhibitor.

29. The method of claim 28, wherein said denitrification inhibitor is selected from the group consisting of dicyandiamide (DCD or 2-cyanoguanidine), DMPP (3,4-dimethylpyrazole phosphate), and nitrapyrin (2-chloro-6-(trichloromethyl)pyridine).

30. The method of claim 16, wherein said NBPT is dissolved in a mixture of N-methyldiethanolamine (MDEA) and 2-((2(2-hydroxyethoxy)ethyl)(methyl)amino)ethanol (MHEEA).

31. The method of claim 16, further including adding additional plant nutrients.

32. A method of claim 16, wherein the NBPT is dissolved in a mixture of an N-alkyl, N,N-dialkyl, or N-alkyl-N-alkoxy amino alcohol which additionally contains triethanolamine, diethanolamine and mixtures thereof.

33. A method of claim 32, in which the pH is adjusted from 7 to 10.

34. A method of claim 32 wherein the NBPT is dissolved in a mixture of N-methyldiethanolamine (MDEA) and 2-((2(2-hydroxyethoxy)ethyl)(methyl)amino)ethanol (MHEEA).

35. A urea fertilizer having reduced nitrogen volatility comprised of urea and a solution of N-(n-butyl)-thiophosphoric triamide (NBPT) dissolved in one or more of N-alkyl amino alcohols, N,N-dialkyl amino alcohols, N-alkyl-N-alkoxy amino alcohols, and mixtures thereof.

36. The urea fertilizer of claim 35, wherein said urea fertilizer is in aqueous solution.

37. The urea fertilizer of claim 35, wherein said urea is granular urea, said granular urea being coated with N-(n-butyl)-thiophosphoric triamide (NBPT) dissolved in one or more of N-alkyl amino alcohols, N,N-dialkyl amino alcohols, N-alkyl-N-alkoxy amino alcohols, and mixtures thereof.

38. The urea fertilizer of claim 35, wherein said NBPT comprises from 0.005% to 0.25% of said fertilizer.

39. The urea fertilizer of claim 35, further including additional plant nutrients.

40. The urea fertilizer of claim 35, wherein said solution is less than 5% of said fertilizer.

41. The urea fertilizer of claim 35, further including an aqueous diluent.

42. The urea fertilizer of claim 35, further including a denitrification inhibitor.

43. A method of reducing the odor of animal waste comprising treating said waste with a solution of N-(n-butyl)-thiophosphoric triamide (NBPT) dissolved in one or more N-alkyl amino alcohols, N,N-dialkyl amino alcohols, N-alkyl-N-alkoxy amino alcohols, and mixtures thereof.