White Light Illumination System with Narrow Band Green Phosphor and Multiple-Wavelength Excitation

• US 20140055982A1
• Filed: 10/25/2013
• Published: 02/27/2014
• Est. Priority Date: 03/07/2008
• Status: Active Grant

• Current Assignee: Intematix Corporation
• Original Assignee: Intematix Corporation
• Inventors: Tao, Dejie, Li, Yi-Qun, Wang, Gang
• Granted Patent: US 8,740,400 B2
• Time in Patent Office: Days
• US Class Current: 362/84
• CPC Class Codes: C09K 11/0883 Arsenides; Nitrides; Phosphides
• CPC Class Codes: C09K 11/7733 with alkali or alkaline earth metals
• CPC Class Codes: C09K 11/7734 Aluminates
• CPC Class Codes: C09K 11/77342 Silicates
• CPC Class Codes: C09K 11/77344 Aluminosilicates
• CPC Class Codes: C09K 11/77348 Silicon Aluminium Nitrides or Silicon Aluminium Oxynitrides
• CPC Class Codes: C09K 11/7739 with halogens
• CPC Class Codes: C09K 11/7774 Aluminates
• CPC Class Codes: F21K 9/64 using wavelength conversion means distinct or spaced from the light-generating element, e.g. a remote phosphor layer
• CPC Class Codes: F21V 33/0052 Audio or video equipment, e.g. televisions, telephones, cameras or computers; Remote control devices therefor
• CPC Class Codes: F21Y 2115/10 Light-emitting diodes [LED]
• CPC Class Codes: H01L 2224/48091 Arched
• CPC Class Codes: H01L 25/0753 the devices being arranged next to each other
• CPC Class Codes: H01L 2924/00 Indexing scheme for arrangements or methods for connecting or disconnecting semiconductor or solid-state bodies as covered by H01L24/00
• CPC Class Codes: H01L 2924/00014 the subject-matter covered by the group, the symbol of which is combined with the symbol of this group, being disclosed without further technical details
• CPC Class Codes: H01L 2924/0002 Not covered by any one of groups H01L24/00, H01L24/00 and H01L2224/00
• CPC Class Codes: H01L 33/504 Elements with two or more wavelength conversion materials
• CPC Class Codes: Y02B 20/00 Energy efficient lighting technologies, e.g. halogen lamps or gas discharge lamps

Abstract

A white light illumination system may comprise: a phosphor package; a first radiation source for providing co-excitation radiation to the phosphor package, the source emitting in wavelengths ranging from about 250 nm to about 410 nm; and a second radiation source for providing co-excitation radiation to the phosphor package, the source emitting in wavelengths ranging from about 410 nm to about 540 nm; wherein the phosphor package is configured to emit photoluminescence in wavelengths ranging from about 440 nm to about 700 nm upon co-excitation from the first and second radiation sources, and wherein the phosphor package comprises at least one narrow band green phosphor with a photoluminescence peak with a full width at half maximum of less than 60 nm, and wherein the narrow band green phosphor is configured to emit photoluminescence in wavelengths ranging from about 500 nm to about 550 nm.

Claims

1. A white light illumination system comprising:

a phosphor package;

a first radiation source for providing co-excitation radiation to the phosphor package, the source emitting in wavelengths ranging from about 250 nm to about 410 nm;

a second radiation source for providing co-excitation radiation to the phosphor package, the source emitting in wavelengths ranging from about 410 nm to about 540 nm; and

wherein the phosphor package is configured to emit photoluminescence comprising light with wavelengths ranging from about 440 nm to about 700 nm upon co-excitation from the first and second radiation sources, and wherein the phosphor package comprises at least one narrow band green phosphor with a photoluminescence peak with a full width at half maximum of less than 60 nm, and wherein the narrow band green phosphor is configured to emit photoluminescence in wavelengths ranging from about 500 nm to about 550 nm.

2. The white light illumination system of claim 1, wherein the full width at half maximum of the photoluminescence peak of the at least one narrow band phosphor is less than 50 nm.

3. The white light illumination system of claim 1, wherein the full width at half maximum of the photoluminescence peak of the at least one narrow band phosphor is less than 40 nm.

4. The white light illumination system of claim 1, wherein the full width at half maximum of the photoluminescence peak of the at least one narrow band phosphor is less than 30 nm.

5. The white light illumination system of claim 1, wherein the first radiation source and the second radiation source are part of a multi-chip excitation source.

6. The white light illumination system of claim 1, wherein the green phosphor has a composition given by the formula M_aEu₁₋

aAl_bO_c, wherein;

M is at least one divalent metal selected from the group consisting of Mg, Ca, Sr, Ba, Mn, Zn, Cu, Cd, Sm and Tm;

0<

a≦

1.0;

0.5≦

b≦

12.0; and

1.75≦

c≦

19.0.

7. The white light illumination system of claim 1, wherein the green phosphor has a composition given by the formula M₁₋

xEu_xMg<sub>1−

y</sub>Mn_yAl₁₀O₁₇, wherein;

M is at least one alkaline earth metal;

0.01<

x≦

1.0; and

0.01<

y≦

1.0.

8. The white light illumination system of claim 7, wherein x=1.

9. The white light illumination system of claim 8, wherein 0.1≦

y≦

0.7.

10. The white light illumination system of claim 8, wherein 0.2≦

y≦

0.4.

11. The white light illumination system of claim 7, wherein M is at least one of Ba and Sr.

12. The white light illumination system of claim 11, wherein 0.1≦

x≦

0.5 and 0.25≦

y≦

0.5.

13. The white light illumination system of claim 11, wherein 0.3≦

x≦

0.5 and 0.3≦

y≦

0.5.

14. The white light illumination system of claim 7, wherein the composition is given by the formula Ba_0.6Eu_0.4Mg_0.6Mn_0.4Al₁₀O₁₇.

15. The white light illumination system of claim 1, wherein the phosphor package further comprises a red phosphor configured to emit photoluminescence in wavelengths ranging from about 600 nm to about 700 nm.

16. The white light illumination system of claim 15, wherein the white light illumination emitted by the system covers an area including greater than 90% of NTSC 1953 color gamut specification as mapped on CIE 1931 xy chromaticity diagram.

17. The white light illumination system of claim 15, wherein the green phosphor has chromaticity coordinates CIE (x, y) within an area of CIE 1931 xy chromaticity diagram defined by a simple quadrilateral with vertices (0.120, 0.775), (0.230, 0.755), (0.360, 0.620) and (0.150, 0.650).

18. The white light illumination system of claim 15, wherein the green phosphor has chromaticity coordinates CIE (x, y) within an area of CIE 1931 xy chromaticity diagram defined by a simple quadrilateral with vertices (0.128, 0.768), (0.205, 0.753), (0.278, 0.660) and (0.150, 0.680).

19. The white light illumination system of claim 15, wherein the green phosphor has chromaticity coordinates CIE (x, y) within an area of CIE 1931 xy chromaticity diagram defined by a simple quadrilateral with vertices (0.135, 0.760), (0.180, 0.750), (0.195, 0.700) and (0.150, 0.710).

20. The white light illumination system of claim 15, wherein the red phosphor has chromaticity coordinates CIE (x, y) within an area of CIE 1931 xy chromaticity diagram defined by a simple quadrilateral with vertices (0.61, 0.39), (0.70, 0.30), (0.68, 0.30) and (0.59, 0.39).

21. The white light illumination system of claim 1, wherein the first radiation source emits in wavelengths ranging from about 390 nm to about 410 nm.

22. The white light illumination system of claim 1, wherein the second radiation source emits in wavelengths ranging from about 445 nm to about 455 nm.

23. The white light illumination system of claim 1, wherein the phosphor package is encapsulated with the first and second radiation sources.

24. The white light illumination system of claim 1, wherein the phosphor package is remote from the first and second radiation sources.

25. The white light illumination system of claim 1, wherein the white light illumination system is a display backlighting system.

26. The white light illumination system of claim 1, wherein a final light product generated by the white light illumination system comprises photoluminescence from the phosphor package and light generated by the second radiation source, but not light generated by the first radiation source.

27. A white light illumination system comprising:

a phosphor package;

a first radiation source for providing co-excitation radiation to the phosphor package, the source emitting in wavelengths ranging from about 250 nm to about 410 nm;

a second radiation source for providing co-excitation radiation to the phosphor package, the source emitting in wavelengths ranging from about 410 nm to about 540 nm; and

wherein the phosphor package is configured to emit photoluminescence comprising light with wavelengths ranging from about 440 nm to about 700 nm upon co-excitation from the first and second radiation sources, and wherein the phosphor package comprises a green phosphor with chromaticity coordinates CIE (x, y) within an area of CIE 1931 xy chromaticity diagram defined by a simple quadrilateral with vertices (0.61, 0.39), (0.70, 0.30), (0.68, 0.30) and (0.59, 0.39).

28. The white light illumination system of claim 27, wherein said phosphor package further comprises a red phosphor, said red phosphor having chromaticity coordinates CIE (x, y) within an area of CIE 1931 xy chromaticity diagram defined by a simple quadrilateral with vertices (0.61, 0.39), (0.70, 0.30), (0.68, 0.30) and (0.59, 0.39).

29. A color display comprising:

a display panel comprising a plurality of red, green and blue pixel areas;

a white light illumination system; and

a color filter plate located on a side of the display panel that is distal to the white light illumination system, wherein the color filter plate comprises at least one of;

first filter areas corresponding to red pixel areas of the display that are operable to allow the passage of red light;

second filter areas corresponding to green pixel areas of the display that are operable to allow the passage of green light; and

third filter areas corresponding to blue pixel areas of the display that are operable to allow the passage of blue light;

wherein the white light illumination system comprises;

a phosphor package;

a first radiation source for providing co-excitation radiation to the phosphor package, the source emitting in wavelengths ranging from about 250 nm to about 410 nm;

a second radiation source for providing co-excitation radiation to the phosphor package, the source emitting in wavelengths ranging from about 410 nm to about 540 nm; and

wherein the phosphor package is configured to emit photoluminescence in wavelengths ranging from about 440 nm to about 700 nm upon co-excitation from the first and second radiation sources, and wherein the phosphor package comprises at least one narrow band green phosphor with a photoluminescence peak with a full width at half maximum of less than 60 nm, and wherein the narrow band green phosphor is configured to emit photoluminescence in wavelengths ranging from about 500 nm to about 550 nm.

30. A photoluminescence color display comprising:

a display panel comprising a plurality of red, green and blue pixel areas;

an excitation source operable to generate excitation radiation for operating the display, said excitation source comprising;

a first radiation source emitting in wavelengths ranging from about 250 nm to about 410 nm;

a second radiation source emitting in wavelengths ranging from about 410 nm to about 540 nm;

a photoluminescence color-elements plate comprising at least one of;

a first photoluminescence material corresponding to red pixel areas of the display that is operable to emit red light in response to said excitation radiation;

a second photoluminescence material corresponding to green pixel areas of the display that is operable to emit green light in response to said excitation radiation; and

a third photoluminescence material corresponding to blue pixel areas of the display that is operable to emit blue light in response to said excitation radiation; and

a color filter plate located on a side of the display panel that is distal to the white light illumination system, wherein the color filter plate comprises at least one of;

first filter areas corresponding to red pixel areas of the display that are operable to allow the passage of red light;

second filter areas corresponding to green pixel areas of the display that are operable to allow the passage of green light; and

third filter areas corresponding to blue pixel areas of the display that are operable to allow the passage of blue light;

wherein the second photoluminescence material comprises at least one narrow band green phosphor with a photoluminescence peak with a full width at half maximum of less than 60 nm, and wherein the narrow band green phosphor is configured to emit photoluminescence in wavelengths ranging from about 500 nm to about 550 nm.