Spectrometer Devices

• US 20140061486A1
• Filed: 02/21/2013
• Published: 03/06/2014
• Est. Priority Date: 02/21/2012
• Status: Abandoned Application

• Current Assignee: Massachusetts Institute of Technology
• Original Assignee: Massachusetts Institute of Technology
• Inventors: Bao, Jie, Bawendi, Moungi G.
• Application Number:
  US13/773,108
• Publication Number:
  US 20140061486A1
• Time in Patent Office: Days
• US Class Current: 250/370.01
• CPC Class Codes: B82Y 15/00 Nanotechnology for interacting, sensing or actuating, e.g. quantum dots as markers in protein assays or molecular motors
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: G01J 1/429 applied to measurement of ultraviolet light using counting tubes G01T
• CPC Class Codes: G01J 2003/1217 Indexed discrete filters or choppers
• CPC Class Codes: G01J 3/0213 using attenuators
• CPC Class Codes: G01J 3/28 Investigating the spectrum using colour filters G01J3/51
• CPC Class Codes: G01J 3/2803 using photoelectric array detector
• CPC Class Codes: G01J 3/513 having fixed filter-detector pairs
• CPC Class Codes: G01N 21/253 for batch operation, i.e. multisample apparatus analytical automats G01N35/00
• CPC Class Codes: G02B 1/02 made of crystals, e.g. rock-salt, semi-conductors G02B1/08 takes precedence
• CPC Class Codes: G02B 2207/101 Nanooptics
• CPC Class Codes: Y10T 29/49 Method of mechanical manufacture

Abstract

A spectrometer can include a plurality of semiconductor nanocrystals. Wavelength discrimination in the spectrometer can be achieved by differing light absorption and emission characteristics of different populations of semiconductor nanocrystals (e.g., populations of different materials, sizes or both). The spectrometer therefore can operate without the need for a grating, prism, or a similar optical component. A personal UV exposure tracking device can be portable, rugged, and inexpensive, and include a semiconductor nanocrystal spectrometer for recording a user'"'"'s exposure to UV radiation. Other applications include a personal device (e.g. a smartphone) or a medical device where a semiconductor nanocrystal spectrometer is integrated.

Claims

1. A spectrometer comprising:

a plurality of detector locations, wherein each detector location includes a plurality of semiconductor nanocrystals capable of absorbing a predetermined wavelength of light, and wherein each detector location includes a photosensitive element capable of providing a differential response based on differing intensity of incident light; and

a data recording system connected to each of the photosensitive elements, wherein the data recording system is configured to record the differential responses at each of the detector locations when the detector locations are illuminated by incident light.

2. The spectrometer of claim 1, wherein the plurality of semiconductor nanocrystals at each detector location is capable of absorbing a different predetermined wavelength of light.

3. The spectrometer of claim 1, wherein the photosensitive elements are photovoltaic cells.

4. The spectrometer of claim 1, wherein the photosensitive elements are photoconductors.

5. The spectrometer of claim 1, wherein the semiconductor nanocrystals, after absorbing the predetermined wavelength of light, are capable of emitting a distinct wavelength of light, and wherein the photosensitive element is sensitive to the distinct wavelength of light.

6. The spectrometer of claim 1, wherein the semiconductor nanocrystals are configured to absorb substantially all of the predetermined wavelength of light incident at a particular detector location, and substantially incapable of emitting a distinct wavelength of light.

7. A method of recording a spectrogram, comprising:

providing a spectrometer comprising;

a plurality of detector locations, wherein each detector location includes a plurality of semiconductor nanocrystals capable of absorbing a predetermined wavelength of light, and wherein each detector location includes a photosensitive element capable of providing a differential response based on differing intensity of incident light; and

a data recording system connected to each of the photosensitive elements, wherein the data recording system is configured to record the differential responses at each of the detector locations when the detector locations are illuminated by incident light;

illuminating the plurality of detector locations with incident light;

recording the differential responses at each of the detector locations; and

determining the intensity of a particular wavelength of incident light based on the recorded differential responses at each of the detector locations.

8. A personal UV exposure tracking device, comprising:

a UV detector that can discriminate between different wavelengths in the UV region; and

a data recording system configured to record differential responses to the different wavelengths in the UV region when the detector locations are illuminated by incident light.

9. The personal UV exposure tracking device of claim 8, wherein the UV detector is a UV sensitive semiconductor photodetector.

10. The personal UV exposure tracking device of claim 8, wherein the UV photodetector is a photodetector array.

11. The personal UV exposure tracking device of claim 8, wherein the UV detector is a nanocrystal spectrometer.

12. The personal UV exposure tracking device of claim 11, wherein the nanocrystal spectrometer includes:

a plurality of detector locations, wherein each detector location includes a plurality of semiconductor nanocrystals capable of absorbing a predetermined wavelength of light, and wherein each detector location includes a photosensitive element capable of providing a differential response based on differing intensity of incident light; and

the data recording system is connected to each of the photosensitive elements, wherein the data recording system is configured to record the differential responses at each of the detector locations when the detector locations are illuminated by incident light.

13. The personal UV exposure tracking device of claim 8, wherein the spectrometer is configured to measure the intensity of one or more UV wavelengths of incident light.

14. The personal UV exposure tracking device of claim 13, wherein the spectrometer is configured to measure the intensity of UVA, UVB, and UVC wavelengths of incident light.

15. The personal UV exposure tracking device of claim 8, further comprising a data storage component configured to record the measured intensity of one or more UV wavelengths of incident light.

16. The personal UV exposure tracking device of claim 8, further comprising a wireless data communication system configured to transmit the measured intensity of one or more UV wavelengths of incident light to an external computing device.

17. The personal UV exposure tracking device of claim 8, wherein the device is configured to provide a real time measurement of UV exposure to a user.

18. The personal UV exposure tracking device of claim 8, wherein the device is configured to provide a historical report of UV exposure to a user.

19. The personal UV exposure tracking device of claim 8, wherein the device is integrated in a portable personal item.

20. The personal UV exposure tracking device of claim 19, wherein the portable personal item is waterproof.

21. A spectrometer comprising:

a plurality of detector locations, wherein each detector location includes a light absorptive material capable of absorbing a predetermined wavelength of light, the light absorptive material being selected from the group consisting of a semiconductor nanocrystal, a carbon nanotube and a photonic crystal, and wherein each detector location includes a photosensitive element capable of providing a differential response based on differing intensity of incident light; and

a data recording system connected to each of the photosensitive elements, wherein the data recording system is configured to record the differential responses at each of the detector locations when the detector locations are illuminated by incident light.

22. The spectrometer of claim 21, wherein the plurality of detector locations includes a filter including a semiconductor nanocrystal.

23. The spectrometer of claim 21, wherein the photosensitive element includes a semiconductor nanocrystal.

24. The spectrometer of claim 21, wherein the plurality of detector locations includes a filter including a first semiconductor nanocrystal through which light passes prior to the photosensitive element, the photosensitive element including a second semiconductor nanocrystal.

25. A method of making a spectrometer comprising:

creating a plurality of detector locations, wherein each detector location includes a light absorptive material capable of absorbing a predetermined wavelength of light, the light absorptive material being selected from the group consisting of a semiconductor nanocrystal, a carbon nanotube and a photonic crystal, and wherein each detector location includes a photosensitive element capable of providing a differential response based on differing intensity of incident light; and

connecting a data recording system to each of the photosensitive elements, wherein the data recording system is configured to record the differential responses at each of the detector locations when the detector locations are illuminated by incident light.

26. The method of claim 25, wherein creating the plurality of detector locations includes inkjet printing or contact transfer printing the light absorptive material on a substrate.

27. The method of claim 25, wherein creating the plurality of detector locations includes forming a vertical stack of a plurality of semiconductor nanocrystal photo detectors.

28. The method of claim 27, further comprising assembling a plurality of vertical stacks to form a matrix of vertical stacks.

29. A method of making a spectral imaging device comprising:

creating a plurality of detector locations, wherein each detector location includes a light absorptive material capable of absorbing a predetermined wavelength of light, the light absorptive material, and wherein each detector location includes a photosensitive element capable of providing a differential response based on differing intensity of incident light; and

connecting a data recording system to each of the photosensitive elements, wherein the data recording system is configured to record the differential responses at each of the detector locations when the detector locations are illuminated by incident light.

30. The method of claim 29, wherein creating the plurality of detector locations includes forming a vertical stack of absorptive layers, each absorptive layer having a different light absorptive characteristic.

31. The method of claim 29, further comprising assembling a plurality of vertical stacks to form a matrix of vertical stacks.

32. The method of claim 29, wherein creating the plurality of detector locations includes forming a horizontal plate of absorptive patches, each patch having a different light absorptive characteristic.

33. The method of claim 29, wherein the light absorptive material is selected from the group consisting of a semiconductor nanocrystal, a carbon nanotube and a photonic crystal.

34. A plate reader comprising a plurality of spectrometers and a plurality of wells, wherein each well is associated with a unique spectrometer of the plurality of spectrometers, each spectrometer comprising a plurality of detector locations, wherein each detector location includes a light absorptive material capable of absorbing a predetermined wavelength of light, the light absorptive material, and wherein each detector location includes a photosensitive element capable of providing a differential response based on differing intensity of incident light;

and

a data recording system to each of the photosensitive elements, wherein the data recording system is configured to record the differential responses at each of the detector locations when the detector locations are illuminated by incident light.

35. A plate reader of claim 34, wherein the light absorptive material is selected from the group consisting of a semiconductor nanocrystal, a carbon nanotube and a photonic crystal.

36. A personal device comprising a spectrometer comprising:

a plurality of detector locations, wherein each detector location includes a plurality of semiconductor nanocrystals capable of absorbing a predetermined wavelength of light, and wherein each detector location includes a photosensitive element capable of providing a differential response based on differing intensity of incident light; and

a data recording system connected to each of the photosensitive elements, wherein the data recording system is configured to record the differential responses at each of the detector locations when the detector locations are illuminated by incident light.

37. A personal device of claim 36, wherein the device is a smartphone or smartphone attachment.

38. A medical device comprising a spectrometer comprising:

a plurality of detector locations, wherein each detector location includes a plurality of semiconductor nanocrystals capable of absorbing a predetermined wavelength of light, and wherein each detector location includes a photosensitive element capable of providing a differential response based on differing intensity of incident light; and

a data recording system connected to each of the photosensitive elements, wherein the data recording system is configured to record the differential responses at each of the detector locations when the detector locations are illuminated by incident light.