Fabrication and Use of Epidermal Electrodes

• US 20140088397A1
• Filed: 09/17/2013
• Published: 03/27/2014
• Est. Priority Date: 09/18/2012
• Status: Abandoned Application

• Current Assignee: Albert J. Swiston, Bersain A. Reyes, Hugo F. Posada-Quintero, Justin Bales, Ki Chon
• Original Assignee: Albert J. Swiston, Bersain A. Reyes, Hugo F. Posada-Quintero, Justin Bales, Ki Chon
• Inventors: Chon, Ki, Bales, Justin, Swiston, Albert J., Reyes, Bersain A., Posada-Quintero, Hugo F.
• Application Number:
  US14/028,817
• Publication Number:
  US 20140088397A1
• Time in Patent Office: Days
• US Class Current: 600/384
• CPC Class Codes: A61B 2562/0215 Silver or silver chloride containing
• CPC Class Codes: A61B 2562/164 the sensor is mounted in or on a conformable substrate or carrier
• CPC Class Codes: A61B 5/276 Protection against electrode failure
• CPC Class Codes: A61B 5/28 for electrocardiography [ECG]
• CPC Class Codes: B29C 39/10 incorporating preformed parts or layers, e.g. casting around inserts or for coating articles coating a surface by casting in general B05D1/30, B29C39/126 takes precedence
• CPC Class Codes: Y10T 29/49117 Conductor or circuit manufacturing

Abstract

An epidermal electrode operable independently of the ambient environment, such as the presence of water, sweat, or dry conditions, and achieve a suitable impedance with the epidermal surface for transmitting electrical signals indicative of bodily physiological process such as ECG signals for heart monitoring. The hydrophobic surface mountable electrode including a flexible, conductive substrate of PDMS (Polydimethylsiloxane) with dispersed carbon black and having a substantially planar sensing area adapted for communication with an electrically sensitive surface such as a patient'"'"'s skin, and a terminal for connection to a monitor circuit, the terminal having electrical continuity with the planar sensing area.

Claims

1. A surface mountable electrode comprising:

a conductive substrate having a substantially planar sensing area adapted for communication with an electrically sensitive surface;

a terminal for connection to a monitor circuit, the terminal having electrical continuity with the planar sensing area;

the planar sensing area defining an impedance with a sensing surface conducive to electrical monitoring; and

the conductive substrate being flexible for electrical communication upon surface placement on the electrically sensitive surface.

2. The electrode of claim 1 wherein the defined impedance is independent of environmental conditions on the sensing surface.

3. The electrode of claim 2 wherein the defined impedance is substantially constant in wet or dry ambient conditions on the sensing surface.

4. The electrode of claim 2 wherein the conductive substrate includes a composition of a polymer and conductive particles.

5. The electrode of claim 4 wherein the conductive substrate includes a dispersion of carbon black such that the carbon black achieves a density based on a predetermined concentration defined by an ability to conduct an electrical signal through the substrate.

6. The electrode of claim 2 wherein the terminal is mounted to the substrate for connection to a control circuit, the control circuit responsive to the electrode, the electrode adapted to sense electrical signals unaffected by liquid presence on the substrate.

7. The electrode of claim 1 wherein the sensing surface is capable of carrying electrical signals sensed on the electrically sensitive surface from the sensing surface to the monitor circuit.

8. The electrode of claim 7 wherein the sensing surface is adapted to maintain a substantially constant impedance with the electrically sensitive surface independently of a mounting environment.

9. The electrode of claim 8 wherein the mounting environment is a human epidermis and the electrode is unaffected by sweat and water.

10. The electrode of claim 9 wherein the mounting environment is submerged underwater and the electrode is affixed to a cardiac region of a subject, the cardiac region for transmitting cardiac rhythms to the sensing circuit via the electrode.

11. The electrode of claim 2 wherein the conductive substrate is a homogeneous structure having a planar contact surface and an integrated electrode, the homogeneous structure formed around the terminal for passing electrical signals from the planar contact surface through the electrode to the control circuit.

12. The electrode of claim 2 wherein the defined impedance of the substrate is proportional to the area of the planar surface, such that the strength of a sensed electrical signals increases with the area.

13. A method for fabricating a surface mount electrode comprising the steps of:

combining a polymeric compound with a conductive medium;

adding a solvent to form a fluidic composition adapted to formation in a mold;

forming the composition into substantially planar shapes having a planar sensing area responsive to electrical signals on a sensing surface; and

inserting a terminal into the formed planar shape, the terminal configured for electrical connection to a monitor circuit.

14. The method of claim 13 wherein the composition is adapted to form conductive agglomerations based on a density of the dispersed conductive medium.

15. The method of claim 14 wherein the polymeric compound includes PDMS and the conductive medium is carbon black powder.

16. The method of claim 13 further comprising dissolving a predetermined quantity of Trifluropropyl POSS (FPOSS) into 50 ml of Asahiklin;

and

adding the FPOSS solution to the composition.

17. The method of claim 16 wherein the predetermined quantity of FPOSS is in the range of 5-50 mg FPOSS per 50 ml of Asahiklin.

18. The method of claim 14 further comprising affixing the electrodes to underwater divers and receiving signals indicative of a respiration of the underwater diver.

19. The method of claim 18 further comprising monitoring the signals received from the underwater divers for detecting symptoms of decompression sickness (DCS)., i.e. bloodstream borne gas bubbles.

20. The method of claim 19 further comprising computing a heart rate variability (HRV) based on variances of distance between the peaks of the monitored signals, and identifying DCS based on the variances

21. The method of claim 14 further comprising

affixing an electrode to an underside of a wristwatch appliance in communication with the wrist epidermis for sensing cardiac signals;

affixing a complementary electrode on an epidermis of an opposed wrist for sensing a complementary signal; and

performing continuous monitoring of the cardiac signals obtained via the electrode and complementary electrode; and

storing the monitored signals in the wristwatch for subsequent analysis.

22. The method of claim 21 wherein the monitored signals detect and define continuous measurement of paroxysmal arterial fibrillation (abnormal heartbeat).

23. A method for fabricating a surface mount electrode comprising the steps of:

dispersing conductive carbon black powder into room temperature polydimethylsiloxane (PDMS), the PDMS providing an insulating matrix;

combining C6H14 (hexane) as a solvent to mix the carbon black with the PDMS to distribute particles of the resulting solution;

placing the hexane/carbon black solution and PDMS in an ultrasonic cleaner;

mixing a curing agent in a 10;

1 mass ratio;

pouring and leveling the mixture with a straight metal edge into wells forming disks within the electrode molds;

applying the mixture to a reverse side of nickel plated snap fasteners appropriately sized for monitor connection;

degassing in a vacuum chamber to remove air bubbles;

affixing to the molded carbon black/PDMS/curing agent mixture by placing the electrodes on the surface with gentle pressure without causing major rippling;

mixing a final layer of PDMS/curing agent solution was mixed and pouring into the top of the mold as a backing to the electrode;

curing in an oven at 70°

C. for 12 hours.