CHEMILUMINESCENT DETECTOR HAVING COATING TO REDUCE EXCITED SPECIES ADSORPTION

• US 20140119993A1
• Filed: 12/18/2012
• Published: 05/01/2014
• Est. Priority Date: 10/25/2012
• Status: Active Grant

• Current Assignee: Agilent Technologies, Inc.
• Original Assignee: Agilent Technologies, Inc.
• Inventors: RHODES, Robert P.
• Granted Patent: US 11,002,684 B2
• Time in Patent Office: Days
• US Class Current: 422/52
• CPC Class Codes: G01N 21/766 of gases

Abstract

An apparatus for receiving a chemical species is disclosed. The apparatus includes an emission block configured to receive a vapor phase chemical species that is excited by chemical reaction in the emission block to provide an excited species that emits hot. The emission block has an interior portion having a surface. A coating is disposed over the surface and the coating reduces adsorption of the excited species onto the surface.

Claims

1. An apparatus for receiving a chemical species, the apparatus comprising:

an emission block configured to receive a vapor phase chemical species that is excited by

chemical reaction in the emission block to provide an excited species that emits light, the

emission block having an interior portion having a surface; and

a coating disposed over the surface, wherein the coating reduces adsorption of the excited species onto the surface.

2. An apparatus as claimed in claim 1, wherein the excited species comprises sulfur.

3. An apparatus as claimed in claim 1, wherein the excited species comprises nitrogen.

4. An apparatus as claimed in claim 1, wherein the excited species comprises phosphorus.

5. An apparatus as claimed in claim 1, wherein the coating comprises silicon.

6. An apparatus as claimed in claim 5, wherein the coating further comprises chemically modified silicon.

7. An apparatus as claimed in claim 6, wherein the chemically modified silicon comprises an organic material.

8. An apparatus as claimed in claim 1, wherein the coating comprises hydrogenated amorphous silicon.

9. An apparatus as claimed in claim 8, wherein the hydrogenated amorphous silicon is modified with an organic material.

10. An apparatus as claimed in claim 1, wherein the coating comprises a fluoropolymer.

11. An apparatus as claimed in claim 1, wherein the vapor phase species is received from a gas chromatograph (GC).

12. An apparatus as claimed in claim 1, further comprising a transfer line comprising a first end and a second end opposing the first end, wherein the vapor phase is received at the emission block from the second end.

13. An apparatus as claimed in claim 12, further comprising:

a block heater disposed around a first portion of the transfer line, the block heater comprising a heater configured to maintain the first portion of the transfer line at a first temperature range; and

a body tube substantially surrounding a second portion of the transfer line, the body tube mechanically and thermally coupled to the emission block, wherein the emission block and the body tube are maintained at a second temperature range that is lower than the first temperature range, and the second portion of the transfer line is maintained at the first temperature range.

14. An apparatus as claimed in claim 13, wherein the body tube is brazed to the transfer line and to the emission block.

15. An apparatus as claimed in claim 13, wherein the heater is a first heater and the emission block comprises a second heater configured to maintain the emission block at the second temperature range.

16. An apparatus as claimed in claim 15, further comprising a controller configured to maintain the second heater so that the emission block is maintained at the second temperature range.

17. An apparatus as claimed in claim 13, further comprising a jet housing disposed around the second portion of the transfer line, wherein the jet housing is brazed to the transfer line.

18. An apparatus as claimed in claim 17, wherein the body tube is brazed to the emission block at a first end of the body tube, and the body tube is brazed to the jet housing at a second end of the body tube.

19. An apparatus as claimed in claim 1, wherein the apparatus is a flame photometric detector.

20. An apparatus as claimed in claim 1, wherein the apparatus is a chemiluminescence detector.