COLD-ROLLED STEEL PLATE COATED WITH ZINC OR A ZINC ALLOY, METHOD FOR MANUFACTURING SAME, AND USE OF SUCH A STEEL PLATE

• US 20140120371A1
• Filed: 05/17/2012
• Published: 05/01/2014
• Est. Priority Date: 06/07/2011
• Status: Abandoned Application

• Current Assignee: Arcelormittal Investigacion Y Desarrollo, S.l. (ArcelorMittal SA)
• Original Assignee: Arcelormittal Investigacion Y Desarrollo, S.l. (ArcelorMittal SA)
• Inventors: Moulin, Antoine, Mbacke, Papa Amadou Mactar
• Application Number:
  US14/124,940
• Publication Number:
  US 20140120371A1
• Time in Patent Office: Days
• US Class Current: 428/659
• CPC Class Codes: B23K 11/11 Spot welding
• CPC Class Codes: B32B 15/013 one layer being formed of an iron alloy or steel, another layer being formed of a metal other than iron or aluminium
• CPC Class Codes: C21D 1/20 Isothermal quenching, e.g. bainitic hardening
• CPC Class Codes: C21D 2211/001 Austenite
• CPC Class Codes: C21D 2211/002 Bainite
• CPC Class Codes: C21D 2211/005 Ferrite
• CPC Class Codes: C21D 2211/008 Martensite
• CPC Class Codes: C21D 8/0247 characterised by the heat treatment
• CPC Class Codes: C21D 9/46 for sheet metals
• CPC Class Codes: C22C 38/02 containing silicon
• CPC Class Codes: C22C 38/04 containing manganese
• CPC Class Codes: C22C 38/06 containing aluminium
• CPC Class Codes: C22C 38/12 containing tungsten, tantalum, molybdenum, vanadium, or niobium
• CPC Class Codes: C23C 2/02 Pretreatment of the material to be coated, e.g. for coating on selected surface areas C23C2/30 takes precedence
• CPC Class Codes: C23C 2/0224 Two or more thermal pretreatments
• CPC Class Codes: C23C 2/024 by cleaning or etching
• CPC Class Codes: Y10T 428/12799 Next to Fe-base component [e.g., galvanized]

Abstract

The present invention provides a “TRIP effect” cold-rolled and annealed steel sheet which has improved formability and weldability, strength between 780 and 900 MPa and elongation at fracture greater than 19%, the composition of which includes the following elements in percentages expressed by weight: 0.17%≦C≦0.25%, 1.5%≦Mn≦2%, 0.50%≦Si≦1%, 0.50%≦Al≦1.2%, whereby Si+Al≧1.30%, the remainder of the composition including iron and the inevitable impurities resulting from processing. The microstructure of the sheet includes 65 to 85% ferrite and 15 to 35% islands of martensite and residual austenite. The average size of these islands of martensite and residual austenite is less than 1.3 micrometers and their shape factor is less than 3.

Claims

1-17. -17. (canceled)

18. A cold-rolled steel sheet coated with zinc or zinc alloy, the composition of which includes the following, expressed by weight:

0.17%≦

C≦

0.25%

1.5%≦

Mn≦

2.0%

0.50%≦

Si≦

1%

0.50%≦

Al≦

1.2%

B≦

0.001%

P≦

0.030%

S≦

0.01%

Nb≦

0.030%

Ti≦

0.020%

V≦

0.015%

Cu≦

0.1%

Cr≦

0.150%

Ni≦

0.1%

0%≦

Mo≦

0.150%

whereby Si+Al≧

1.30%,

the remainder of the composition consists of iron and the inevitable impurities resulting from processing,

a microstructure of the composition includes, with the contents expressed in area percentage;

of 65 to 85% ferrite, and

of 15 to 35% islands of martensite and residual austenite, the ferrite containing less than 5% non-recrystallized ferrite, a total content of residual austenite being between 10 and 25% and a total martensite content being less than or equal to 10%, an average size of the martensite and residual austenite islands being less than 1.3 micrometers, and an average shape factor of the islands being less than 3,

a mechanical strength Rm of the sheet being between 780 and 900 MPa, and an elongation at fracture A % being greater than or equal to 19%.

19. The steel sheet as recited in claim 18, wherein the composition includes the following, expressed by weight,

0.19%≦

C≦

0.23%.

20. The steel sheet as recited in claim 18, wherein the composition includes the following, expressed by weight,

1.6%≦

Mn≦

1.8%.

21. The steel sheet as recited in claim 18, wherein the composition includes the following, expressed by weight,

0.7%≦

Si≦

0.9. %

22. The steel sheet as recited in claim 18, wherein the composition includes the following, expressed by weight,

0.6%≦

Al≦

0.8%.

23. The steel sheet as recited in claim 18, wherein the composition includes the following, expressed by weight,

0%<

B≦

0.0005%.

24. The steel sheet as recited in claim 18, wherein more than 90% in area percentage of the martensite and residual austenite islands have a size less than or equal to two micrometers.

25. A method for the fabrication of a steel sheet cold rolled and coated with zinc or zinc alloy, comprising the following steps:

procuring a steel having the composition recited in claim 18;

casting the steel in a form of a semi-finished product;

heating the semi-finished product to a temperature between 1150 and 1250°

C.;

hot rolling the semi-finished product, finishing the rolling at an end-of-rolling temperature T_FL greater than or equal to Ar3 to obtain a sheet;

coiling the hot rolled sheet at a temperature T_bob between 500 and 600°

C.;

cooling the hot rolled sheet to an ambient temperature;

cold rolling the sheet;

reheating the cold-rolled sheet at a rate V_c between 1 and 30°

C./s to a temperature T_r for a length of time t_r which is greater than or equal to 15 seconds, the temperatures and times being selected to obtain an area percentage of between 35 and 70% austenite;

cooling the cold-rolled sheet to a temperature T_eg between 475 and 440°

C. at a rate V_ref which is sufficiently rapid to prevent a formation of pearlite;

holding the cold-rolled sheet at the equalization temperature T_eg for a length of time t_eg between 20 and 120 seconds;

coating the cold-rolled sheet by continuous hot-dipping in a bath of zinc or zinc alloy;

cooling the cold-rolled, coated sheet to the ambient temperature.

26. The method for the fabrication of the sheet as recited in claim 25, wherein the temperature T_FL is greater than 900°

C.

27. The method for the fabrication of the sheet as recited in claim 25, wherein the temperature T_FL is greater than 920°

C.

28. The method for the fabrication of the sheet as recited in claim 25, wherein a dew point during the annealing at the temperature T_r for the time t_r is between −

20°

C. and −

15°

C.

29. The method for the fabrication of the steel sheet as recited in claim 25, wherein the temperature T_r is between Ac1+50°

C. and Ac3−

50°

C.

30. The method for the fabrication of the steel sheet as recited in claim 25, wherein the temperature Tr is between Ac1+50°

C. and Ac1+170°

C.

31. The method for the fabrication of the steel sheet as recited in claim 25, wherein the time t_eg is between 30 and 80 seconds.

32. The method for the fabrication of the steel sheet as recited in claim 25, for which said time t_eg is between 30 and 60 seconds.

33. A method for the fabrication of a part comprising:

welding of at least one sheet cold rolled and coated as recited in claim 18 by resistance spot welding.

34. A method for the fabrication of a part comprising:

welding of at least one sheet obtained by the method recited in claim 25 by resistance spot welding.

35. A structural or safety part for ground motor vehicles comprising:

a steel sheet cold rolled and coated as recited in claim 18.

36. A method for the fabrication of structural or safety parts for ground motor vehicles comprising:

obtaining the steel sheet cold rolled and coated as recited in claim 25.

37. The method for the fabrication of the steel sheet as recited in claim 25, further comprising pickling the hot rolled sheet.

38. The method for the fabrication of the steel sheet as recited in claim 25, wherein the steps are performed successively.