COATINGS, COMPOSITION AND METHOD RELATED TO NON-SPALLING LOW DENSITY HARDFACE COATINGS

• US 20140134452A1
• Filed: 03/13/2013
• Published: 05/15/2014
• Est. Priority Date: 02/03/2009
• Status: Active Grant

• Current Assignee: Hybrid Materials LLC
• Original Assignee: MesoCoat, Inc. (Abakan, Inc.)
• Inventors: Sherman, Andrew, Glasgow, Curt
• Granted Patent: US 9,376,573 B2
• Time in Patent Office: Days
• US Class Current: 428/614
• CPC Class Codes: B22F 7/08 with one or more parts not made from powder B22F7/062 takes precedence
• CPC Class Codes: C09D 1/00 Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
• CPC Class Codes: C22C 29/00 Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides C22C26/00 takes precedence
• CPC Class Codes: C22C 29/02 based on carbides or carbonitrides
• CPC Class Codes: C23C 14/223 specially adapted for coating particles
• CPC Class Codes: C23C 4/067 containing free particles of non-metal elements, e.g. carbon, silicon, boron, phosphorus or arsenic
• CPC Class Codes: Y10T 428/12486 Laterally noncoextensive components [e.g., embedded, etc.]

Abstract

A heterogeneous composite body that is spall resistant and comprises a substantially discontinuous cermet phase in a substantially continuous metal rich matrix phase. The heterogeneous composite body is typically bonded to a substrate to form a hardfacing on the substrate. The heterogeneous composite body exhibits ductile phase toughening with a strain to failure of at least about 2 percent, a modulus of elasticity of less than about 35 million pounds per square inch, and a density of less than about 7 grams per cubic centimeter. The metal rich matrix phase between the ceramic rich regions in the heterogeneous composite body has an average minimum span of about 0.5 to 8 microns to allow ductility in the heterogeneous composite body. The heterogeneous composite body has a Vicker'"'"'s hardness number of greater than approximately 500. The ceramic rich regions exhibit high hardness as compared with the matrix phase.

Claims

1. A heterogeneous composite body adhered to a substrate with an adhesive strength of greater than about 10,000 pounds per square inch gauge, said heterogeneous composite body being spall resistant and comprising a discontinuous cermet phase formed by cermet regions in a metal rich matrix phase, said metal rich matrix phase having an average span between said cermet regions sufficient to permit said metal rich matrix phase to work harden, said discontinuous cermet phase including ceramic particles and a cermet binder, said ceramic particles having a Moh'"'"'s hardness of at least approximately 7.5, a modulus of less than approximately 46,000,000 pounds per square inch, and an average particle size of from about 0.1 to 10 microns, said heterogeneous composite body having a Vicker'"'"'s hardness number of greater than approximately 500, a strain to failure of more than 1 percent, exhibits residual stresses of generally between approximately 5,000 pounds per square inch compressive and approximately 3,000 pounds per square inch tensile, and a modulus of less than approximately 35,000,000 pounds per square inch.

2. A heterogeneous composite body of claim 1 wherein said heterogeneous composite body exhibits said residual stresses of generally between approximately 2,000 pounds per square inch compressive and approximately neutral tensile.

3. A heterogeneous composite body of claim 1 wherein said heterogeneous composite body has a strain to failure of from about 2 to 6 percent.

4. A heterogeneous composite body of claim 1 wherein said heterogeneous composite body has a modulus of from approximately 35,000,000 to 15,000,000 pounds per square inch.

5. A heterogeneous composite body of claim 1 wherein said cermet binder comprises a metal.

6. A heterogeneous composite body of claim 1 wherein said metal rich matrix phase comprises at least one of nickel, iron, copper, cobalt, silicon, alloys thereof with one another or with chromium, tungsten or molybdenum.

7. A heterogeneous composite body of claim 1 wherein said heterogeneous composite body has a density of less than about 6 grams per cubic centimeter.

8. A heterogeneous composite body of claim 1 wherein said heterogeneous composite body has a strain to failure of from about 1 to 6 percent.

9. A heterogeneous composite body of claim 1 wherein said ceramic particles comprise at least one of a nitride, an oxynitride, or a carbonitride.

10. A heterogeneous composite body of claim 1 wherein said ceramic particles comprise at least one of Si₃N₄, zircon, mullite, VN, V₂N, CrN, Cr₂N, ZrN, Nb₂N, SiCN, or SiON.

11. A heterogeneous composite body of claim 1 wherein said heterogeneous composite body has a modulus of from approximately 30,000,000 to 20,000,000 pounds per square inch.

12. A heterogeneous composite body of claim 1 wherein said metal rich matrix phase has an average span of about 0.4 to 8 microns.

13. A heterogeneous composite body of claim 1 wherein said metal rich matrix phase has an average span of less than about 2 microns.

14. A heterogeneous composite body of claim 1 wherein said discontinuous cermet phase generally comprises a plurality of approximately parallel extending lenticular shaped islands embedded in said metal rich matrix phase.

15. A heterogeneous composite body of claim 1 wherein said ceramic particles have an average particle size of from about 0.3 to 8 microns.

16. A heterogeneous composite body, said heterogeneous composite body being spall resistant and adhered to a substrate with an adhesive strength of greater than about 10,000 pounds per square inch gauge, said heterogeneous composite body comprising a discontinuous cermet phase in a metal rich matrix phase, said discontinuous cermet phase including ceramic particles and a cermet binder, said ceramic particles having a Moh'"'"'s hardness of at least approximately 8, a modulus of less than approximately 46,000,000 pounds per square inch, and an average particle size of from about 0.1 to 10 microns, said heterogeneous composite body having a Vicker'"'"'s hardness number of greater than approximately 650, a strain to failure of at least about 2 percent, said heterogeneous composite body exhibiting strain tolerance wherein defects work harden and redirect strain away from a deformation zone, a density of less than about 7 grams per cubic centimeter, and a modulus of less than approximately 35,000,000 pounds per square inch, and said metal rich matrix phase having an average span sufficient to permit said metal rich matrix phase to work harden.

17. A heterogeneous composite body, said heterogeneous composite body being spall resistant and adhered to a substrate with an adhesive strength of greater than about 10,000 pounds per square inch gauge, said heterogeneous composite body comprising a discontinuous cermet phase in a metal rich matrix phase, said metal rich matrix phase having a modulus of less than approximately 42,000,000 pounds per square inch, said discontinuous cermet phase including ceramic particles and a cermet binder, said ceramic particles having a Moh'"'"'s hardness of at least approximately 8, a modulus of less than approximately 46,000,000 pounds per square inch, and an average particle size of from about 0.3 to 8 microns, said heterogeneous composite body having a Vicker'"'"'s hardness number of greater than approximately 750, a strain to failure of from at least about 2 to about 6 percent, said heterogeneous composite body exhibiting strain tolerance wherein defects work harden and redirect strain away from a deformation zone, a density of less than about 6 grams per cubic centimeter, residual stresses of generally between approximately 5,000 pounds per square inch compressive and approximately 3,000 pounds per square inch tensile, and a modulus of less than approximately 35,000,000 pounds per square inch, and said metal rich matrix phase has an average span of about 0.5 to 2 microns.

18. A heterogeneous composite body adhered to a substrate with an adhesive strength of greater than about 10,000 pounds per square inch gauge, said heterogeneous composite body being spall resistant and comprising a discontinuous cermet phase in a metal rich matrix phase, said discontinuous cermet phase including ceramic particles and a cermet binder, said metal rich matrix phase having an average span of about 0.4 to 8 microns and a modulus of less than approximately 42,000,000 pounds per square inch, said heterogeneous composite body having a Vicker'"'"'s hardness number of greater than approximately 650, a strain to failure of at least about 2 percent, said heterogeneous composite body exhibiting strain tolerance wherein defects work harden and redirect strain away from a deformation zone, and a modulus of less than approximately 35,000,000 pounds per square inch, there being little strain mismatch between said substrate and said heterogeneous composite body.

19. A heterogeneous composite body of claim 18 wherein said heterogeneous composite body exhibits residual stresses of generally between approximately 5,000 pounds per square inch compressive and approximately 3,000 pounds per square inch tensile.

20. A heterogeneous composite body of claim 18 wherein said ceramic particles have a modulus of less than approximately 40 million pounds per square inch.