ALKALI METAL CELL, ATOMIC OSCILLATOR, AND ALKALI METAL CELL FABRICATING METHOD

• US 20140139294A1
• Filed: 11/18/2013
• Published: 05/22/2014
• Est. Priority Date: 11/21/2012
• Status: Active Grant

• Current Assignee: Ricoh Company Limited
• Original Assignee: Ricoh Company Limited
• Inventors: Harasaka, Kazuhiro, Adachi, Kazuhiko, Shouji, Hiroyoshi, Itoh, Akihiro, Sato, Shunichi, Satoh, Shinji
• Granted Patent: US 9,201,404 B2
• Time in Patent Office: Days
• US Class Current: 331/1.R
• CPC Class Codes: G04F 5/145 using Coherent Population Trapping
• CPC Class Codes: H03B 17/00 Generation of oscillations using radiation source and detector, e.g. with interposed variable obturator
• CPC Class Codes: H03L 7/26 using energy levels of molecules, atoms, or subatomic particles as a frequency reference

Abstract

An alkali metal cell is disclosed, including a substrate in which is formed an opening which penetrates from one face to the other face thereof; a first transparent substrate bonded to the other face of the substrate; and a second transparent substrate bonded to the one face of the substrate, wherein an alkali metal is sealed into a space surrounded by the first transparent substrate and the second transparent substrate in the opening of the substrate, wherein, in the substrate and the second transparent substrate, the space is enclosed by a bonding between a first bonding metal layer formed by a first bonding metal and a second bonding metal layer formed by a second bonding metal, and wherein the second bonding metal layer has a bonding temperature higher than that of the first bonding metal layer.

Claims

1. An alkali metal cell, comprising:

a substrate in which is formed an opening which penetrates from one face to the other face thereof;

a first transparent substrate bonded to the other face of the substrate; and

a second transparent substrate bonded to the one face of the substrate, wherein an alkali metal is sealed into a space surrounded by the first transparent substrate and the second transparent substrate in the opening of the substrate, wherein, in the substrate and the second transparent substrate, the space is enclosed by a bonding between a first bonding metal layer formed by a first bonding metal and a second bonding metal layer formed by a second bonding metal, and wherein the second bonding metal layer has a bonding temperature higher than that of the first bonding metal layer.

2. The alkali metal cell as claimed in claim 1, wherein the first bonding metal layer is formed by a material containing Au.

3. The alkali metal cell as claimed in claim 1, wherein the second bonding metal layer is formed by a material containing any one of AuSn, AuGe, and AuSi.

4. The alkali metal cell as claimed in claim 1, wherein an interval between the substrate and the second transparent substrate is the same in an area bonded by the first bonding metal layer and an area bonded by the second bonding metal layer.

5. The alkali metal cell as claimed in claim 4, wherein there is an area which is not bonded by the first bonding metal layer and the second bonding metal layer between the substrate and the second transparent substrate and, in the area which is not bonded, there is a gap which allows alkali metal gas to enter.

6. The alkali metal cell as claimed in claim 1, wherein the first bonding metal is formed by a material containing AuSn.

7. The alkali metal cell as claimed in claim 1, wherein the first bonding metal and the second bonding metal are both formed by a material containing AuSn, wherein the first bonding metal contains more Sn than the second bonding metal.

8. The alkali metal cell as claimed in claim 1, wherein a groove which connects to the opening is formed on the one face of the substrate, and wherein

the substrate is bonded to the second transparent substrate by the second bonding metal layer in the groove.

9. The alkali metal cell as claimed in claim 1, wherein a groove is formed such that a front face side of the one face of the substrate is wider and a bottom face side thereof is narrower.

10. The alkali metal cell as claimed in claim 1, wherein the ether face of the substrate and the first transparent substrate are bonded by anodic bonding or direct bonding.

11. An alkali metal cell fabricating method, comprising the steps of:

forming, in a substrate, two or more openings penetrating the substrate and, on one face of the substrate, a groove which spatially connects the two openings;

bonding a first transparent substrate to the other face of the substrate;

providing a compound containing an alkali metal in one opening of the openings;

forming a first bonding metal layer formed by a first bonding metal in a surrounding of the two or more openings on the one face of the substrate, or in a portion corresponding to the surrounding of the two or more openings on one face of a second transparent substrate;

forming a second bonding metal layer formed by a second bonding metal in the groove of the substrate, or in a portion corresponding to the groove on the one face of the second transparent substrate;

bonding the one face of the substrate and the one face of the second transparent substrate by the first bonding metal layer;

causing the alkali metal to be produced from the compound containing the alkali metal to supply the alkali metal to the other opening via the groove from the one opening; and

bonding the substrate and the second transparent substrate by the second bonding metal layer in the groove after supplying the alkali metal to the other opening.

12. The alkali metal cell fabricating method as claimed in claim 11, wherein a gap between the one opening and the other opening is cut to separate the other opening and an inner part of an alkali metal cell is formed by the separated other opening.

13. The alkali metal cell fabricating method as claimed in claim 11, wherein the second bonding metal has a higher melting temperature than the first bonding metal.

14. The alkali metal cell fabricating method as claimed in claim 11, wherein the first bonding metal is formed by metal fine particles.

15. An alkali metal cell fabricating method, comprising the steps of:

forming, in a substrate, two or more openings which penetrate the substrate;

bonding a first transparent substrate to another face of the substrate;

providing a compound containing an alkali metal in one opening of the openings;

forming a first bonding metal member formed by a first bonding metal around the two or more openings on one face of the substrate, or in a portion corresponding to the two or more openings on one face of a second transparent substrate;

providing a second bonding metal member formed by a second bonding metal in a portion corresponding to a gap between the opening and another opening on one face of the second transparent substrate or on one face of the substrate;

bonding the one face of the substrate and the one face of the second transparent substrate by a first bonding metal layer formed by applying the first bonding metal member;

forming, in between the one face of the substrate and the one face of the second transparent substrate, a gap which spatially connects the one opening and the other opening;

causing the alkali metal to be produced from the compound containing the alkali metal to supply the alkali metal to the other opening via the gap between the substrate and the second transparent substrate from the one opening; and

bonding the substrate and the second transparent substrate by the second bonding metal layer formed by heating the second bonding metal member in a portion corresponding to the gap between the one opening and the other opening after supplying the alkali metal to the other opening.

16. The alkali metal cell fabricating method as claimed in claim 15, wherein a thickness of the second bonding metal member formed by the second bonding metal provided in the portion corresponding to the gap between the one opening and the other opening is smaller than a thickness of the first bonding metal layer.

17. The alkali metal cell fabricating method as claimed in claim 15, wherein the gap between the one opening and the other opening is cut to separate the other opening and an inner part of the alkali metal cell is formed by the separated other opening.

18. The alkali metal cell fabricating method as claimed in claim 15, wherein the first bonding metal is formed by a metal fine particle.

19. The alkali metal cell fabricating method as claimed in claim 18, wherein the metal fine particle is a fine particle formed by a material containing Au;

and wherein a particle diameter of the fine particle is between 0.05 μ

m and 1 μ

m.