Flow Battery And Regeneration System With Improved Safety
First Claim
1. A method for producing electric power from an aqueous multi-electron oxidant and a reducer and for simultaneously generating a discharge fluid, said method comprising:
- providing a discharge system comprising one or more forms of a reducer fluid, one or more forms of an oxidant fluid, a discharge unit, and an acidification reactor, said discharge unit comprising an electrolytic cell stack, said electrolytic cell stack comprising a plurality of electrolytic cells, wherein each of said electrolytic cells comprises an electrolyte-electrode assembly; and
facilitating discharge of said discharge unit for producing said electric power from a neutral oxidant fluid comprising one or more forms of said aqueous multi-electron oxidant, and from said reducer fluid comprising one or more forms of said reducer, said facilitation of said discharge comprising;
lowering pH of said neutral oxidant fluid in said acidification reactor for generating an acidic oxidant fluid;
transferring electrons from a positive electrode of said electrolyte-electrode assembly to said aqueous multi-electron oxidant in said acidic oxidant fluid; and
transferring electrons from said reducer fluid to a negative electrode of said electrolyte-electrode assembly to produce said electric power in an external electric circuit operably connected to terminals of said discharge unit and to generate an acidic discharge fluid on consumption of said acidic oxidant fluid and said reducer fluid.
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Accused Products
Abstract
A method for producing electric power and regenerating an aqueous multi-electron oxidant (AMO) and a reducer in an energy storage cycle is provided. A discharge system includes a discharge unit, an acidification reactor, and a neutralization reactor. The acidification reactor converts an oxidant fluid including the AMO into an acidic oxidant fluid. The discharge unit generates electric power and a discharge fluid by transferring electrons from a positive electrode of an electrolyte-electrode assembly (EEA) to the AMO and from a reducer to a negative electrode of the EEA. The neutralization reactor neutralizes the discharge fluid to produce a neutral discharge fluid. The regeneration system splits an alkaline discharge fluid into a reducer and an intermediate oxidant in a splitting-disproportionation reactor and releases the reducer and a base, while producing the AMO by disproportionating the intermediate oxidant. The regenerated AMO and reducer are supplied to the discharge unit for power generation.
16 Citations
102 Claims
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1. A method for producing electric power from an aqueous multi-electron oxidant and a reducer and for simultaneously generating a discharge fluid, said method comprising:
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providing a discharge system comprising one or more forms of a reducer fluid, one or more forms of an oxidant fluid, a discharge unit, and an acidification reactor, said discharge unit comprising an electrolytic cell stack, said electrolytic cell stack comprising a plurality of electrolytic cells, wherein each of said electrolytic cells comprises an electrolyte-electrode assembly; and facilitating discharge of said discharge unit for producing said electric power from a neutral oxidant fluid comprising one or more forms of said aqueous multi-electron oxidant, and from said reducer fluid comprising one or more forms of said reducer, said facilitation of said discharge comprising; lowering pH of said neutral oxidant fluid in said acidification reactor for generating an acidic oxidant fluid; transferring electrons from a positive electrode of said electrolyte-electrode assembly to said aqueous multi-electron oxidant in said acidic oxidant fluid; and transferring electrons from said reducer fluid to a negative electrode of said electrolyte-electrode assembly to produce said electric power in an external electric circuit operably connected to terminals of said discharge unit and to generate an acidic discharge fluid on consumption of said acidic oxidant fluid and said reducer fluid. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, 22, 23, 24)
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25. A discharge system comprising:
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one or more forms of an oxidant fluid comprising one or more forms of an aqueous multi-electron oxidant; one or more forms of a reducer fluid comprising one or more forms of a reducer; a discharge unit comprising an electrolytic cell stack, said electrolytic cell stack comprising a plurality of electrolytic cells, wherein each of said electrolytic cells comprises an electrolyte-electrode assembly; an acidification reactor operably connected to said discharge unit, said acidification reactor configured to lower pH of a neutral oxidant fluid for generating an acidic oxidant fluid; and said discharge unit configured to produce said electric power from said acidic oxidant fluid and from said reducer fluid by; transferring electrons from a positive electrode of said electrolyte-electrode assembly to said aqueous multi-electron oxidant in said acidic oxidant fluid; and transferring electrons from said reducer fluid to a negative electrode of said electrolyte-electrode assembly to produce said electric power in an external electric circuit operably connected to terminals of said discharge unit and to generate an acidic discharge fluid on consumption of said acidic oxidant fluid and said reducer fluid. - View Dependent Claims (26, 27, 28, 29)
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30. A method for regenerating an aqueous multi-electron oxidant and a reducer in stoichiometric amounts from one or more forms of a neutral discharge fluid using external power, said method comprising:
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converting said neutral discharge fluid into an alkaline discharge fluid by using one or more of an externally supplied base and a base produced in a splitting-disproportionation reactor configured for one of an aqueous multi-electron oxidant-on-negative electrode mode of operation, a no-aqueous multi-electron oxidant-on-negative electrode mode of operation, and a combination thereof; splitting said alkaline discharge fluid into a reducer and an intermediate oxidant in said splitting-disproportionation reactor, wherein said intermediate oxidant is converted into one or more forms of said aqueous multi-electron oxidant via disproportionation of said intermediate oxidant with said base, and wherein said splitting releases a stoichiometric amount of said reducer and said base in said splitting-disproportionation reactor; and continuing said splitting and said disproportionation in said splitting-disproportionation reactor in one of a batch mode of operation, a cyclic flow mode of operation, a cascade flow mode of operation, and a combination thereof until a desired degree of conversion of a discharge product of said aqueous multi-electron oxidant into said one or more forms of said aqueous multi-electron oxidant is achieved. - View Dependent Claims (31, 32, 33, 34, 35, 36, 37, 38, 39, 40, 41, 42, 43, 44, 45)
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46. A regeneration system comprising:
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a splitting-disproportionation reactor configured to convert a neutral discharge fluid into an alkaline discharge fluid by using one or more of an externally supplied base and a base produced in said splitting-disproportionation reactor; said splitting-disproportionation reactor further configured to split said alkaline discharge fluid into a reducer and an intermediate oxidant, wherein said splitting releases a stoichiometric amount of said reducer and said base in said splitting-disproportionation reactor; said splitting-disproportionation reactor further configured to convert said intermediate oxidant into one or more forms of an aqueous multi-electron oxidant via disproportionation of said intermediate oxidant with said base; and said splitting-disproportionation reactor further configured to continue said splitting and said disproportionation in one of a batch mode of operation, a cyclic flow mode of operation, a cascade flow mode of operation, and any combination thereof, until a desired degree of conversion of a discharge product of said aqueous multi-electron oxidant into said one or more forms of said aqueous multi-electron oxidant is achieved. - View Dependent Claims (47, 48, 49, 50, 51)
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52. A regeneration system comprising:
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an electrolysis-disproportionation reactor configured to convert a neutral discharge fluid into an alkaline discharge fluid by using one or more of an externally supplied base and a base produced at one or more negative electrodes of said electrolysis-disproportionation reactor in one of an aqueous multi-electron oxidant-on-negative electrode mode of operation, a no-aqueous multi-electron oxidant-on-negative electrode mode of operation, and a combination thereof; said electrolysis-disproportionation reactor further configured to split said alkaline discharge fluid into a reducer and an intermediate oxidant via electrolysis, wherein said electrolysis releases a stoichiometric amount of said reducer and said base at said one or more negative electrodes of said electrolysis-disproportionation reactor; said electrolysis-disproportionation reactor further configured to convert said intermediate oxidant produced at one or more positive electrodes of said electrolysis-disproportionation reactor into one or more forms of an aqueous multi-electron oxidant via disproportionation of said intermediate oxidant produced at said one or more positive electrodes with said base; and said electrolysis-disproportionation reactor further configured to continue said electrolysis and said disproportionation in one of a batch mode of operation, a cyclic flow mode of operation, a cascade flow mode of operation, and any combination thereof, until a desired degree of conversion of a discharge product of said aqueous multi-electron oxidant into said one or more forms of said aqueous multi-electron oxidant is achieved.
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53. A method for producing electric power and regenerating an aqueous multi-electron oxidant and a reducer in an energy storage cycle, said method comprising:
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providing a discharge system comprising one or more forms of a reducer fluid, one or more forms of an oxidant fluid, a discharge unit, an acidification reactor, and optionally a neutralization reactor, said discharge unit comprising an electrolytic cell stack, said electrolytic cell stack comprising a plurality of electrolytic cells, wherein each of said electrolytic cells comprises an electrolyte-electrode assembly; facilitating discharge of said discharge unit for producing said electric power from a neutral oxidant fluid comprising one or more forms of said aqueous multi-electron oxidant, and from said reducer fluid comprising one or more forms of said reducer, said facilitation of said discharge comprising; lowering pH of said neutral oxidant fluid in said acidification reactor for generating an acidic oxidant fluid; transferring electrons from a positive electrode of said electrolyte-electrode assembly to said aqueous multi-electron oxidant in said acidic oxidant fluid; and transferring electrons from said reducer fluid to a negative electrode of said electrolyte-electrode assembly to produce said electric power in an external electric circuit operably connected to terminals of said discharge unit and to generate an acidic discharge fluid on consumption of said acidic oxidant fluid and said reducer fluid; optionally neutralizing said acidic discharge fluid in said neutralization reactor of said discharge system to produce a neutral discharge fluid; regenerating said one or more forms of oxidant fluid comprising said aqueous multi-electron oxidant and said reducer fluid comprising said reducer in stoichiometric amounts from one or more forms of said neutral discharge fluid in a regeneration system using external power, said regeneration comprising; converting said neutral discharge fluid into an alkaline discharge fluid by using one or more of an externally supplied base and a base produced in a splitting-disproportionation reactor configured for one of an aqueous multi-electron oxidant-on-negative electrode mode of operation, a no-aqueous multi-electron oxidant-on-negative electrode mode of operation, and a combination thereof; splitting said alkaline discharge fluid into a reducer and an intermediate oxidant in said splitting-disproportionation reactor, wherein said intermediate oxidant is converted into one or more forms of said aqueous multi-electron oxidant via disproportionation of said intermediate oxidant with said base, and wherein said splitting releases a stoichiometric amount of said reducer and said base in said splitting-disproportionation reactor; and continuing said splitting and said disproportionation in said splitting-disproportionation reactor in one of a batch mode of operation, a cyclic flow mode of operation, a cascade flow mode of operation, and a combination thereof, until a desired degree of conversion of a discharge product of said aqueous multi-electron oxidant into said one or more forms of said aqueous multi-electron oxidant is achieved; and supplying said regenerated one or more forms of said oxidant fluid comprising said aqueous multi-electron oxidant and said regenerated reducer fluid comprising said reducer to said discharge system for said facilitation of said discharge of said discharge unit. - View Dependent Claims (54, 55, 56, 57, 58, 59, 60, 61, 62, 63, 64, 65, 66, 67, 68, 69, 70, 71, 72, 73, 74, 75, 76, 77, 78, 79, 80, 81, 82, 83)
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84. A method for producing electric power and regenerating hydrogen and an oxidant fluid comprising lithium bromate in an energy storage cycle, said method comprising:
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providing a discharge system comprising a discharge unit, an acidification reactor, and optionally a neutralization reactor, said discharge system comprising a neutral oxidant fluid comprising said lithium bromate, one or more forms of a buffer, and said hydrogen, wherein concentration of said lithium bromate dissolved in said neutral oxidant fluid is above one of 1M, 2M, 5M, and 10M; converting said neutral oxidant fluid into an acidic oxidant fluid in said acidification reactor, wherein concentration of acidic protons in said acidic oxidant fluid is below one of 0.1M, 0.5M, 1M, 2M, 5M, and 10M; facilitating discharge of said discharge unit for producing said electric power from said acidic oxidant fluid and from said hydrogen and generating an acidic discharge fluid on consumption of said acidic oxidant fluid and said hydrogen, wherein said discharge is facilitated via a pH-dependent solution-phase comproportionation of bromate with bromide formed via electroreduction of an intermediate bromine; optionally neutralizing said acidic discharge fluid in said neutralization reactor of said discharge system to produce one or more forms of a neutral discharge fluid; regenerating said hydrogen and one or more forms of said oxidant fluid comprising said lithium bromate in stoichiometric amounts from one or more forms of said neutral discharge fluid in a regeneration system using external power, said regeneration comprising; splitting said one or more forms of said neutral discharge fluid into stoichiometric amounts of bromine, hydrogen, and a base form of said buffer using said external power in a splitting-disproportionation reactor, and producing said lithium bromate via disproportionation of said bromine with said base form of said buffer, wherein said splitting is performed via one or more of electrolysis, photolysis, photoelectrolysis, radiolysis, and thermolysis, and wherein said disproportionation of said bromine is facilitated by a buffer capable of maintaining a solution pH between 4 and 9; and continuing said splitting and said disproportionation in said splitting-disproportionation reactor in one of a no-aqueous multi-electron oxidant-on-negative electrode mode of operation and an aqueous multi-electron oxidant-on-negative electrode mode of operation in one of a plurality of modes, until a desired degree of conversion of said bromide into said bromate is achieved; and supplying said regenerated one or more forms of said oxidant fluid comprising said bromate and said regenerated hydrogen to said discharge system for subsequent generation of electric power on demand. - View Dependent Claims (85, 86, 87, 88, 89, 90, 91, 92)
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93. A system for producing electric power and regenerating an aqueous multi-electron oxidant and a reducer in an energy storage cycle, said system comprising:
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a discharge system comprising; a neutral oxidant fluid comprising one or more forms of said aqueous multi-electron oxidant; a reducer fluid comprising one or more forms of said reducer; a discharge unit comprising an electrolytic cell stack, said electrolytic cell stack comprising a plurality of electrolytic cells, wherein each of said electrolytic cells comprises an electrolyte-electrode assembly; an acidification reactor operably connected to said discharge unit, said acidification reactor configured to lower pH of said neutral oxidant fluid for generating an acidic oxidant fluid; and said discharge unit configured to produce said electric power from said acidic oxidant fluid and from said reducer fluid by performing; transferring electrons from a positive electrode of said electrolyte-electrode assembly to said aqueous multi-electron oxidant in said acidic oxidant fluid; and transferring electrons from said reducer fluid to a negative electrode of said electrolyte-electrode assembly to produce said electric power in an external electric circuit operably connected to terminals of said discharge unit and to generate an acidic discharge fluid on consumption of said acidic oxidant fluid and said reducer fluid; and a regeneration system comprising; an splitting-disproportionation reactor configured to convert a neutral discharge fluid into an alkaline discharge fluid by using one or more of an externally supplied base and a base produced in said splitting-disproportionation reactor configured for one of an aqueous multi-electron oxidant-on-negative electrode mode of operation, a no-aqueous multi-electron oxidant-on-negative electrode mode of operation, and a combination thereof; said splitting-disproportionation reactor configured to split said alkaline discharge fluid into a reducer and an intermediate oxidant via one of electrolysis, photoelectrolysis, photolysis, thermolysis, and radiolysis, wherein said splitting also releases stoichiometric amounts of said reducer and said base in said splitting-disproportionation reactor; said splitting-disproportionation reactor configured to convert said intermediate oxidant produced in said splitting-disproportionation reactor into one or more forms of said aqueous multi-electron oxidant via disproportionation of said intermediate oxidant with said base; and said splitting-disproportionation reactor configured to continue said splitting and said disproportionation in one of a batch mode of operation, a cyclic flow mode of operation, a cascade flow mode of operation, and a combination thereof, until a desired degree of conversion of a discharge product of said aqueous multi-electron oxidant into one or more forms of said aqueous multi-electron oxidant is achieved. - View Dependent Claims (94, 95, 96, 97, 98, 99, 100, 101, 102)
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Specification