THERMOPLASTIC COMPOSITIONS, METHODS OF MANUFACTURE, AND ARTICLES THEREOF

• US 20140179855A1
• Filed: 12/20/2012
• Published: 06/26/2014
• Est. Priority Date: 12/20/2012
• Status: Abandoned Application

• Current Assignee: SABIC Global Technologies BV (Government of Saudi Arabia)
• Original Assignee: Sabic Innovative Plastics IP BV (Government of Saudi Arabia)
• Inventors: Farrell, Tony, Lohmeijer, Johannes Hubertus Gabriel Marie, van Zyl, Andries J.P.
• Application Number:
  US13/721,842
• Publication Number:
  US 20140179855A1
• Time in Patent Office: Days
• US Class Current: 524/494
• CPC Class Codes: B29C 65/1616 Near infrared radiation [NIR], e.g. by YAG lasers
• CPC Class Codes: B29C 65/1635 at least passing through one of the parts to be joined, i.e. laser transmission welding
• CPC Class Codes: B29C 65/1677 making use of an absorber or impact modifier
• CPC Class Codes: B29C 66/71 characterised by the composition of the plastics material of the parts to be joined welding bar compositions B29C65/125
• CPC Class Codes: B29C 66/73771 the to-be-joined area of at least one of the parts to be joined being amorphous
• CPC Class Codes: B29C 66/73773 the to-be-joined area of at least one of the parts to be joined being semi-crystalline
• CPC Class Codes: B29C 66/73921 characterised by the materials of both parts being thermoplastics
• CPC Class Codes: B29K 2067/00 Use of polyesters or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2067/003 PET, i.e. poylethylene terephthalate
• CPC Class Codes: B29K 2067/006 PBT, i.e. polybutylene terephthalate
• CPC Class Codes: B29K 2069/00 Use of PC, i.e. polycarbonates or derivatives thereof, as moulding material
• CPC Class Codes: C08K 7/14 Glass
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence
• CPC Class Codes: C08L 67/03 the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
• CPC Class Codes: C08L 69/00 Compositions of polycarbonates; Compositions of derivatives of polycarbonates

Abstract

A laser weldable composition made from a process of melt blending a combination of a partially crystalline thermoplastic polyester component such as poly(butylene terephthalate), an amorphous thermoplastic polycarbonate having a Fries rearrangement of greater than 150 to 10,000 ppm, and a filler such as glass fiber. The laser weldable composition has a polycarbonate aryl hydroxy end-group content of at least 300 ppm and provides improved near infrared transmission at 960 nanometers. A method welding components made from the weldable composition and welded articles made therefrom are also disclosed.

Claims

1-13. -13. (canceled)

14. A process for welding a laser-transmissive first part to a laser-absorbing second part of an article, wherein

the first part comprises a composition made by a process comprising melt blending:

(a) from 10 to 70 weight percent of a partially crystalline polyester component selected from poly(butylene terephthalate), poly(ethylene terephthalate), poly(butylene terephthalate) copolymers, poly(ethylene terephthalate) copolymers, and combinations thereof;

(b) from 10 to 60 weight percent of an amorphous polycarbonate having a Fries rearrangement of greater than 150 to 10,000 ppm;

(c) from 5 to 50 weight percent of a filler; and

(d) optionally, from 0.01 to 10 wt. % of an antioxidant, mold release agent, stabilizer, or a combination thereof;

wherein the melt blended composition has a polycarbonate aryl hydroxy end-group content of at least 300 ppm;

wherein the melt blended composition excludes colorant; and

wherein the composition, when molded into an article having a 2.0 mm thickness, provides a near infrared transmission at 960 nanometers of greater than 45%; and

the second part comprises a thermoplastic composition comprising an NIR-absorbing agent, and where at least a portion of a surface of the first part is placed in physical contact with at least a portion of a surface of the second part to form a welding join area,

the process further comprising applying NIR-laser radiation to the first part such that the radiation substantially passes through the first part and is absorbed by the second part so that sufficient heat is generated to effectively weld the first part to the second part of the article.

15. The process of claim 14, wherein the second article comprises a polymer selected from the group consisting of polycarbonate, polyester, polycarbonate copolymers, polyester copolymers, and combinations thereof.

16. The process of claim 14, wherein the second article comprises a NIR absorbing material selected from the group consisting of organic dyes, metal oxides, mixed metal oxides, complex oxides, metal-sulphides, metal-borides, metal-phosphates, metal-carbonates, metal-sulphates, metal-nitrides, lanthanum hexaboride, cesium tungsten oxide, indium tin oxide, antimony tin oxide, indium zinc oxide, and combinations thereof, wherein the NIR absorbing material is present in the thermoplastic composition of the second part in an effective amount from 0.00001 to 5 wt. %, based on total weight of the laser-weldable composition.

18. The process of claim 14 wherein the composition, when molded into an article having a 2.0 mm thickness, provides a near infrared transmission at 960 nanometers, of greater than 48%, based on an average of samples molded at 70°

C. and 90°

C.

19. The process of claim 14 wherein an article having a 2.0 mm thickness and molded from the composition has a near infrared transmission at 960 nanometers at least 5% greater than the same composition with the polycarbonate replaced by an comparable polycarbonate having a Fries rearrangement of less than 150 ppm.

20. The process of claim 14 wherein the composition has a Vicat softening temperature of 120 to 180°

C. according to ISO 306 at 120°

C./hr and 50 N load.

21. The process of claim 14 wherein the partially crystalline thermoplastic is poly(butylene terephthalate).

22. The process of claim 14 wherein the amorphous thermoplastic polymer comprises a bisphenol A polycarbonate.

23. The process of claim 14 wherein the Fries content is at least 250 ppm.

24. The process of claim 14 wherein the polycarbonate is made by a process of melt polycondensation.

25. The process of claim 14 wherein the filler is glass fiber having an average diameter of 3 to 30 micrometers and an average length of 0.1 to 15 mm before said melt blending.

26. The process of claim 14 wherein the composition comprises a product made by a process of melt blending a combination of:

(a) from more than 20 to 60 weight percent of a partially crystalline polyester component selected from crystalline poly(butylene terephthalate), poly(ethylene terephthalate), poly(butylene terephthalate) copolymers, poly(ethylene terephthalate) copolymers, and combinations thereof;

(b) from 20 to 50 weight percent of an amorphous polycarbonate having a Fries rearrangement of greater than 250 to 10,000 ppm;

(c) from 10 to 40 weight percent glass filler; and

(d) optionally from 0.1 to 5 weight percent of an antioxidant, mold release agent, stabilizer, or a combination thereof;

wherein the melt blended composition has a polycarbonate aryl hydroxy end-group content of at least 400 ppm; and

wherein an article having a 2 mm thickness and molded from the composition has a near infrared transmission at 960 nanometers, of greater than 50 percent and a Vicat softening temperature of at least 130°

C. according to ISO 306 at 120°

C./hr and 50 N load.

27. The process of claim 14 wherein an article having a 2.0 mm thickness and molded from the composition has a near infrared transmission at 960 nanometers of greater than 55 percent.

28. The process of claim 14 wherein the composition comprises a product made by a process of melt blending a combination of:

(a) from more than 20 to 60 weight percent of poly(butylene terephthalate);

(b) from 20 to 50 weight percent of an amorphous bisphenol A polycarbonate having a Fries rearrangement of greater than 300 to 10,000 ppm;

(c) from 10 to 40 weight percent glass filler; and

(d) from 0.1 to 5 weight percent of an antioxidant, mold release agent, stabilizer, or a combination thereof;

wherein the melt blended composition has a polycarbonate aryl hydroxy end-group content of at least 500 ppm; and

wherein an article having a 2 mm thickness and molded from the composition has a near infrared transmission at 960 nanometers, of greater than 55 percent and a Vicat softening temperature of 135°

C. to 190°

C. according to ISO 306 at 120°

C./hr and 50 N load.

17. A laser welded, molded article comprising a first laser-transmissive part welded to a second laser-absorbing part, wherein the first part comprises a product made by a process comprising melt blending:

(a) from 10 to 70 weight percent of a partially crystalline thermoplastic polyester component selected from poly(butylene terephthalate), poly(ethylene terephthalate), poly(butylene terephthalate) copolymers, poly(ethylene terephthalate) copolymers, and combinations thereof;

(b) from 10 to 60 weight percent of an amorphous polycarbonate having a Fries rearrangement of greater than 150 to 10,000 ppm;

(c) from 5 to 50 weight percent of a filler; and

(d) optionally, from 0.01 to 10 wt. % of an antioxidant, mold release agent, stabilizer, or a combination thereof;

wherein the product made by the process excludes colorant;

wherein the melt blended composition has a polycarbonate aryl hydroxy end-group content of at least 300 ppm; and

wherein the composition, when molded into an article having a 2.0 mm thickness, provides a near infrared transmission at 960 nanometers of greater than 45%.