Producing Nanostructure of Polymeric Core-Shell to Intelligent Control solubility of Hidrophilic Polymer during Polymer Flooding Process

• US 20140187451A1
• Filed: 12/29/2012
• Published: 07/03/2014
• Est. Priority Date: 12/29/2012
• Status: Abandoned Application

• Current Assignee: Ahmad Ramazani Saadatabadi, Yousef Tamsilian
• Original Assignee: Ahmad Ramazani Saadatabadi, Yousef Tamsilian
• Inventors: Tamsilian, Yousef, Saadatabadi, Ahmad Ramazani
• Application Number:
  US13/730,938
• Publication Number:
  US 20140187451A1
• Time in Patent Office: Days
• US Class Current: 507/213
• CPC Class Codes: C08F 2/32 Polymerisation in water-in-oil emulsions
• CPC Class Codes: C08F 212/08 Styrene
• CPC Class Codes: C08F 265/06 Polymerisation of acrylate or methacrylate esters on to polymers thereof
• CPC Class Codes: C09K 2208/10 Nanoparticle-containing well treatment fluids
• CPC Class Codes: C09K 8/588 characterised by the use of specific polymers polymeric surfactants C09K8/584

Abstract

Hydrophilic polymer particles have been obtained using polyacrylamide, xanthane, maleic anhydride polymers, allylamine, ethyleneimine, and oxazoline as core polymers. Then, hydrophobic polymers shells have been produced on the core-side using styrene, styrene copolymers, polyvinyl state, polysolfune, polymethyl methacrylate, and polycyclohxyl methacrylate by in-situ polymerization of monomer as method one and inverse emulsion process as method two. These particles can release hydrophilic polymers at oil-water interface at the reservoir temperature where the water flooding should have the maximum viscosity. So, active materials cause to decrease the mobility ratio of water to oil in the reservoirs and on the other hand, plug the swept porosities and prevent to act the water fingering process.

Claims

1. A method of producing nanostructure of polymeric core-shell to intelligent control solubility of hydrophilic polymer during polymer flooding process;

comprising nanoparticles consisting of two parts, core and shell;

wherein said core is hydrophilic polymer and said shell is a hydrophobic polymer;

wherein said nanostructure is released inside an oil reservoir;

wherein said shell is solvent in oil and said core increases water viscosity;

wherein said shell dissolves in said oil reservoir and decreases water mobility ratio than underground oil in said oil reservoir and further increases efficiency of said oil in an oil removal procedure.

2. The method of claim 1, wherein said shell is anti bacterial and prevents physical and/or thermal degradation and/or gel condensation in undesirable areas in said oil reservoir.

3. The method of claim 2, wherein said shell comprises an intelligent release of said core in depths of said oil reservoir;

wherein some particles of said shell remain in said depths of said oil reservoir.

4. The method of claim 3, wherein said core further comprises active polymers comprising mixed combination of water, monomer of said organic hydrophilic polymer, initiator, organic solvent and surfactant.

5. The method of claim 4, wherein said initiator comprises redox (potassium persulfate-Iron (II) and sulphate-7H₂O) and/or potassium persulphate and/or benzoyl peroxide;

and wherein said organic solvent comprises hexane and wherein said surfactant comprises span and/or sodium dodecyl sulfate (SDS).

6. The method of claim 5, further comprising a polymerization process comprising step of mixing said solvent and said surfactant in a reactor;

and wherein said water and said monomer are dispersed in said reactor controlling a size of said core;

wherein said method is inverse emulsion and said polymerization process is performed in water phase;

wherein said core particles comprise smaller particles.

7. The method of claim 6, wherein said initiator and said monomer of organic hydrophilic polymer are injected inside said reactor simultaneously.

8. The method of claim 7, wherein said core comprises high molecular weight and wherein said shell comprises organic polymer monolayer with low molecular weight;

wherein size of said core is less than 90 nm and wherein size of said shell is less than 25 nm.

9. The method of claim 8, wherein said nanostructure of polymeric core-shell comprises a release time of more than 21 days and a recovery factor of more than 50%.

10. The method of claim 9, wherein said core comprises of Polyacrylamide, Poly(2-acrylamido-2-methyl-1-propanesulfonic acid-co-acrylonitrile) acrylonitrile, Poly(N-isopropylacrylamide), Poly(N-isopropylacrylamide), carboxylic acid terminated, Poly(N-isopropylacrylamide), maleimide terminated and Poly(N-isopropylacrylamide-co-methacrylic acid) 10 mol % in methacrylic acid;

and wherein said shell comprises Poly(butyl acrylate) solution in toluene, Poly(ethyl acrylate) solution in toluene, Poly(2-ethylhexyl acrylate) solution in toluene, Poly(methyl acrylate) solution, Poly(methyl acrylate), azide terminated and Polyacrylonitrile.

11. The method of claim 3, wherein said core comprises natural polymer nanoparticles comprising xanthane and/or prepared gels;

wherein said core is produced with a spray drying technique and wherein said hydrophobic monomers, powder of nanosized particles of said hydrophilic polymer nanoparticles and a suitable surfactant are placed inside a reactor under stirring for 1 hr under nitrogen atmosphere; and

wherein an appropriate initiator and deionized water are added for beginning of a polymerization reaction.

12. The method of claim 10;

wherein molecular weight of said shell is lower than 60000 Dolton.

13. Method of claim 12, wherein said nanostructure of polymeric core-shell slowly release in said reservoir and wherein said release enables said shell to reach deeper areas of said reservoir and wherein said shell protects said core from physical and mechanical damages.

14. The method of claim 13, wherein said release is 6 days for pure polycrylamide and 21 days for coated polyacrylamide polymer.

15. The method of claim 14, wherein said nanostructure of polymeric core-shell is polyacrylamide-polystyrene and wherein said polyacrylamide-polystyrene increases oil recovery up to 17% more than water flooding and comprises same recovery percentage of oil as flooding of said pure polyacrylamide.

16. The method of claim 15, wherein said initiator comprises redox, potassium persolphate, sodium didyl solphate, banzoeil perozid and kiomil peroxide.