Structuring Agents and Emulsifiers for Agricultural Oil-Based Formulations

• US 20140206542A1
• Filed: 06/08/2012
• Published: 07/24/2014
• Est. Priority Date: 06/10/2011
• Status: Active Application

• Current Assignee: Indorama Ventures Oxides Australia Pty Limited
• Original Assignee: Huntsman Corporation Australia Pty. Ltd. (Huntsman Corporation)
• Inventors: Saylik, Dilek, Moody, Keith, Brown, Rowan
• Application Number:
  US14/115,362
• Publication Number:
  US 20140206542A1
• Time in Patent Office: Days
• US Class Current: 504/234
• CPC Class Codes: A01N 25/04 Dispersions, emulsions, suspoemulsions, suspension concentrates or gels foams A01N25/16
• CPC Class Codes: A01N 25/30 characterised by the surfactants
• CPC Class Codes: A01N 43/70 Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
• CPC Class Codes: A01N 47/14 Di-thio analogues thereof
• CPC Class Codes: A01N 47/30 Derivatives containing the group >N—CO—N aryl or >N—CS—N—aryl
• CPC Class Codes: A01N 47/32 containing >N—CO—N< or >N—CS—N< groups directly attached to a cycloaliphatic ring
• CPC Class Codes: A01N 55/02 containing metal atoms
• CPC Class Codes: C08G 63/664 derived from hydroxy carboxylic acids

Abstract

An agricultural oil-based suspension formulation comprising an active ingredient suspended in finely divided form in an oil; and at least one surfactant selected from a polyalkylene glycol-fatty acid condensate or a polyalkylene glycolether fatty acid condensate formed from a reaction between a compound having Structure (1) and a compound having Structure (2):

• • wherein
    • R₁=H or a C₁-C₃₀ alkyl radical;
    • A and B are ethylene or propylene groups in succession or random;
    • n=0 or >1; and
    • m=0 or >1,
  • and wherein
    • n+m>34;
    • R₂=C₈-C₃₀ alkyl or alkylene radical (branched or linear); and
    • x=>1.

Claims

1. An agricultural oil-based suspension formulation comprising an active ingredient suspended in finely divided form in an oil;

and at least one surfactant selected from a polyalkylene glycol-fatty acid condensate or a polyalkylene glycolether fatty acid condensate formed from a reaction between a compound having Structure (1) and a compound having Structure (2);

2. An agricultural oil-based suspension formulation according to claim 1, wherein the surfactant comprises a diblock condensate of polyethylene glycol having a molecular weight greater than 1500 amu and a polyhydroxystearic acid copolymer of condensation range greater than 2 units.

3. An agricultural oil-based suspension formulation according to claim 1, wherein the surfactant comprises at least one monoblock condensate of a polyalkylene glycol ether-fatty acid condensate, wherein the polyalkylene glycol ether is an ethylene oxide-propylene oxide copolymer butyl ether having a molecular weight of greater than 1800 amu and the fatty acid condensate is a polyhydroxystearic acid copolymer of condensation range greater than 2 units.

4. An agricultural oil-based suspension formulation according to claim 1, wherein the formulation is selected from an Oil Dispersion (“

OD”

) or an Oil-miscible Flowable (“

OF”

) formulation.

5. An agricultural oil-based suspension formulation according to claim 4, wherein the OD formulation further comprises an emulsifying agent and/or a rubber-type copolymer as an additional anti-settling agent.

6. An agricultural oil-based suspension formulation according to claim 1, wherein the active ingredient is selected from Mancozeb, Diuron, Atrazine and Captan, or mixtures thereof.

7. An agricultural oil-based suspension formulation according to claim 6, wherein the active ingredient is Mancozeb.

8. An agricultural oil-based suspension according to claim 7, wherein the Mancozeb is present in a concentration greater than 400 g/L.

9. An agricultural oil-based suspension formulation according to claim 8, wherein the Mancozeb is present in a concentration greater than 580 g/L.

10. A method of application of the agricultural oil-based suspension formulation according to claim 1, having a rate of use of polyalkylene glycol-fatty acid condensate or polyalkylene glycolether fatty acid condensate in a range of from 2-10% w/v in the formulation.

11. A method of application according to claim 10, wherein the rate of use is in the range of 3-8% w/v in the formulation.

12. The method according to claim 10, wherein the active ingredient is selected from Mancozeb, Diuron, Atrazine and Captan, or mixtures thereof.

13. The method according to claim 12, wherein the active ingredient is Mancozeb.

14. The method according to claim 13, wherein the Mancozeb is present in a concentration greater than 400 g/L.

15. The method according to claim 14, wherein Mancozeb is present in a concentration greater than 580 g/L.

16. A method of preparing an OD formulation comprising an active ingredient comprising the steps of:

a) preparing a surfactant solution premix by combining at least one surfactant selected from a polyalkylene glycol-fatty acid condensate or a polyalkylene glycolether fatty acid condensate of the present invention with a surfactant and an oil to give a liquid;

b) dispersing the active ingredient in the surfactant solution by either stirring or high shear mixing;

c) milling the active ingredient dispersion to achieve a particle size average in the range 1-12 microns;

d) adding surfactant emulsifying agents; and

e) optionally adjusting the final concentration of active ingredient content by adding additional oil and other required ingredients,

wherein steps a) to d) are carried out in any order.

17. The method according to claim 16, wherein step (e) includes adding a rubber-type copolymer as an additional anti-settling agent.

18. The method according to claim 17, wherein the active ingredient is selected from Mancozeb, Diuron, Atrazine or Captan, or mixtures thereof.

19. The method according to claim 18, wherein the active ingredient is Mancozeb.

20. The method according to claim 19, wherein the Mancozeb is present in a concentration greater than 400 g/L.