Cu-Mg-P-BASED COPPER ALLOY SHEET HAVING EXCELLENT FATIGUE RESISTANCE CHARACTERISTIC AND METHOD OF PRODUCING THE SAME

• US 20140209221A1
• Filed: 04/04/2012
• Published: 07/31/2014
• Est. Priority Date: 04/04/2012
• Status: Active Grant

• Current Assignee: Mitsubishi Shindoh Company Limited (Mitsubishi Materials Corporation)
• Original Assignee: Mitsubishi Shindoh Company Limited (Mitsubishi Materials Corporation)
• Inventors: Abe, Yoshio, Sukumoda, Shunroku, Kumagai, Jun-Ichi
• Granted Patent: US 9,169,539 B2
• Time in Patent Office: Days
• US Class Current: 148/681
• CPC Class Codes: C22C 1/10 Alloys containing non-metals C22C1/05, C22C1/08 take precedence
• CPC Class Codes: C22C 9/00 Alloys based on copper
• CPC Class Codes: C22C 9/05 with manganese as the next major constituent
• CPC Class Codes: C22F 1/08 of copper or alloys based thereon
• CPC Class Codes: H01B 1/026 Alloys based on copper

Abstract

The fatigue resistance characteristics, particularly, fatigue resistance characteristics after retention at 150° C. for 1000 hours are improved while maintaining the characteristics in the related art. Provided is a copper alloy sheet having a composition containing 0.2% by mass to 1.2% by mass of Mg, and 0.001% by mass to 0.2% by mass of P, the balance being Cu and unavoidable impurities. When X-ray diffraction intensity of a {110} crystal plane is set as I{110}, and X-ray diffraction intensity of {110} crystal plane of a pure copper standard powder is set as I₀{110}, a surface crystal orientation of the copper alloy sheet satisfies a relation of 4.0≦I{110}/I₀{110}≦6.0.

Claims

1. A Cu—

Mg—

P-based copper alloy sheet having excellent fatigue resistance characteristics which has a composition containing;

0.2% by mass to 1.2% by mass of Mg; and

0.001% by mass to 0.2% by mass of P, the balance being Cu and unavoidable impurities,

wherein when X-ray diffraction intensity of a {110} crystal plane is set as I{110}, and X-ray diffraction intensity of a {110} crystal plane of a pure copper standard powder is set as I₀{110}, a surface crystal orientation of the copper alloy sheet satisfies a relation of 4.0≦

I{110}/I₀{110}≦

6.0,

when X-ray diffraction intensity of a {100} crystal plane is set as I{100}, and X-ray diffraction intensity of a {100} crystal plane of the pure copper standard powder is set as I₀{100}, the surface crystal orientation of the copper alloy sheet satisfies a relation of I{100}/I₀{100}≦

0.8,

when X-ray diffraction intensity of a {111} crystal plane is set as I{111}, and X-ray diffraction intensity of a {111} crystal plane of the pure copper standard powder is set as I₀{111}, the surface crystal orientation of the copper alloy sheet satisfies a relation of I{111}/I₀{111}≦

0.8, and

an average grain size of the copper alloy sheet is 1.0 μ

m to 10.0 μ

m.

2. The Cu—

Mg—

P-based copper alloy sheet having excellent fatigue resistance characteristics according to claim 1, further containing;

0.0002% by mass to 0.0013% by mass of C, and 0.0002% by mass to 0.001% by mass of oxygen.

3. The Cu—

Mg—

P-based copper alloy sheet having excellent fatigue resistance characteristics according to claim 1, further containing;

0.001% by mass to 0.03% by mass of Zr.

4. The Cu—

Mg—

P-based copper alloy sheet having excellent fatigue resistance characteristics according to claim 2, further containing;

0.001% by mass to 0.03% by mass of Zr.

5. A method of producing the Cu—

Mg—

P-based copper alloy sheet having excellent fatigue resistance characteristics according to claim 1, the method comprising;

a process of carrying out hot rolling, cold rolling, continuous annealing, finish cold rolling, and tension leveling in this order to produce the copper alloy sheet,

wherein the hot rolling is carried out under conditions in which a hot rolling initiation temperature is 700°

C. to 800°

C., a total hot-rolling rate is 80% or more, and an average hot rolling rate for one pass is 15% to 30%,

the cold rolling is carried out at a cold rolling rate of 50% or more,

the continuous annealing is carried out at a temperature of 300°

C. to 550°

C. for 0.1 minutes to 10 minutes, and

the tension leveling is carried out at a line tension of 10 N/mm² to 140 N/mm².

6. A method of producing the Cu—

Mg—

P-based copper alloy sheet having excellent fatigue resistance characteristics according to claim 2, the method comprising;

a process of carrying out hot rolling, cold rolling, continuous annealing, finish cold rolling, and tension leveling in this order to produce the copper alloy sheet,

wherein the hot rolling is carried out under conditions in which a hot rolling initiation temperature is 700°

C. to 800°

C., a total hot-rolling rate is 80% or more, and an average hot rolling rate for one pass is 15% to 30%,

the cold rolling is carried out at a cold rolling rate of 50% or more,

the continuous annealing is carried out at a temperature of 300°

C. to 550°

C. for 0.1 minutes to 10 minutes, and

the tension leveling is carried out at a line tension of 10 N/mm² to 140 N/mm².

7. A method of producing the Cu—

Mg—

P-based copper alloy sheet having excellent fatigue resistance characteristics according to claim 3, the method comprising;

a process of carrying out hot rolling, cold rolling, continuous annealing, finish cold rolling, and tension leveling in this order to produce the copper alloy sheet,

wherein the hot rolling is carried out under conditions in which a hot rolling initiation temperature is 700°

C. to 800°

C., a total hot-rolling rate is 80% or more, and an average hot rolling rate for one pass is 15% to 30%,

the cold rolling is carried out at a cold rolling rate of 50% or more,

the continuous annealing is carried out at a temperature of 300°

C. to 550°

C. for 0.1 minutes to 10 minutes, and

the tension leveling is carried out at a line tension of 10 N/mm² to 140 N/mm².

8. A method of producing the Cu—

Mg—

P-based copper alloy sheet having excellent fatigue resistance characteristics according to claim 4, the method comprising;

a process of carrying out hot rolling, cold rolling, continuous annealing, finish cold rolling, and tension leveling in this order to produce the copper alloy sheet,

wherein the hot rolling is carried out under conditions in which a hot rolling initiation temperature is 700°

C. to 800°

C., a total hot-rolling rate is 80% or more, and an average hot rolling rate for one pass is 15% to 30%,

the cold rolling is carried out at a cold rolling rate of 50% or more,

the continuous annealing is carried out at a temperature of 300°

C. to 550°

C. for 0.1 minutes to 10 minutes, and

the tension leveling is carried out at a line tension of 10 N/mm² to 140 N/mm².