REDOX-ACTIVE LIGAND-BASED TRANSITION METAL COMPLEX FLOW BATTERIES

• US 20140239906A1
• Filed: 02/25/2014
• Published: 08/28/2014
• Est. Priority Date: 02/28/2013
• Status: Abandoned Application

• Current Assignee: Sandia Corporation (Martin Marietta Corporation)
• Original Assignee: Sandia Corporation (Martin Marietta Corporation)
• Inventors: Anderson, Travis Mark, Anstey, Mitchell, Tomson, Neil C.
• Application Number:
  US14/189,830
• Publication Number:
  US 20140239906A1
• Time in Patent Office: Days
• US Class Current: 320/128
• CPC Class Codes: H01M 8/188 by recharging of redox couples containing fluids; Redox flow type batteries
• CPC Class Codes: H01M 8/20 Indirect fuel cells, e.g. fuel cells with redox couple being irreversible H01M8/18 takes precedence
• CPC Class Codes: H02J 7/0068 Battery or charger load switching, e.g. concurrent charging and load supply H02J7/0013 takes precedence
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

Flow batteries including one or more metals complexed by one or more redox-active ligands are disclosed herein. In a general embodiment, the flow battery includes an electrochemical cell having an anode portion, a cathode portion and a separator disposed between the anode portion and the cathode portion. Each of the anode portion and the cathode portion includes one or more metals complexed by one or more redox-active ligands. The flow battery further includes an anode electrode disposed in the anode portion and a cathode electrode disposed in the cathode portion.

Claims

1. A flow battery comprising one or more metals complexed by one or more redox-active ligands.

2. The flow battery of claim 1, wherein the metal is a type selected from the group consisting of alkali series, alkaline earth series transition series, main group series, lanthanide series, the actinide series, and combinations thereof.

3. The flow battery of claim 1, wherein the metal is complexed by a combination of non-redox-active ligands and redox-active ligands.

4. The flow battery of claim 1, wherein the flow battery comprises an anode portion and a cathode portion each including the metal complexed by one or more redox-active ligands.

5. The flow battery of claim 1, wherein the redox-active ligands are selected from the group consisting of nitrosyl, α

-diimines, α

-diketones, α

-dithiolenes, bipyridines, terpyridines, catechols, phenolates, tetrapyrrole macrocycles and combinations thereof.

6. A flow battery comprising:

an electrochemical cell comprising an anode portion, a cathode portion and a separator disposed between the anode portion and the cathode portion, wherein each of the anode portion and the cathode portion comprises one or more metals complexed by one or more redox-active ligands;

an anode electrode disposed in the anode portion; and

a cathode electrode disposed in the cathode portion.

7. The flow battery of claim 6, wherein the metal is a type selected from the group consisting of alkali series, alkaline earth series transition series, main group series, lanthanide series, the actinide series, and combinations thereof.

8. The flow battery of claim 6, wherein the metal complexed by one or more redox-active ligands of each of the anode portion and the cathode portion are a similar material.

9. The flow battery of claim 6, wherein the anode electrode and the cathode electrode are each connected to a load.

10. The flow battery of claim 6, further comprising an anode reservoir coupled to the anode portion of the cell and a cathode reservoir coupled to the cathode portion.

11. The flow battery of claim 6, wherein the redox-active ligands are selected from the group consisting of nitrosyl, α

-diimines, α

-diketones, α

-dithiolenes, bipyridines, terpyridines, catechols, phenolates, tetrapyrrole macrocycles and combinations thereof.

12. A method comprising:

introducing one or more metals complexed by one or more redox-active ligands into at least one of an anode portion and a cathode portion of an electrochemical cell; and

charging or discharging the cell.

13. The method of claim 12, wherein introducing comprises bringing the metal complexed by one or more redox-active ligands into each of the anode portion and the cathode portion of the electrochemical cell.

14. The method of claim 12, wherein the metal complexed by one or more redox-active ligands introduced into the anode portion is similar to the metal complexed by one or more redox-active ligands introduced into the cathode portion.

15. The method of claim 12, wherein the redox-active ligands are selected from the group consisting of nitrosyl, α

-diimines, α

-diketones, α

-dithiolenes, bipyridines, terpyridines, catechols, phenolates, tetrapyrrole macrocycles and combinations thereof.

16. The method of claim 12, wherein the metal is a type selected from the group consisting of alkali series, alkaline earth series transition series, main group series, lanthanide series, the actinide series, and combinations thereof.

17. A flow battery comprising an electrolyte of an aqueous or non-aqueous solution including one or more metals complexed by one or more redox-active ligands.

18. The flow battery of claim 17, wherein the flow battery comprises an anode portion and a cathode portion each including a portion of the electrolyte.

19. The flow battery of claim 17, wherein the redox-active ligands are selected from the group consisting of nitrosyl, α

-diimines, α

-diketones, α

-dithiolenes, bipyridines, terpyridines, catechols, phenolates, tetrapyrrole macrocycles and combinations thereof.