USE OF DETECTION TECHNIQUES FOR CONTAMINANT AND CORROSION CONTROL IN INDUSTRIAL PROCESSES

• US 20140260708A1
• Filed: 03/11/2014
• Published: 09/18/2014
• Est. Priority Date: 03/13/2013
• Status: Active Grant

• Current Assignee: Baker Hughes Holdings LLC (Baker Hughes Company)
• Original Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Inventors: Harrell, Bradley G., Pinappu, Sai Reddy, Duggan, George G.
• Granted Patent: US 9,804,076 B2
• Time in Patent Office: Days
• US Class Current: 73/866
• CPC Class Codes: G01N 17/00 Investigating resistance of materials to the weather, to corrosion, or to light
• CPC Class Codes: G01N 33/2823 raw oil, drilling fluid or polyphasic mixtures hydrocarbon content of earth materials G01N33/241; prospecting G01V; drilling per se E21B

Abstract

Industrial fluids may be monitored at the site of each industrial fluid by introducing a sample of the industrial fluid into a device employing a detection technique for detecting at least one composition within the sample. The detection technique may be or include surface enhanced Raman scattering (SERS), mass spectrometry (MS), nuclear magnetic resonance (NMR), ultraviolet light (UV) spectroscopy, UV spectrophotometry, indirect UV spectroscopy, contactless conductivity, laser induced fluorescence, and combinations thereof. In one non-limiting embodiment, a separation technique may be applied to the sample prior to the introduction of the sample into the device for detecting the composition.

Claims

1. A method for monitoring at least one industrial fluid comprising:

a. introducing a sample of the at least one industrial fluid into a device employing a detection technique selected from the group consisting of surface enhanced Raman scattering (SERS), mass spectrometry (MS), nuclear magnetic resonance (NMR), ultraviolet light (UV) spectroscopy, UV spectrophotometry, indirect UV spectroscopy, contactless conductivity, laser induced fluorescence, and combinations thereof;

wherein the industrial fluid is selected from the group consisting of a refinery fluid, a production fluid, cooling water, process water, drilling fluids, completion fluids, production fluids, crude oil, feed streams to desalting units, outflow from desalting units, refinery heat transfer fluids, gas scrubber fluids, refinery unit feed streams, refinery intermediate streams, finished product streams, and combinations thereof; and

b. detecting at least one composition within the sample of the at least one industrial fluid; and

wherein the method occurs in an amount of time less than about 24 hours.

2. The method of claim 1, further comprising conditioning the sample prior to introducing the sample of the at least one industrial fluid into the device, wherein the conditioning is a method selected from the group consisting of filtration, pH adjustment, chemical labeling, a separation technique, solid-phase extraction, adding a background electrolyte (BGE) to the sample, adding a complexing agent to the sample, adding peroxide to the sample, adding a chelant to the sample, applying chelating resins to the sample, and combinations thereof.

3. The method of claim 2, wherein the separation technique is selected from the group consisting of gas chromatography (GC), ion chromatography (IC), high performance liquid chromatography (HPLC), capillary electrochromatography (GEC);

electrokinetic chromatography (EKC), affinity capillary electrophoresis (ACE), non-aqueous capillary electrophoresis (NACE), capillary electrophoresis (CE), capillary zone electrophoresis (CZE), gradient elution moving boundary electrophoresis (GEMBE), capillary isotachophoresis (CITP), capillary isoelectric focusing (CIEF), and combinations thereof.

4. The method of claim 1, wherein the at least one composition within the at least one industrial fluid is quantified in an amount greater than about 10 ppb.

5. The method of claim 1 further comprising altering at least one parameter of the industrial fluid after detecting the at least one composition;

wherein the at least one parameter is selected from the group consisting of temperature, amount of the at least one composition therein, pressure, and combinations thereof.

6. The method of claim 1, wherein the amount of the sample introduced into the device ranges from about 1 μ

L to about 250 μ

L.

7. The method of claim 1, wherein the at least one composition is selected from the group consisting of amines, sulfides, chlorides, bromides, organic acids, perchlorates, selenates, phosphates, polyphosphates, cyanide, selenium, borate, sulfides, mercaptans, primary amines, secondary amines, and tertiary amines, mercaptoethanol, thioglycolic acid, glycols, polyols, polydimethylsiloxanes, organic halides, C₁-C₂₂ organic acids, hydroxyacids, imidazoline, alkyl pyridine quaternary compounds, imides, amides, thiophosphate esters, phosphate esters, polyamines, dimethyl fatty amines, quaternized dimethyl fatty amines, ethylene vinylacetate, phenylenediamine (PDA), hindered phenols, nitrites, sulfites, N,N′

-diethyl hydroxylamine, hydrazine, ascorbic acid, organic nitroxides, triazoles and polytriazoles, hydroxylamines, acrylic acids and sulfonic acids, fatty acid methyl ester (FAME), propargyl alcohols, acetylenic alcohols, pyroles, indoles, indenes, thiophenols, dyes, H₂S, MEA triazine, MEA thiadiazine, MEA dithiazine, MA triazine, MA thiadiazine, MA dithiazine, metal ions, polynuclear aromatic hydrocarbons, benzene, toluene, xylene, ethylbenzene, and combinations thereof.

8. The method of claim 1, wherein the at least one composition is selected from the group consisting of scale inhibitors, sulfide inhibitors, corrosion inhibitors, antifoam additives, antifoulant additives, paraffin control additives, cleaners/degreasers, lubricity additives, cold flow additives, oxygen scavengers, hydrogen sulfide scavengers, mercaptan scavengers, corrosion inhibitor, detergents, demulsifiers, derivatives thereof, degradation products thereof, and combinations thereof.

9. The method of claim 1, wherein the detecting the at least one composition occurs in an amount of time ranging from about 30 seconds to about 5 hours.

10. A method for monitoring at least one industrial fluid comprising:

a. performing a separation technique on a sample of the at least one industrial fluid to form a separated sample;

wherein the separation technique is selected from the group consisting of gas chromatography (GC), ion chromatography (IC), high performance liquid chromatography (HPLC), capillary electrochromatography (CEC), electrokinetic chromatography (EKC), affinity capillary electrophoresis (ACE), non-aqueous capillary electrophoresis (NACE), capillary electrophoresis (CE), capillary zone electrophoresis (CZE), gradient elution moving boundary electrophoresis (GEMBE), capillary isotachophoresis (CITP), capillary isoelectric focusing (CIEF), and combinations thereof;

b. introducing the separated sample into a device employing a detection technique selected from the group consisting of surface enhanced Raman scattering (SERS), mass spectrometry (MS), nuclear magnetic resonance (NMR), ultraviolet light (UV) spectroscopy, UV spectrophotometry, indirect UV spectroscopy, contactless conductivity, laser induced fluorescence, and combinations thereof; and

wherein the industrial fluid is selected from the group consisting of a refinery fluid, a production fluid, cooling water, process water, drilling fluids, completion fluids, production fluids, crude oil, feed streams to desalting units, outflow from desalting units, refinery heat transfer fluids, gas scrubber fluids, refinery unit feed streams, refinery intermediate streams, finished product streams, and combinations thereof;

c. detecting at least one composition within the sample, wherein the at least one composition is selected from the group consisting of amines, sulfides, chlorides, bromides, organic acids, perchlorates, selenates, phosphates, polyphosphates, cyanide, selenium, borate, sulfides, mercaptans, primary amines, secondary amines, and tertiary amines, mercaptoethanol, thioglycolic acid, glycols, polyols, polydimethylsiloxanes, organic halides, C₁-C₂₂ organic acids, hydroxyacids, imidazoline, alkyl pyridine quaternary compounds, imides, amides, thiophosphate esters, phosphate esters, polyamines, dimethyl fatty amines, quaternized dimethyl fatty amines, ethylene vinylacetate, phenylenediamine (PDA), hindered phenols, nitrites, sulfites, N,N′

-diethyl hydroxylamine, hydrazine, ascorbic acid, organic nitroxides, triazoles and polytriazoles, hydroxylamines, acrylic acids and sulfonic acids, fatty acid methyl ester (FAME), propargyl alcohols, acetylenic alcohols, pyroles, indoles, indenes, thiophenols, H₂S, MEA triazine, MEA thiadiazine, MEA dithiazine, MA triazine, MA thiadiazine, MA dithiazine, metal ions, polynuclear aromatic hydrocarbons, benzene, toluene, xylene, ethylbenzene, and combinations thereof at the site of at least one industrial fluid; and

wherein the method occurs in an amount of time less than about 24 hours.

11. The method of claim 10, wherein the sample is conditioned prior to performing the separation technique, introducing the sample into the device, and combinations thereof.

12. The method of claim 11, wherein the sample is conditioned by a method selected from the group consisting of filtration, pH adjustment, chemical labeling, solid-phase extraction, adding background electrolyte (BGE) to the sample, adding a complexing agent to the sample, adding peroxide to the sample, adding a chelant to the sample, applying chelating resins to the sample, and combinations thereof.

13. The method of claim 10, wherein the at least one composition within the at least one industrial fluid is quantified in an amount greater than about 10 ppb.

14. The method of claim 10, wherein the amount of the sample introduced into the device ranges from about 1 μ

L to about 250 μ

L.

15. The method of claim 10 further comprising altering at least one parameter of the industrial fluid after detecting the at least one composition;

wherein the at least one parameter is selected from the group consisting of temperature, amount of the at least one composition therein, pressure, and combinations thereof.

16. The method of claim 10, wherein the industrial fluid is selected from the group consisting of an aqueous fluid, a non-aqueous fluid, and combinations thereof.

17. The method of claim 10, wherein the at least one composition is selected from the group consisting of scale inhibitors, sulfide inhibitors, corrosion inhibitor, antifoam additives, antifoulant additives, paraffin control additives, cleaners/degreasers, lubricity additives, cold flow additives, oxygen scavengers, hydrogen sulfide scavengers, mercaptan scavengers, corrosion inhibitor, neutralizers, detergents, demulsifiers;

degradation products thereof, derivatives thereof; and

combinations thereof.

18. The method of claim 10, wherein the detecting the at least one composition occurs in an amount of time ranging from about 30 seconds to about 5 hours.

19. A fluid composition comprising a conditioned sample of an industrial fluid prepared for analysis by a device employing a detection technique selected from the group consisting of surface enhanced Raman scattering (SERS), mass spectrometry (MS), nuclear magnetic resonance (NMR), ultraviolet light (UV) spectroscopy, UV spectrophotometry, indirect UV spectroscopy, contactless conductivity, laser induced fluorescence, and combinations thereof;

wherein the industrial fluid is selected from the group consisting of a refinery fluid, a production fluid, cooling water, process water, drilling fluids, completion fluids, production fluids, crude oil, feed streams to desalting units, outflow from desalting units, refinery heat transfer fluids, gas scrubber fluids, refinery unit feed streams, refinery intermediate streams, finished product streams, and combinations thereof; and

wherein the conditioned sample is compositionally distinct as compared to a non-conditioned sample of the industrial fluid.

20. The fluid composition of claim 19, wherein the amount of the conditioned sample ranges from about 100 μ

L to about 250 μ

L.