TUNING THE ANTI-REFLECTIVE, ABRASION RESISTANCE, ANTI-SOILING AND SELF-CLEANING PROPERTIES OF TRANSPARENT COATINGS FOR DIFFERENT GLASS SUBSTRATES AND SOLAR CELLS

• US 20140261615A1
• Filed: 03/10/2014
• Published: 09/18/2014
• Est. Priority Date: 03/15/2013
• Status: Abandoned Application

• Current Assignee: Enki Technology, Inc. (First Solar Incorporated)
• Original Assignee: Enki Technology, Inc. (First Solar Incorporated)
• Inventors: Nair, Vinod, Brophy, Brenor L.
• Application Number:
  US14/203,368
• Publication Number:
  US 20140261615A1
• Time in Patent Office: Days
• US Class Current: 136/244
• CPC Class Codes: C03C 17/002 for flat glass, e.g. float glass
• CPC Class Codes: C03C 17/30 with silicon-containing compounds
• CPC Class Codes: C03C 2217/732 made of a single layer
• CPC Class Codes: C03C 2217/76 Hydrophobic and oleophobic coatings
• CPC Class Codes: C03C 2218/36 Underside coating of a glass sheet
• CPC Class Codes: G02B 1/11 Anti-reflection coatings
• CPC Class Codes: H01L 31/048 Encapsulation of modules
• CPC Class Codes: Y02E 10/50 Photovoltaic [PV] energy
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/315 Surface modified glass [e.g., tempered, strengthened, etc.]
• CPC Class Codes: Y10T 428/31612 As silicone, silane or siloxane

Abstract

Functionalized coatings preferentially coated on the tin-side of float glass used in solar and other applications are disclosed. Coating compositions include silane-based precursors that are used to form coatings through a sol-gel process including hydrolyzed alkoxysilane-based sols. The coatings are characterized by anti-reflective, abrasion resistant, and anti-soiling properties and the tunability of those properties with respect to different applications. The coatings formed from the compositions described herein have wide application, including, for example, use as abrasion resistant coatings on the outer glass of solar modules, wherein the coating adheres through siloxane linkages. In some embodiments, when applied to glass and cured at a temperature of less than 300° C., the dried sol gel has abrasion resistance sufficient to pass standard EN-1096-2 with a loss of transmission of no more than 0.5% and enables a post-test light transmission gain of greater than 1% as compared to uncoated glass.

Claims

1. A coated glass element, comprising:

a float glass component; and

a coating adhered to the tin-side of the float glass component through siloxane linkages, the coating having at least one of an anti-reflective property, a high abrasion resistance property, a hydrophobic property and an oleophobic property;

wherein the coating comprises a dried gel formed from at least one hydrolyzed alkoxysilane based sol; and

wherein the coated glass element has greater light transmission than a coated glass element wherein the coating is adhered to the air-side of the float glass component.

2. The element of claim 1, wherein the float glass component is a component of a solar module.

3. The element of claim 1, wherein the float glass component is a component of a window.

4. The element of claim 1, wherein the float glass component is a component of a mirror.

5. The element of claim 1, wherein the float glass component has a low iron content when compared to the iron content of standard architectural window glass.

6. The element of claim 1, wherein the float glass component is tempered.

7. The element of claim 1, wherein the float glass component is untempered.

8. The element of claim 1, wherein the air-side of the float glass component is coated with a transparent conductive oxide.

9. The element of claim 8, wherein the transparent conductive oxide is the front electrode of a thin film solar panel.

10. The element of claim 1, wherein the coated glass element has an increased optical transmission of about 1% to about 3% on an absolute basis compared to an uncoated glass element.

11. The element of claim 1, wherein the float glass component is a component of a solar module and the coating increases the peak power output of the solar module by about 1.0% to about 3.5% compared to a module with an uncoated float glass component.

12. The element of claim 1, wherein the coating has abrasion resistance sufficient to pass standard EN1096-2 with an absolute loss of transmission of no more than 0.5% and enables a post-test light transmission gain of greater than 1% on an absolute basis as compared to uncoated glass.

13. The element of claim 1, wherein the coating has an anti-reflective property and a thickness of about 60 nm to about 150 nm.

14. The element of claim 1, wherein the coating has an anti-reflective property and a thickness of the coating is adapted to enhance solar transmission between 400 nanometers and 1150 nanometers.

15. The element of claim 1, wherein the coating has a water contact angle of about 70 degrees to about 178 degrees.

16. The element of claim 1, wherein the coating has an abrasion resistance property that is tuned by means of changing the curing temperature from about 120°

C. to about 300°

C.

17. A method of making a coated glass element, by:

a) identifying the tin-side of a float glass substrate; and

b) pre-treating the identified side; and

c) applying a coating to the identified side,

wherein the coating comprises a dried gel formed from at least one hydrolyzed alkoxysilane based sol; and

d) curing the coating using heat,

wherein the coating increases the transmission of the glass element by a greater amount compared to performing the method on the air-side of the float glass substrate; and

the coating has at least one of an anti-reflective property, a high abrasion resistance property, a hydrophobic property and an oleophobic property.

18. The method of claim 17, wherein the identified side is pre-treated by washing with water and drying.

19. The method of claim 18, wherein the washing is by the mechanical action of a cleaning brush.

20. The method of claim 17, wherein the identified side is pre-treated by polishing with abrasive material, rinsing and drying.

21. The method of claim 20, wherein the pre-treatment further comprises pre-cleaning with an organic solvent.

22. The method of claim 20, wherein the abrasive is selected from a group consisting of ceria, titania, zirconia, alumina, aluminum silicate, silica, magnesium hydroxide and aluminum hydroxide.

23. The method of claim 17, wherein the coating is applied by means of flow-coating.

24. The method of claim 17, wherein the coating is applied by means of depositing the liquid sol onto a substrate followed by use of a mechanical dispersant to spread the liquid evenly onto the substrate.

25. The method of claim 17, wherein the coating is dried prior to curing.

26. The method of claim 17, wherein the coating is cured by means of heating in a convection oven.

27. The method of claim 17, wherein the coating is cured by means of heating by impinging hot air on the coated surface.

28. The method of claim 17, wherein the coating is cured by means of heating by a light source.

29. The method of claim 17, wherein the coating has an anti-reflective property that is optimized depending on the spectral response of a particular solar cell type by means of tuning its thickness.

30. The method of claim 17, wherein the coating has an abrasion resistance property that is tuned by means of changing the curing temperature from about 120°

C. to about 300°

C.