LIQUID LAUNDRY DETERGENTS COMPRISING A SILICONE ANTI-FOAM

• US 20140289969A1
• Filed: 06/12/2014
• Published: 10/02/2014
• Est. Priority Date: 03/01/2010
• Status: Active Grant

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: SADLOWSKI, Eugene Steven, SOPER, Shari Joy
• Granted Patent: US 9,120,997 B2
• Time in Patent Office: Days
• US Class Current: 8/137
• CPC Class Codes: C11D 1/002 Surface-active compounds containing sulfur SO3 and SO4, C11D1/12; sulfonium compounds C11D1/60; sulfoxides C11D1/755; sulfobetaines C11D1/92
• CPC Class Codes: C11D 1/29 Sulfates of polyoxyalkylene ethers
• CPC Class Codes: C11D 17/0026 Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
• CPC Class Codes: C11D 3/0026 Low foaming or foam regulating compositions
• CPC Class Codes: C11D 3/373 containing silicones

Abstract

Dual-usage aqueous liquid detergent compositions having suds compatibility and improved cleaning, said composition containing from about 1% to about 60%, by weight of the composition, of a surfactant system wherein said surfactant system contains at least 35%, by weight of the surfactant system, of alkylethoxysulfate; from 0% to about 10%, by weight of the surfactant system, of nonionic surfactant; from 0% to about 10%, by weight of the surfactant system, of soap; further contains from about 0.001% to about 4.0%, by weight of the composition, of an anti-foam selected from organomodified silicone polymers with aryl or alkylaryl substituents combined with silicone resin and the primary filler is modified silica; and mixtures thereof; and contains from about 0.01% to about 2.5%, by weight of the composition, of a structurant.

Methods of using such detergent compositions for laundering textiles.

Claims

1. An aqueous liquid detergent composition having suds compatibility and improved cleaning, said composition comprising:

a) from about 1% to about 60%, by weight of the composition, of a surfactant system wherein said surfactant system comprises;

i) at least 35%, by weight of the surfactant system, of alkylethoxysulfate;

iii) linear alkylbenzene sulfonate

iv) soap

b) from about 0.001% to about 4.0%, by weight of the composition, of an anti-foam selected from organomodified silicone polymers with aryl or alkylaryl substituents combined with silicone resin and a primary filler, which is modified silica;

c) from about 0.01% to about 2.5%, by weight of the composition, of a structurant, wherein the structurant is selected from;

crystalline, hydroxyl-containing stabilizers, polymer gums, and mixtures thereof.

4. An aqueous liquid detergent composition according to claim 1, wherein the surfactant system further comprises an additional surfactant selected from the group consisting of anionic surfactants, cationic surfactants, zwitterionic surfactants, and mixtures thereof.

5. An aqueous liquid detergent composition according to claim 1 wherein the anti-foam is selected from:

a) mixtures of from about 80 to about 92% ethylmethyl, methyl(2-phenylpropyl) siloxane;

from about 5 to about 14% MQ resin in octyl stearate; and

from about 3 to about 7% modified silica;

b) mixtures of from about 78 to about 92% ethylmethyl, methyl(2-phenylpropyl) siloxane;

from about 3 to about 10% MQ resin in octyl stearate;

from about 4 to about 12% modified silica; and

c) mixtures thereof.

wherein percentages are by weight of the anti-foam.

8. An aqueous liquid detergent composition according to claim 1 wherein the composition comprises from about 5% to about 50%, by weight of the composition, of the surfactant system.

9. An aqueous liquid detergent composition according to claim 1, wherein the composition comprises from about 15% to about 35%, by weight of the composition, of the surfactant system.

10. An aqueous liquid detergent composition according to claim 1 wherein the composition comprises from about 0.01% to about 2.0%%, by weight of the composition, of the silicone anti-foam.

11. An aqueous liquid detergent composition according to claim 1 wherein the surfactant system comprises from at least 50%, by weight of the surfactant system, of alkylethoxysulfate.

12. An aqueous liquid detergent composition according to claim 1 wherein the composition further comprises from about 0.1% to about 10.0%, by weight of the composition, of a laundry adjunct selected from the group consisting of enzymes, enzymes stabilizers, optical brighteners, particulate material, hydrotropes, perfume and other odour control agents, soil suspending polymers and/or soil release polymers, suds suppressors, fabric care benefits, pH adjusting agents, dye transfer inhibiting agents, preservatives, hueing dyes, non-fabric substantive dyes, encapsulated actives, and mixtures thereof.

13. An aqueous liquid detergent composition according to claim 1 wherein the composition further comprises perfume microcapsules, a hueing dye, or a mixture thereof.

14. A domestic method of treating a textile garment with an aqueous liquid detergent composition, the method comprising the steps of:

a) treating a textile with an aqueous solution comprising a mixture of water and the detergent composition of claim 1 in relative amounts such that the aqueous solution comprises from about 0.01 g/L to about 1 g/L of an alkyl ethoxy sulfate surfactant and from about 0.1 mg/L to about 100 mg/L of a silicone anti-foam; and

b) rinsing and drying the textile.

2. An aqueous liquid detergent composition having suds compatibility and improved cleaning, said composition comprising:

a) from about 1% to about 60%, by weight of the composition, of a surfactant system wherein said surfactant system comprises;

i) at least 35%, by weight of the surfactant system, of alkylethoxysulfate;

iii) linear alkylbenzene sulfonate

iv) soap

b) from about 0.001% to about 4.0%, by weight of the composition, of an anti-foam selected from organomodified silicone polymers with aryl or alkylaryl substituents combined with silicone resin and a primary filler, which is modified silica;

c) from about 0.01% to about 2.5%, by weight of the composition, of a structurant, wherein the structurant is selected from;

crystalline, hydroxyl-containing stabilizers, polymer gums, and mixtures thereof;

d) amine ethoxylate polymer.

15. An aqueous liquid detergent composition according to claim 2 wherein the composition further comprises from about 0.1% to about 10.0%, by weight of the composition, of a laundry adjunct selected from the group consisting of enzymes, enzymes stabilizers, optical brighteners, particulate material, hydrotropes, perfume and other odour control agents, soil suspending polymers and/or soil release polymers, suds suppressors, fabric care benefits, pH adjusting agents, dye transfer inhibiting agents, preservatives, hueing dyes, non-fabric substantive dyes, encapsulated actives, and mixtures thereof.

17. An aqueous liquid detergent composition according to claim 2 wherein the composition further comprises perfume microcapsules, a hueing dye, or a mixture thereof.

19. A domestic method of treating a textile garment with an aqueous liquid detergent composition, the method comprising the steps of:

a) treating a textile with an aqueous solution comprising a mixture of water and the detergent composition of claim 2 in relative amounts such that the aqueous solution comprises from about 0.01 g/L to about 1 g/L of an alkyl ethoxy sulfate surfactant and from about 0.1 mg/L to about 100 mg/L of a silicone anti-foam; and

b) rinsing and drying the textile.

3. A dual-usage aqueous liquid detergent composition having suds compatibility and improved cleaning, said composition comprising:

a) from about 1% to about 60%, by weight of the composition, of a surfactant system wherein said surfactant system comprises;

i) at least 35%, by weight of the surfactant system, of alkylethoxysulfate;

iii) linear alkylbenzene sulfonate

iv) soap

b) from about 0.001% to about 4.0%, by weight of the composition, of an anti-foam selected from organomodified silicone polymers with aryl or alkylaryl substituents combined with silicone resin and a primary filler, which is modified silica;

c) from about 0.01% to about 2.5%, by weight of the composition, of a structurant, wherein the structurant is selected from;

crystalline, hydroxyl-containing stabilizers, polymer gums, and mixtures thereof;

d) amine ethoxylate polymer;

wherein said detergent composition is adapted to be used in both a top-loading washing machine and a front-loading washing machine.

16. An aqueous liquid detergent composition according to claim 3 wherein the composition further comprises from about 0.1% to about 10.0%, by weight of the composition, of a laundry adjunct selected from the group consisting of enzymes, enzymes stabilizers, optical brighteners, particulate material, hydrotropes, perfume and other odour control agents, soil suspending polymers and/or soil release polymers, suds suppressors, fabric care benefits, pH adjusting agents, dye transfer inhibiting agents, preservatives, hueing dyes, non-fabric substantive dyes, encapsulated actives, and mixtures thereof.

18. An aqueous liquid detergent composition according to claim 3 wherein the composition further comprises perfume microcapsules, a hueing dye, or a mixture thereof.

20. A domestic method of treating a textile garment with an aqueous liquid detergent composition, the method comprising the steps of:

a) treating a textile with an aqueous solution comprising a mixture of water and the detergent composition of claim 3 in relative amounts such that the aqueous solution comprises from about 0.01 g/L to about 1 g/L of an alkyl ethoxy sulfate surfactant and from about 0.1 mg/L to about 100 mg/L of a silicone anti-foam; and

b) rinsing and drying the textile.

6. (canceled)

7. (canceled)

21. An aqueous liquid detergent composition having suds compatibility and improved cleaning, said composition comprising:

a) from about 1% to about 60%, by weight of the composition, of a surfactant system wherein said surfactant system comprises;

i) at least 35%, by weight of the surfactant system, of alkylethoxysulfate;

ii) amine oxide;

iii) linear alkylbenzene sulfonate

b) from about 0.001% to about 4.0%, by weight of the composition, of an anti-foam selected from organomodified silicone polymers with aryl or alkylaryl substituents combined with silicone resin and a primary filler, which is modified silica;

c) from about 0.01% to about 2.5%, by weight of the composition, of a structurant, wherein the structurant is selected from;

crystalline, hydroxyl-containing stabilizers, polymer gums, and mixtures thereof.

22. An aqueous liquid detergent composition according to claim 21 wherein the composition further comprises from about 0.1% to about 10.0%, by weight of the composition, of a laundry adjunct selected from the group consisting of enzymes, enzymes stabilizers, optical brighteners, particulate material, hydrotropes, perfume and other odour control agents, soil suspending polymers and/or soil release polymers, suds suppressors, fabric care benefits, pH adjusting agents, dye transfer inhibiting agents, preservatives, hueing dyes, non-fabric substantive dyes, encapsulated actives, and mixtures thereof.