Three Way Catalyst Double Impregnation Composition and Method Thereof

• US 20140301906A1
• Filed: 04/04/2013
• Published: 10/09/2014
• Est. Priority Date: 04/04/2013
• Status: Abandoned Application

• Current Assignee: Clean Diesel Technologies, Inc.
• Original Assignee: CDTI
• Inventors: Hatfield, Randal
• Application Number:
  US13/856,884
• Publication Number:
  US 20140301906A1
• Time in Patent Office: Days
• US Class Current: 422/168
• CPC Class Codes: B01D 2255/1023 Palladium
• CPC Class Codes: B01D 2255/2042 Barium
• CPC Class Codes: B01D 2255/2065 Cerium
• CPC Class Codes: B01D 2255/2068 Neodymium
• CPC Class Codes: B01D 2255/402 Perovskites
• CPC Class Codes: B01D 53/944 Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts three-way-catalysts [TWC] B01D53/9445
• CPC Class Codes: B01D 53/945 characterised by a specific catalyst
• CPC Class Codes: B01J 23/58 with alkali- or alkaline earth metals
• CPC Class Codes: B01J 23/63 with rare earths or actinides
• CPC Class Codes: B01J 35/56 Foraminous structures having flow-through passages or channels, e.g. grids or three-dimensional monoliths

Abstract

A double impregnation method and composition for producing three way catalysts (TWC) are disclosed. The TWC may generally include a substrate, a washcoat, a first and second impregnation compositions, and optionally at least an overcoat over the impregnation compositions. The first impregnation composition may include a composition of a perovskite, base metal oxides, and alkaline earth carbonates. The method for applying the first impregnation composition may include combining all base metals in the composition, adding Pd, drying, and adding a heat treatment. The method for applying the second impregnation composition may include adding a remainder of Pd as a Pd solution over the first impregnation, drying, and applying a heat treatment.

Claims

1. A catalytic converter, comprising:

a substrate; and

a washcoat on the substrate, comprising an oxide solid selected from the group consisting of at least one of a carrier material oxide and at least one catalyst;

a first impregnation composition, and a second impregnation composition;

wherein the first impregnation composition comprises a material including one or more selected from the group consisting of Ba, Ce, Nd, Sr and Pd, and the second impregnation composition comprises a material including one or more selected from the group consisting of Ba, Ce, Nd, Sr and Pd.

2. The catalytic converter of claim 1, wherein the first impregnation composition includes a perovskite, a base metal oxide, and an alkaline earth carbonate;

and the first impregnation composition is absorbed by the washcoat.

3. The catalytic converter of claim 1, wherein the first impregnation composition includes PdNO₃.

4. The catalytic converter of claim 1, wherein the first impregnation composition includes a base metal oxide selected from the group, in oxide form, consisting of at least one of Mg, Ca, Sr, Ba, Mn, Zn, Zr, Ce, Pr, Nd, Ni, Co, Fe, Rh, Pd, and rare earth elements.

5. The catalytic converter of claim 1, wherein the first impregnation composition includes a base metal oxide selected from the group consisting of at least one of CeO₂, CeZrO₂, CeZrO₂ doped with rare earth elements, NdCeO₂, and PdCeO₂.

6. The catalytic converter of claim 1, wherein the first impregnation composition includes a perovskite having a formula ABO₃;

wherein A and B are cations of different size and O is an oxide anion that bonds to both A and B.

7. The catalytic converter of claim 6, wherein A from the formula ABO₃ of the perovskite is selected from the group consisting of at least one of Sr, Ba, La, Nd, and Pr.

8. The catalytic converter of claim 6, wherein B from the formula ABO₃ of the perovskite is selected from the group consisting of at least one of La, Nd, Pr, Pd, Mn, Co, and platinum group metals.

9. The catalytic converter of claim 1, wherein the first impregnation composition includes a perovskite is selected from the group consisting of BaCeO₃, NdBaCeO₃, BaCeNdO₃, SrLaMnPdO₃, and BaLaMnPdO₃.

10. The catalytic converter of claim 2, wherein the alkaline earth carbonate is selected from the group consisting of BaCO₃, SrCO₃, and witherite.

11. The catalytic converter of claim 1, wherein the second impregnation composition is absorbed by the washcoat separately from the first impregnation composition that is absorbed by the washcoat.

12. The catalytic converter of claim 11, wherein the second impregnation composition includes PdNO₃.

13. The catalytic converter of claim 11, wherein the second impregnation composition is absorbed by the washcoat after the first impregnation composition is absorbed by the washcoat.

14. The catalytic converter of claim 13, wherein the second impregnation composition includes a base metal oxide selected from the group, in oxide form, consisting of at least one of Mg, Ca, Sr, Ba, Mn, Zn, Zr, Ce, Pr, Nd, Ni, Co, Fe, Rh, and rare earth elements.

15. The catalytic converter of claim 13, wherein the second impregnation composition includes a base metal oxide selected from the group consisting of at least one of CeO₂, CeZrO₂, CeZrO₂ doped with rare earth elements, NdCeO₂, and PdCeO₂.

16. The catalytic converter of claim 15, wherein the first impregnation composition includes a perovskite having a formula ABO₃;

wherein A and B are cations of different size and O is an oxide anion that bonds to both A and B.

17. The catalytic converter of claim 16, wherein A from the formula ABO₃ of the perovskite is selected from the group consisting of at least one of Sr, Ba, La, Nd, and Pr.

18. The catalytic converter of claim 17, wherein B from the formula ABO₃ of the perovskite is selected from the group consisting of at least one of La, Nd, Pr, Pd, Mn, Co, and platinum group metals.

19. The catalytic converter of claim 1, further comprising an overcoat that is deposited over the washcoat that includes the first impregnation composition and the second impregnation composition.

20. The catalytic converter of claim 19, wherein the overcoat includes a material that is selected from a group consisting of at least one of a catalyst and a carrier material oxide.

21. The catalytic converter of claim 19, wherein the overcoat includes at least one oxide solid selected from the group consisting of at least one of a carrier material oxide and a catalyst.

22. The catalytic converter of claim 20, wherein the overcoat includes the catalyst which is a metal from the platinum group metals selected from the group consisting of ruthenium, rhodium, palladium, iridium, and platinum.

23. The catalytic converter of claim 1, wherein the substrate is made from a material that is selected from the group consisting of at least one of a refractive material, a ceramic substrate, a honeycomb structure, a metallic substrate, a ceramic foam, a metallic foam, a reticulated foam, metallic, ceramic, alumina, silica alumina, silica, titania.

24. The catalytic converter of claim 1, wherein the substrate includes a characteristic selected from the group consisting of at least one of a plurality of channels, porosity, a three-dimensional support structure, in the form of beads, in the form of pellets, a ceramic honeycomb substrate, a monolithic carrier, a monolithic carrier that a plurality of parallel flow passages extending through the monolith, a monolithic carrier that a plurality of parallel flow passages extending through the monolith wherein the flow passages have shape selected from the group consisting of trapezoidal, rectangular, square, sinusoidal, hexagonal, oval, and circular, and the monolith containing from about 9 to about 1200 gas inlet openings per square inch of cross section.

25. The catalytic converter of claim 1, wherein the substrate is a metal honeycomb substrate made from a heat-resistant base metal alloy that includes iron.

26. The catalytic converter of claim 1, wherein the substrate is a ceramic honeycomb substrate that may be formed from a material selected from the group consisting of at least one of:

sillimanite, zirconia, petalite, spodumene, magnesium silicates, mullite, alumina, cordierite, alumino-silicate, silicon carbide, and aluminum nitride.

27. The catalytic converter of claim 1, wherein the washcoat includes the carrier material oxide selected from the group consisting of at least one of an oxygen storage material, aluminum oxide, doped aluminum oxide, spinel, delafossite, lyonsite, garnet, perovskite, pyrochlore, doped ceria, fluorite, zirconium oxide, doped zirconia, titanium, tin oxide, and silicon dioxide.

28. A method of making a catalytic converter, the method comprising the steps of:

providing a substrate;

applying a washcoat on the substrate;

applying a first impregnation composition on the washcoat;

wherein the first impregnation composition includes a perovskite, a base metal oxide, and an alkaline earth carbonate;

drying the first impregnation composition;

applying heat to the first impregnation composition;

applying a second impregnation composition over the first impregnation composition after drying the first impregnation composition;

drying the second impregnation composition; and

applying heat to the second impregnation composition.

29. The method of claim 28, further comprising the steps of:

determining an amount of Pd to use in first and second impregnation compositions;

adding a first portion of the amount of Pd to the first impregnation compositions prior to said drying and said applying heat to the first impregnation compositions.

30. The method of claim 29, wherein said adding the first portion of the amount of Pb comprises a rate of about 50 g/ft³ to about 100 g/m of the washcoat.

31. The method of claim 29, wherein said applying the washcoat on the substrate comprises suspending oxide solids in water to form an aqueous slurry;

and applying the aqueous slurry on the substrate.

32. The method of claim 31, further comprising the step of:

adding a material selected from a group consisting of ammonium hydroxide, aluminum hydroxide, acetic acid, citric acid, tetraethylammonium hydroxide, other tetralkylammonium salts, ammonium acetate, ammonium citrate, glycerol, polyethylene glycol, polyvinyl alcohol and polymers to the aqueous slurry to adjust rheology of the aqueous slurry.

33. The method of claim 31, further comprising the step of:

applying the aqueous slurry on the substrate by a method selected from the group consisting of dipping and spraying.

34. The method of claim 28, further comprising the step of:

cooling the washcoat and substrate to about room temperature.