System and Method for ZPGM Catalytic Converters

• US 20140301909A1
• Filed: 04/04/2013
• Published: 10/09/2014
• Est. Priority Date: 04/04/2013
• Status: Abandoned Application

• Current Assignee: Clean Diesel Technologies, Inc.
• Original Assignee: CDTI
• Inventors: Nazarpoor, Zahra
• Application Number:
  US13/856,904
• Publication Number:
  US 20140301909A1
• Time in Patent Office: Days
• US Class Current: 422/177
• CPC Class Codes: B01D 2255/104 Silver
• CPC Class Codes: B01D 2255/2045 Calcium
• CPC Class Codes: B01D 2255/2061 Yttrium
• CPC Class Codes: B01D 2255/2063 Lanthanum
• CPC Class Codes: B01D 2255/2065 Cerium
• CPC Class Codes: B01D 2255/20715 Zirconium
• CPC Class Codes: B01D 2255/2073 Manganese
• CPC Class Codes: B01D 2255/20738 Iron
• CPC Class Codes: B01D 2255/20746 Cobalt
• CPC Class Codes: B01D 2255/20761 Copper
• CPC Class Codes: B01D 2255/209 Other metals
• CPC Class Codes: B01D 2255/2094 Tin
• CPC Class Codes: B01D 2255/9022 Two layers
• CPC Class Codes: B01D 2255/908 O2-storage component incorporated in the catalyst
• CPC Class Codes: B01D 2255/9202 Linear dimensions
• CPC Class Codes: B01D 53/945 characterised by a specific catalyst
• CPC Class Codes: B01J 23/02 of the alkali- or alkaline earth metals or beryllium
• CPC Class Codes: B01J 23/10 of rare earths
• CPC Class Codes: B01J 23/14 of germanium, tin or lead
• CPC Class Codes: B01J 23/20 Vanadium, niobium or tantalum
• CPC Class Codes: B01J 23/34 : Manganese
• CPC Class Codes: B01J 23/50 : Silver
• CPC Class Codes: B01J 23/72 : Copper
• CPC Class Codes: B01J 23/745 : Iron
• CPC Class Codes: B01J 23/75 : Cobalt
• CPC Class Codes: Y02T 10/12 : Improving ICE efficiencies

Abstract

Compositions and methods for the preparation of ZPGM oxidation catalytic converters are disclosed. ZPGM catalyst systems may be employed within catalytic converters under lean hydrocarbon, air to fuel ratio condition to oxidize toxic gases, such as carbon monoxide and other hydrocarbons that may be included in exhaust gas. ZPGM oxidation catalyst systems are completely free of PGM catalyst and may include: a substrate, a washcoat, and an overcoat. Washcoat may include silver as ZPGM catalyst, and carrier material oxides. Similarly, overcoat may include at least one ZPGM catalyst, carrier material oxides and OSMs. Overcoat of the disclosed ZPGM catalyst system may include copper and cerium as ZPGM catalysts. Suitable known in the art chemical techniques, deposition methods and treatment systems may be employed in order to form the disclosed ZPGM catalyst systems. ZPGM catalyst systems may include high surface area, low conversion temperature catalysts that may exhibit high efficiency in the conversion of exhaust gases

Claims

1. A catalytic converter comprising:

a substrate;

a washcoat on the substrate; and

an overcoat on the washcoat;

wherein the washcoat includes an oxide solid comprising least one a carrier material oxide milled with at least one catalyst;

wherein the washcoat includes a first impregnation composition that includes at least one selected from the group comprising transition metals, alkali and alkaline earth metals, cerium, lanthanum, yttrium, lanthanides, actinides, or mixtures thereof; and

wherein the first impregnation composition is absorbed by the washcoat.

2. The catalytic converter of claim 1, wherein the at least one catalyst is a zero platinum group metal (ZPGM).

3. The catalytic converter of claim 2, wherein the ZPGM is selected from the group consisting of copper, cerium, silver, tin, niobium, zirconium, lanthanum, iron, cobalt, manganese, calcium and combinations thereof.

4. The catalytic converter of claim 1, wherein the overcoat comprises at least one second catalyst.

5. The catalytic converter of claim 4, wherein the at least one second catalyst comprises a ZPGM.

6. The catalytic converter of claim 5, wherein the ZPGM is selected from the group consisting of copper, cerium, silver, tin, niobium, zirconium, lanthanum, iron, cobalt, manganese, calcium and combinations thereof.

7. The catalytic converter of claim 1, wherein the overcoat further comprises at least one oxygen storage material.

8. The catalytic converter of claim 1, wherein the oxygen storage material is selected from the group consisting of at least one of cerium, zirconium, neodymium, praseodymium, samarium, lanthanum, and yttrium.

9. The catalytic converter of claim 1, wherein the at least one catalyst comprises silver and is about 4% to about 10% by weight of the washcoat.

10. The catalytic converter of claim 1, wherein the at least one catalyst comprises silver, copper, and cerium and has suitable oxidation properties at less than about 300°

Celsius.

11. The catalytic converter of claim 1, wherein the substrate is selected from the group consisting of a refractive material, a ceramic substrate, a metallic substrate, a ceramic foam, a metallic foam, a reticulated foam, and mixtures thereof.

12. The catalytic converter of claim 1, wherein the substrate comprises at least one of the group consisting of zeolites, cordierites, or mixtures thereof.

13. The catalytic converter of claim 1, wherein the particle size of the oxide solid is about 4 microns to about 10 microns.

14. A catalytic converter comprising:

a substrate;

a washcoat located on the substrate; and

an overcoat located on the washcoat;

wherein the washcoat includes an oxide solid consisting of at least one of a carrier material oxide precipitated with at least one catalyst;

wherein the washcoat includes a first impregnation composition;

wherein the first impregnation composition includes at least one selected from the group comprising transition metals, alkali and alkaline earth metals, cerium, lanthanum, yttrium, lanthanides, actinides, or mixtures thereof; and

wherein the first impregnation composition is absorbed by the washcoat.

15. The catalytic converter of claim 14, wherein the at least one catalyst is a zero platinum group metal (ZPGM).

16. The catalytic converter of claim 15, wherein the ZPGM is selected from the group consisting of copper, cerium, silver, tin, niobium, zirconium, lanthanum, iron, cobalt, manganese, calcium and combinations thereof.

17. The catalytic converter of claim 15, wherein the ZPGM is selected from the group consisting of copper, cerium, silver, tin, niobium, zirconium, lanthanum, iron, cobalt, manganese, calcium and combinations thereof.

18. The catalytic converter of claim 14, wherein the overcoat further comprises at least one oxygen storage material.

19. The catalytic converter of claim 18, wherein the oxygen storage material is selected from the group consisting of at least one of cerium, zirconium, neodymium, praseodymium, samarium, lanthanum, and yttrium.

20. The catalytic converter of claim 15, wherein the ZPGM comprises silver and is about 4% to about 10% by weight of the washcoat.

21. The catalytic converter of claim 14, wherein particle size of the oxide solid is about 4 microns to about 10 microns.