Multi-Barrier System For Water Treatment

• US 20140353256A1
• Filed: 12/18/2012
• Published: 12/04/2014
• Est. Priority Date: 12/22/2011
• Status: Abandoned Application

• Current Assignee: ItN Nanovation AG
• Original Assignee: ItN Nanovation AG
• Inventors: Grnitz, Christof, Kaschek, Martin, Verplancke, Sylvie
• Application Number:
  US14/366,563
• Publication Number:
  US 20140353256A1
• Time in Patent Office: Days
• US Class Current: 210/663
• CPC Class Codes: C02F 1/001 Processes for the treatment of water whereby the filtration technique is of importance C02F1/44 takes precedence; construction of filters in general B01D24/00 - B01D41/00
• CPC Class Codes: C02F 1/32 with ultraviolet light
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration
• CPC Class Codes: C02F 1/725 by catalytic oxidation
• CPC Class Codes: C02F 1/78 with ozone C02F1/4672 takes precedence
• CPC Class Codes: C02F 2201/008 Mobile apparatus and plants, e.g. mounted on a vehicle for biological treatment C02F2203/008
• CPC Class Codes: C02F 2201/784 Diffusers or nozzles for ozonation
• CPC Class Codes: C02F 2209/23 O3
• CPC Class Codes: C02F 2301/046 Recirculation with an external loop
• CPC Class Codes: C02F 2303/04 Disinfection
• CPC Class Codes: C02F 2303/20 Prevention of biofouling
• CPC Class Codes: C02F 9/00 Multistage treatment of water, waste water or sewage

Abstract

A multi-barrier system for cleaning waste water, in particular for the removal of pathogenic microbes from waste water, and a method for the removal of pathogenic microbes from waste water with the multi-barrier system. The multi-barrier system includes an enclosed containment that comprises a first water container, an adjustable ozonation unit, a second water container and a UV unit. In addition, the first water container comprises an ozone-resistant filtration unit.

Claims

1. A multi-barrier system for the removal of pathogenic microbes from waste water comprising a first water container, an adjustable ozonation unit, a second water container and a UV unit,

wherein the first water container comprises an ozone-resistant filtration unit that includes at least one membrane plate of porous oxidic ceramics, the membrane plate has pores with an average diameter of between 1 μ

m and 10 μ

M, a coating outside and at least one channel inside for the drainage of a filtrate, and the coating comprises at least one separating layer produced with a coating slip comprising nanoscale and/or microscale oxidic particles, wherein the at least one channel of the membrane plate is connected with the second water container so the filtrate can be transferred into the second water container,

wherein the adjustable ozonation unit is coupled with a sprinkler system,

and the ozonation unit includes an ozone outlet positioned in the first water container and an outlet of the sprinkler system is located above the water level of the first water container,

wherein the UV unit is positioned such that the filtrate in the second water container is irradiated by the UV unit, and

wherein the first water container, the ozone-resistant filtration unit, the adjustable ozonation unit, the second water container and the UV unit are placed in a closed containment.

2. Multi-barrier system according to claim 1, wherein the porous oxidic ceramics of the membrane plate have pores with an average diameter in the range of between 1 μ

m and 6 μ

m, or between 1 μ

m and 3 μ

m.

3. Multi-barrier system according to claim 1, wherein the porous oxidic ceramics are aluminium oxide-based ceramics.

4. Multi-barrier system according to claim 1, wherein the outside coating of the membrane plate has a thickness in the range of between 100 nm and 150 μ

m, or from 25 μ

m to 60 μ

m.

5. Multi-barrier system according to claim 4, wherein the separating layer has pores with an average diameter in the range of between 1 nm and 1400 nm, between 50 nm and 300 nm, or between 200 nm and 300 nm.

6. Multi-barrier system according to claim 5, wherein the oxidic nanoparticles and/or microparticles of the separating layer are preferably selected from the group consisting of aluminium oxide, zirconium oxide, titanium dioxide, and mixtures thereof.

7. Multi-barrier system according to claim 4, wherein the coating of the membrane plate comprises at least one porous layer arranged between the membrane plate and the separating layer.

8. Multi-barrier system according to claim 1, wherein the UV unit comprises a mercury vapour lamp or a UV-LED lamp.

9. Multi-barrier system according to claim 1, wherein the closed containment is transportable.

10. Multi-barrier system according to claim 9, wherein the containment has maximum dimensions of 6.06 m×

2.44 m×

2.59 m and a maximum weight of 25,000 kg.

11. A method for the removal of pathogenic microbes from waste water by means of a multi-barrier system according to claim 1, the method comprising the steps of

a) providing a supply of waste water contaminated with pathogenic microbes into the first water container,

b) filtering the waste water through the ozone-resistant filtration unit with the at least one coated membrane plate, wherein the waste water is treated with ozone in the first water container during filtration and the ozone content in the waste water is controlled with the ozonation unit being coupled to the sprinkler system,

c) transferring the filtrate through the at least one channel of the membrane plate into the second water container,

d) irradiation of irradiating the filtrate in the second water container with UV radiation in a wavelength range of from 100 nm to 300 nm and a dose of from 50 J/m² to 2000 J/m².

12. Method for the removal of pathogenic microbes from waste water according to claim 11, wherein the total concentration of pathogenic microbes being present in the water upon release of the filtrate from the second water container is less than 100 KbE/ml, less than 10 KbE/ml, or less than 1 KbE/ml.

13. Method for the removal of pathogenic microbes from waste water according to claim 11, wherein the pathogenic microbes being present in the waste water are removed from the waste water to an extent of at least 99.90%, or at least 99.99%.

14. Method for the removal of pathogenic microbes from waste water according to claim 11, wherein the ozone penetrates the at least one coated membrane plate of the ozone-resistant filtration unit during operation.

15. Method for the removal of pathogenic microbes from waste water according to claim 11, wherein the ozone concentration is detected in the filtrate in the outlet of the first water container and the amount of ozone to be supplied to the first water container is adjusted such that the concentration of ozone in the filtrate in the outlet is between 0.1 mg/l and 0.3 mg/l.

16. Method for the removal of pathogenic microbes from waste water according to claim 11, wherein the ozone concentration is detected in the airspace in the first water container and the sprinkler system turns on automatically if the ozone concentration reaches a value selected from 0.5 mg/m 0.3 mg/m³, or 0.1 mg/m³.

17. Method for the removal of pathogenic microbes from waste water according to claim 11, wherein the dose of UV irradiation is reduced by a factor of 2, a factor of 3, or a factor of 4, compared with a system for the removal of pathogenic microbes that does not include a filtration unit.

18. Method for the removal of pathogenic microbes from waste water according to claim 11, wherein the turbidity of the water being present in the second water container is less than 1 NTU, less than 0.5 NTU, or less than 0.2 NTU.

19. Method for the removal of pathogenic microbes from waste water according to claim 11, wherein the service life of the multi-barrier system is extended by a factor of 5, a factor of 10, a factor of 15, compared with a system for the removal of pathogenic microbes from waste water without ozonation and without irradiation with an UV unit.

20. Method for the removal of pathogenic microbes from waste water according to claim 11, wherein a biological cleaning stage is conducted upstream of the multi-barrier system.

21. Method for the removal of pathogenic microbes from waste water according to claim 11, wherein the pathogenic microbes are selected from the group consisting of viruses, bacteria, protozoa, and helminthes, and particularly preferred bacteria.

22. Method for the removal of pathogenic microbes from waste water according to claim 20, wherein the bacteria are selected from the group consisting of Escherichia coli, Salmonella, Shigella, Mycobacterium tuberculosis, and Vibrio cholerae.

23. Multi-barrier system according to claim 2, wherein the outside coating of the membrane plate has a thickness of between 25 μ

m and 60 μ

m.

24. Multi-barrier system according to claim 4, wherein the separating layer has pores with an average diameter of between 50 nm and 300 nm.