PROCESSES FOR RECOVERING RARE EARTH ELEMENTS FROM VARIOUS ORES

• US 20140373683A1
• Filed: 05/03/2012
• Published: 12/25/2014
• Est. Priority Date: 05/04/2011
• Status: Active Grant

• Current Assignee: AEM Technologies Incorporated
• Original Assignee: Orbite Aluminae Inc.
• Inventors: Boudreault, Richard, Fournier, Jol, Primeau, Denis, Simoneau, Raymond, Garcia, Maria Cristina, Krivanec, Heinz, Dittrich, Carsten
• Granted Patent: US 9,410,227 B2
• Time in Patent Office: Days
• US Class Current: 75/743
• CPC Class Codes: C22B 26/12 Obtaining lithium
• CPC Class Codes: C22B 3/10 Hydrochloric acid , other halogenated acids or salts thereof
• CPC Class Codes: C22B 3/26 by liquid-liquid extraction using organic compounds
• CPC Class Codes: C22B 3/46 by substitution, e.g. by cementation
• CPC Class Codes: C22B 34/14 Obtaining zirconium or hafnium treatment or purification of solutions by liquid-liquid extraction, by ion exchange or by adsorption C22B3/00, C01G25/003, C01G27/003
• CPC Class Codes: C22B 34/34 Obtaining molybdenum treatment or purification of solutions by adsorption on solids C22B3/24, by liquid-liquid extraction C22B3/26, by ion-exchange extraction C22B3/42; preparation of molybdenum involving liquid-liquid extraction, adsorption or ion-exchange C01G39/003
• CPC Class Codes: C22B 58/00 Obtaining gallium or indium treatment or purification of solutions by liquid-liquid extraction, by ion-exchange or by adsorption C22B3/20
• CPC Class Codes: C22B 59/00 Obtaining rare earth metals
• CPC Class Codes: Y02P 10/20 Recycling

Abstract

The present disclosure relates to processes for recovering rare earth elements from various materials. The processes can comprise leaching the at least one material with at least one acid so as to obtain a leachate comprising at least one metal ion and at least one rare earth element, and a solid, and separating the leachate from the solid. The processes can also comprise substantially selectively removing at least one of the at least one metal ion from the leachate and optionally obtaining a precipitate. The processes can also comprise substantially selectively removing the at least one rare earth element from the leachate and/or the precipitate.

Claims

1. A process for recovering at least one rare earth element and/or at least one rare metal chosen from In, Zr, Li and Ga from at least one material, said process comprising:

leaching said at least one material with HCl so as to obtain a leachate comprising a first metal ion, a second metal ion, said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga, and a solid, and separating said leachate from said solid;

substantially selectively removing said first metal ion from said leachate, thereby obtaining a composition comprising said second metal ion and said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga;

substantially selectively at least partially removing said second metal ion from said composition, thereby obtaining a liquor comprising said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga; and

substantially selectively removing said at least one rare earth element and/or at least one rare metal chosen from In, Zr, Li and Ga from said liquor, wherein said liquor comprises GaCl₃ and is reacted with a first extracting agent in order to substantially selectively extract GaCl₃ therefrom, thereby obtaining a Ga-free solution and an extracted gallium solution, and separating said solutions from one another.

4. The process of claim 1, wherein said first metal ion is substantially selectively removed from said leachate by substantially selectively precipitating it from said leachate and removing it therefrom by carrying out a solid-liquid separation.

5. The process of claim 1, wherein said first metal ion is at least one aluminum ion and is substantially selectively removed from said leachate by substantially selectively precipitating it under the form of AlCl₃ and removing it therefrom by carrying out a solid-liquid separation.

6. The process of claim 1, wherein said composition comprises HCl, said second metal ion, and said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga.

10. The process of claim 4, wherein said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga is substantially selectively precipitated, extracted and/or isolated from said liquor by means of a liquid-liquid extraction.

24. The process of claim 1, wherein said extracted GaCl₃ is then precipitated and then converted into Ga₂O₃.

25. The process of claim 1, wherein the Ga-free solution is then reacted with another an extracting agent in order to substantially selectively extract cerium therefrom, thereby obtaining a Ce-free solution and an extracted cerium solution, and separating said solutions from one another.

26. The process of claim 25, wherein said cerium in said Ga-free solution is under the form of CeCl₃.

29. The process of claim 26, further comprising reacting the Ce-free solution with a further extracting agent in order to substantially selectively extract scandium therefrom, thereby obtaining a Sc-free solution and an extracted scandium solution, and separating said solutions from one another.

34. The process of claim 29, further comprising reacting the Sc-free solution with still a further extracting agent in order to substantially selectively extract samarium, europium or a mixture thereof, thereby obtaining a Sm-free solution and/or Eu-free solution and extracted samarium and/or europium solution, and separating said solutions from one another.

36. The process of claim 34, further comprising reacting the Sm-free solution and/or Eu-free solution with still another extracting agent in order to substantially selectively extract gadolinium, thereby obtaining a Gd-free solution and an extracted gadolinium solution, and separating said solutions from one another.

38. The process of claim 36, further comprising reacting the Gd-free solution with yet another extracting agent in order to substantially selectively extract yttrium, thereby obtaining a Y-free solution and an extracted yttrium solution, and separating said solutions from one another.

41. The process of claim 38, further comprising reacting the Y-free solution with still yet another extracting agent in order to substantially selectively extract dysprosium and/or erbium, thereby obtaining a Dy-free solution and/or an Er-free solution and an extracted dysprosium and/or erbium solution, and separating said solutions from one another.

45. The process of claim 1, wherein said first extracting agent is tri-butyl phosphate in kerosene.

46. The process of claim 1, wherein said Ga-free solution is reacted with a precipitating agent for precipitating at least one rare earth element present in said Ga-free solution, thereby obtaining a precipitate containing said at least one rare earth element and recovering said precipitate via a solid-liquid separation.

64. The process of claim 1, wherein said at least one rare earth element is substantially selectively removed by means of a liquid-liquid extraction.

75. The process of claim 1, wherein said at least one rare element is chosen from scandium, gallium, yttrium and cerium and said at least one rare metal chosen from In, Zr, Li and Ga is gallium.

78. The process of claim 1, wherein said at least one rare earth element is scandium.

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156. A process for recovering at least one rare earth element and/or at least one rare metal chosen from In, Zr, Li and Ga from at least one material, said process comprising:

leaching said at least one material with HCl so as to obtain a leachate comprising a first metal ion, a second metal ion, said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga, and a solid, and separating said leachate from said solid;

substantially selectively removing said first metal ion from said leachate, thereby obtaining a composition comprising said second metal ion and said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga;

substantially selectively at least partially removing said second metal ion from said composition, thereby obtaining a liquor comprising said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga;

substantially selectively removing said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga from said liquor, wherein said liquor is reacted with a first extracting agent in order to substantially selectively extract gallium therefrom, thereby obtaining a Ga-free solution and an extracted gallium solution, and separating said solutions from one another; and

reacting said Ga-free solution with a precipitating agent for precipitating at least one rare earth element present in said Ga-free solution, thereby obtaining a precipitate containing said at least one rare earth element and recovering said precipitate via a solid-liquid separation.

157. A process for recovering at least one rare earth element and/or at least one rare metal chosen from In, Zr, Li and Ga from at least one material, said process comprising:

leaching said at least one material with HCl so as to obtain a leachate comprising a first metal ion, a second metal ion, said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga, and a solid, and separating said leachate from said solid;

substantially selectively removing said first metal ion from said leachate, thereby obtaining a composition comprising said second metal ion and said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga;

substantially selectively at least partially removing said second metal ion from said composition, thereby obtaining a liquor comprising said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga, wherein said second metal ion is at least one iron ion and is substantially selectively removed from said composition by carrying out an hydrolysis so as to convert said at least one iron ion into Fe₂O₃ and removing said precipitated Fe₂O₃ from said composition by carrying out a solid-liquid separation, thereby obtaining said liquor comprising said at least one rare earth element and/or said at least one rare metal chosen from In, Zr, Li and Ga from said liquor; and

substantially selectively removing said at least one rare earth element and/or at least one rare metal chosen from In, Zr, Li and Ga from said liquor.