LOW-K OXIDE DEPOSITION BY HYDROLYSIS AND CONDENSATION
First Claim
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1. A method of depositing a film on a semiconductor substrate, the method comprising:
- introducing process gases comprising a silicon-containing precursor, an oxidant, and a halogen-free acid catalyst compound to a reaction chamber; and
exposing the substrate to the process gases under conditions such that a condensed flowable film forms on the substrate,wherein the chemical reactions that form the flowable film comprise a SN1 hydrolysis mechanism and condensation.
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Abstract
Methods for depositing flowable dielectric films using halogen-free precursors and catalysts on a substrate are provided herein. Halogen-free precursors and catalysts include self-catalyzing aminosilane compounds and halogen-free organic acids. Flowable films may be used to fill pores in existing dielectric films on substrates having exposed metallization layers. The methods involve hydrolysis and condensation reactions.
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Citations
20 Claims
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1. A method of depositing a film on a semiconductor substrate, the method comprising:
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introducing process gases comprising a silicon-containing precursor, an oxidant, and a halogen-free acid catalyst compound to a reaction chamber; and exposing the substrate to the process gases under conditions such that a condensed flowable film forms on the substrate, wherein the chemical reactions that form the flowable film comprise a SN1 hydrolysis mechanism and condensation. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10)
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11. A method of depositing a film on a semiconductor substrate, the method comprising:
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introducing process gases comprising a silicon-containing precursor, an oxidant, and a halogen-free catalyst compound to a reaction chamber; and exposing the substrate to the process gases under conditions such that a condensed flowable film forms on the substrate, wherein the catalyst compound is selected from the group consisting of sulfonic acid, picric acid, tartaric acid, citric acid, ethylenediaminetetraacetic acid, pyrophosphoric acid, and combinations thereof. - View Dependent Claims (12)
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13. A method of depositing a film on a semiconductor substrate, the method comprising:
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introducing process gases comprising a silicon-containing precursor and an oxidant to a reaction chamber; and exposing the substrate to the process gases under conditions such that a condensed flowable film forms on the substrate, wherein the silicon-containing precursor is a halogen-free self-catalyzing aminosilane compound, and wherein the chemical reactions that form the flowable film comprise a hydrolysis mechanism between an amine group on the aminosilane compound and the oxidant, and condensation. - View Dependent Claims (14, 15, 16, 17, 18)
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19. A method of depositing a film on a semiconductor substrate, the method comprising:
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introducing process gases comprising a halogen-free silicon-containing precursor and an oxidant to a reaction chamber; and exposing the substrate to the process gases under conditions such that a condensed flowable film forms on the substrate, wherein the halogen-free silicon-containing precursor is selected from the group consisting of dimethylamino trimethylsilane, dimethylaminotriethylsilane, bisdimethylaminodiethylsilane, trisdimethylamino methylsilane, trismethylamino methylsilane, trismethylamino silane, bisdimethylamino dimethylsilane, bisdimethylamino ethoxy methyl silane, methylamino diethoxy methyl silane, trismethylamino vinyl silane, bismethylamino divinyl silane, bisdimethylamino ethoxy vinyl silane acetoxysilane, and combinations thereof. - View Dependent Claims (20)
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Specification