Optimization of Zero-PGM Metal Loading on Metallic Substrates

• US 20150005159A1
• Filed: 06/26/2013
• Published: 01/01/2015
• Est. Priority Date: 06/26/2013
• Status: Abandoned Application

• Current Assignee: Clean Diesel Technologies, Inc.
• Original Assignee: CDTI
• Inventors: Nazarpoor, Zahra, Kitazumi, Sen, Ngo, Johnny T.
• Application Number:
  US13/927,953
• Publication Number:
  US 20150005159A1
• Time in Patent Office: Days
• US Class Current: 502/304
• CPC Class Codes: B01D 2255/104 Silver
• CPC Class Codes: B01D 2255/2065 Cerium
• CPC Class Codes: B01D 2255/20707 Titanium
• CPC Class Codes: B01D 2255/20715 Zirconium
• CPC Class Codes: B01D 2255/20761 Copper
• CPC Class Codes: B01D 2255/908 O2-storage component incorporated in the catalyst
• CPC Class Codes: B01D 53/944 Simultaneously removing carbon monoxide, hydrocarbons or carbon making use of oxidation catalysts three-way-catalysts [TWC] B01D53/9445
• CPC Class Codes: B01J 23/83 with rare earths or actinides
• CPC Class Codes: B01J 23/894 with rare earths or actinides
• CPC Class Codes: B01J 37/0225 of metal substrates
• CPC Class Codes: B01J 37/0244 Coatings comprising several layers

Abstract

The present disclosure refers to a plurality of process employed for optimization of Zero-PGM metal loading in Washcoat and Overcoat on metallic substrates. According to an embodiment a substantial increase in conversion of HC and CO may be achieved by optimizing the metal loading of the catalyst. According to another embodiment, the present disclosure may provide solutions to determine the optimum metal loading in washcoat for minimizing washcoat adhesion loss. As a result, may increase the conversion of HC and CO from discharge of exhaust gases from internal combustion engines, optimizing performance of Zero-PGM catalyst systems.

Claims

1. A method for optimizing a catalytic system, comprising:

providing a catalyst system, comprising;

a substrate;

a washcoat suitable for deposition on the substrate, comprising at least one first oxide solid selected from the group consisting of a first carrier material oxide, at least one first catalyst, and a mixture thereof; and

an overcoat suitable for deposition on the substrate, comprising at least one second oxide solid selected from the group consisting of a second carrier material oxide, at least one second catalyst, and a mixture thereof;

adjusting an amount of metal in the at least one first catalyst whereby the T50 temperatures for HC and CO are substantially equal.

2. The method according to claim 1, wherein the metal is selected from the group consisting of Cu, Ag, Ce, and combinations thereof.

3. The method according to claim 2, wherein the silver in present at about 5.5 g/L.

4. The method according to claim 2, wherein the copper in present at about 6.5 g/L.

5. The method according to claim 4, wherein the ratio of cerium to copper remains substantially unchanged.

6. The method according to claim 2, wherein the copper in present at less than about 8.0 g/L.

7. The method according to claim 1, wherein the substrate is metallic.

8. The method according to claim 1, wherein the overcoat further comprises at least one oxygen storage material.

9. The method according to claim 1, wherein the first carrier material oxide is selected from the group consisting of CeO₂, ZrO₂, TiO₂, and combinations thereof.

10. The method according to claim 1, wherein the second carrier material oxide is selected from the group consisting of CeO₂, ZrO₂, TiO₂, and combinations thereof.

11. A method for optimizing a catalytic system, comprising:

providing a catalyst system, comprising;

a substrate;

a washcoat suitable for deposition on the substrate, comprising at least one first oxide solid selected from the group consisting of a first carrier material oxide, at least one first catalyst, and a mixture thereof; and

an overcoat suitable for deposition on the substrate, comprising at least one second oxide solid selected from the group consisting of a second carrier material oxide, at least one second catalyst, and a mixture thereof;

adjusting an amount of metal in the at least one first catalyst in accordance with the union of the T50 temperature for HC and washcoat adhesion loss.

12. The method according to claim 11, wherein the washcoat adhesion loss is about 0.5%.

13. The method according to claim 11, wherein the washcoat adhesion loss is about 0.5%.

14. The method according to claim 11, wherein the metal is selected from the group consisting of Cu, Ag, Ce, and combinations thereof.

15. The method according to claim 14, wherein the Ag is present at about 4.8 g/L to about 7.2 g/L.

16. The method according to claim 14, wherein the Cu is present at about 6 g/L to about 10 g/L and wherein the washcoat adhesion loss is about 1% to about 8%.

17. The method according to claim 14, wherein the Cu is present at about 6.5 g/L and Ce is present at about 7.8 g/L.