CHARACTERIZATION AND PREDICTION OF JET FUEL QUALITY

• US 20150041634A1
• Filed: 10/29/2013
• Published: 02/12/2015
• Est. Priority Date: 11/29/2012
• Status: Abandoned Application

• Current Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Original Assignee: ExxonMobil Research & Engineering Company (Exxon Mobil Corporation)
• Inventors: Quann, Richard J., Novak, William J., Qian, Kuangnan, Gaughan, Roger G., Riedinger, William E., Gooding, Beatrice M.
• Application Number:
  US14/065,626
• Publication Number:
  US 20150041634A1
• Time in Patent Office: Days
• US Class Current: 250/282
• CPC Class Codes: C10G 45/10 containing platinum group metals or compounds thereof
• CPC Class Codes: C10L 1/00 Liquid carbonaceous fuels
• CPC Class Codes: C10L 2270/04 for turbines, planes, power generation
• CPC Class Codes: C10L 2290/60 Measuring or analysing fractions, components or impurities or process conditions during preparation or upgrading of a fuel
• CPC Class Codes: G01N 33/22 Fuels, explosives liquid hydrocarbons G01N33/28
• CPC Class Codes: G01N 33/2805 investigating the resistance to heat or oxidation to the weather, to corrosion, or to light G01N17/00
• CPC Class Codes: G01N 33/2841 gas in oil, e.g. hydrogen in insulating oil
• CPC Class Codes: H01J 49/0027 Methods for using particle spectrometers

Abstract

Systems and methods are provided for characterizing kerosene fractions in order to determine whether the fractions will satisfy a desired thermal breakpoint specification. Additionally, hydrotreating conditions can be determined that will result in a hydrotreated kerosene fraction that satisfies the desired thermal breakpoint specification. The hydrotreating conditions can be determined based on a model constructed from data corresponding to a plurality of reference samples. The model can include data for compositional groups within the reference samples. The data for compositional groups can be derived from Fourier transform ion cyclotron resonance mass spectrometry data or from another suitable characterization technique.

Claims

1. A method for preparing a jet fuel or kerosene product, comprising:

measuring a thermal breakpoint for a plurality of kerosene fractions;

measuring one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for the plurality of kerosene fractions;

analyzing the plurality of kerosene fractions, using Fourier transform ion cyclotron resonance mass spectrometry, to determine weights for the plurality of compositional groups within each kerosene fraction;

constructing a model for correlating a thermal breakpoint of a kerosene fraction with a) the one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for a kerosene fraction, and b) weights for a plurality of compositional groups in a kerosene fraction, the model being constructed based on the measured thermal breakpoints for the plurality of kerosene fractions, the measured values for the one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for the plurality of kerosene fractions, and the determined weights for the plurality of compositional groups for the plurality of kerosene fractions;

determining, for a first kerosene fraction, a thermal breakpoint and the one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity;

assigning weights for a plurality of compositional groups for the first kerosene fraction based on the determined thermal breakpoint and the determined one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity;

selecting hydroprocessing conditions for the first kerosene fraction based on the assigned weights for the plurality of compositional groups, the determined one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity, and the constructed model; and

hydroprocessing the first kerosene fraction using the selected hydroprocessing conditions.

2. The method of claim 1, wherein the plurality of kerosene fractions are derived from a single oil source.

3. The method of claim 1, wherein one or more of the plurality of kerosene fractions are derived from a biological source, a pre-refined crude oil source, or an oil source that has been exposed to a cracking process.

4. The method of claim 1, wherein one or more kerosene fractions in the plurality of kerosene fractions are hydrotreated kerosene fractions.

5. The method of claim 4, wherein a plurality of the one or more hydrotreated kerosene fractions are related to at least one other kerosene fraction in the plurality of kerosene fraction based on being derived from the same oil source.

6. The method of claim 1, wherein one or more kerosene fractions in the plurality of kerosene fractions comprise aged kerosene fractions.

7. The method of claim 1, wherein measuring one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for the plurality of kerosene fractions comprises measuring a sulfur content, a nitrogen content, and an API gravity.

8. The method of claim 1, further comprising:

measuring a thermal breakpoint for the hydroprocessed first kerosene fraction;

measuring the one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for the hydroprocessed first kerosene fraction; and

updating the constructed model by incorporating the first kerosene fraction and the hydroprocessed first kerosene fraction into the plurality of kerosene fractions.

9. The method of claim 1, wherein the weights for the plurality of compositional groups further comprise at least one weight for a compound.

10. The method of claim 1, wherein determining one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for the first kerosene fraction comprises measuring a sulfur content, a nitrogen content, and an API gravity.

11. The method of claim 1, wherein determining a thermal breakpoint further comprises determining a breakpoint stability.

12. The method of claim 1, wherein a thermal breakpoint corresponds to a thermal breakpoint determined according to ASTM D3241.

13. The method of claim 1, wherein assigning weights for the plurality of compositional groups for the first kerosene fraction comprises assigning weights based on the determined thermal breakpoint and the determined one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity.

14. The method of claim 13, wherein assigning weights based on the determined thermal breakpoint and the determined one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity comprises:

identifying one or more kerosene fractions in the plurality of kerosene fractions that have at least one value for a thermal breakpoint, a sulfur content, a nitrogen content, an aromatics content, or an API gravity that differs from the corresponding value for the first kerosene fraction by less than a threshold value;

determining a weighted average of the one or more identified kerosene fractions, the determined weighted average having weighted average values for a thermal breakpoint and for the at least one of a sulfur content, a nitrogen content an aromatics content, and an API gravity to within a tolerance value; and

calculating weights for the plurality of compositional groups for the first kerosene fraction based on compositional group weights for the determined weighted average of the one or more identified kerosene fractions.

15. The method of claim 1, wherein assigning weights for the plurality of compositional groups for the first kerosene fraction comprises analyzing the first kerosene fraction to determine weights for the plurality of compositional groups.

16. The method of claim 1, wherein a kerosene fraction comprises a fraction with an initial boiling point of least about 284°

F. (140°

C.) and a final boiling point of less than about 572°

F. (300°

C.).

17. The method of claim 1, wherein a compositional group in the plurality of compositional groups is defined based on at least one of a number and type of heteroatoms in a compound, a Z class for a compound, and a molecular weight for a compound.

18. The method of claim 17, wherein each compositional group in the plurality of compositional groups is defined based on at least two of a number and type of heteroatoms in a compound, a Z class for a compound, and a molecular weight for a compound.

19. A method for constructing a model of the thermal breakpoint of a kerosene fraction, comprising:

measuring a thermal breakpoint for the plurality of kerosene fractions;

measuring one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for the plurality of kerosene fractions;

analyzing the plurality of kerosene fractions, using Fourier transform ion cyclotron resonance mass spectrometry, to determine weights for a plurality of compositional groups within each kerosene fraction; and

constructing a model for correlating a thermal breakpoint of a kerosene fraction with a) the one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for a kerosene fraction, and b) weights for a plurality of compositional groups in a kerosene fraction, the model being constructed based on the measured thermal breakpoints for the plurality of kerosene fractions, the measured values for the one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for the plurality of kerosene fractions, and the determined weights for the plurality of compositional groups for the plurality of kerosene fractions.

20. The method of claim 19, further comprising:

measuring a thermal breakpoint for a first kerosene fraction;

measuring the one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for the first kerosene fraction;

hydroprocessing the first kerosene fraction;

measuring a thermal breakpoint for the hydroprocessed first kerosene fraction;

measuring the one or more of a sulfur content, a nitrogen content, an aromatics content, and an API gravity for the hydroprocessed first kerosene fraction; and

updating the constructed model by incorporating the first kerosene fraction and the hydroprocessed first kerosene fraction into the plurality of kerosene fractions.