MULTILAYER CERAMIC CAPACITOR

• US 20150049413A1
• Filed: 10/30/2014
• Published: 02/19/2015
• Est. Priority Date: 03/19/2013
• Status: Active Grant

• Current Assignee: Murata Manufacturing Co Limited
• Original Assignee: Murata Manufacturing Co Limited
• Inventors: AWATA, Hiroki, UNO, Sui, WADA, Hiroyuki, SHIMADA, Kohei, TAKAGI, Kenji, KOGA, Tomomi, HIRATA, Tomotaka, NISHIMURA, Hitoshi
• Granted Patent: US 9,042,082 B2
• Time in Patent Office: Days
• US Class Current: 361/301.4
• CPC Class Codes: H01G 4/012 Form of non-self-supporting electrodes
• CPC Class Codes: H01G 4/12 Ceramic dielectrics H01G4/085 takes precedence
• CPC Class Codes: H01G 4/1209 characterised by the ceramic dielectric material H01G4/1272, H01G4/1281 take precedence
• CPC Class Codes: H01G 4/1227 based on alkaline earth titanates
• CPC Class Codes: H01G 4/1245 containing also titanates
• CPC Class Codes: H01G 4/224 Housing; Encapsulation
• CPC Class Codes: H01G 4/248 the terminals embracing or surrounding the capacitive element, e.g. caps H01G4/252 takes precedence
• CPC Class Codes: H01G 4/30 Stacked capacitors H01G4/33 takes precedence

Abstract

A multilayer ceramic capacitor includes a ceramic main body including an inner layer portion including third ceramic layers and a plurality of inner electrodes arranged at interfaces between the third ceramic layers, and first and second outer layer portions respectively including first and second ceramic layers, the first and second ceramic layers being arranged vertically so as to sandwich the inner layer portion. The third ceramic layers and the first and second outer layer portions contain a perovskite-type compound represented by ABO₃ where A contains one or more of Ba, Sr, and Ca, B contains one or more of Ti, Zr, and Hf, and O represents oxygen) as a main component. Where a rare-earth element concentration (C_R) in the third ceramic layers is compared to a rare-earth element concentration (C_r) in outermost layer portions including at least outermost surfaces of the first and second outer layer portions, C_R>C_r (inclusive of C_r=0).

Claims

1. A multilayer ceramic capacitor comprising:

a ceramic main body including;

a first outer layer portion including first ceramic layers;

a second outer layer portion including second ceramic layers;

an inner layer portion including third ceramic layers and inner electrodes arranged at a plurality of interfaces between at least some of the third ceramic layers; and

outer electrodes arranged on surfaces of the ceramic main body and electrically connected to the inner electrodes;

wherein

the first outer layer portion and the second outer layer portion are arranged vertically so as to sandwich the inner layer portion therebetween;

the third ceramic layers contain a perovskite-type compound represented by ABO₃, where A contains one or more of Ba, Sr, and Ca;

B contains one or more of Ti, Zr, and Hf; and

O represents oxygen, and a rare-earth element;

an outermost layer portion of at least one of the first and the second outer layer portions including at least a portion of a surface of the ceramic main body contains a perovskite-type compound represented by A′

B′

O₃, where A′

contains one or more of Ba, Sr, and Ca;

B′

contains one or more of Ti, Zr, and Hf; and

O represents oxygen, and optionally a rare-earth element that is the same or different as the rare-earth element of the third ceramic layers;

a mol concentration (C_R) of the rare-earth element in the third ceramic layers is greater than a mol concentration (C_r) of the rare-earth element in the outermost layer portion, C_R>

C_r, inclusive of C_r=0;

the mol concentration (C_R) is about 0.3 parts by mole or more with respect to 100 parts by mole of total amount of Ti, Zr, and Hf included in the third ceramic layers; and

the mol concentration (C_r) is less than about 0.3 parts by mole with respect to 100 parts by mole of total amount of Ti, Zr, and Hf included in the outermost layer portions.

2. The multilayer ceramic capacitor according to claim 1, wherein an entirety of the surface of the ceramic main body contains the perovskite-type compound represented by A′

B′

O₃.

3. A multilayer ceramic capacitor comprising:

a ceramic main body including;

a first outer layer portion including first ceramic layers;

a second outer layer portion including second ceramic layers;

an inner layer portion including third ceramic layers and inner electrodes arranged at a plurality of interfaces between at least some of the third ceramic layers; and

outer electrodes arranged on surfaces of the ceramic main body and electrically connected to the inner electrodes;

wherein

the first outer layer portion and the second outer layer portion are arranged vertically so as to sandwich the inner layer portion therebetween;

the third ceramic layers contain a perovskite-type compound represented by ABO₃, where A contains one or more of Ba, Sr, and Ca;

B contains one or more of Ti, Zr, and Hf; and

O represents oxygen, a rare-earth element, and Mn;

an outermost layer portion of at least one of the first and the second outer layer portions including a portion of a surface of the ceramic main body contains a perovskite-type compound represented by A′

B′

O₃, where A′

contains one or more of Ba, Sr, and Ca;

B′

contains one or more of Ti, Zr, and Hf; and

O represents oxygen, and optionally Mn and a rare-earth element that is the same or different as the rare-earth element of the third ceramic layers;

a mol concentration (C_R) of the rare-earth element in the third ceramic layers is greater than a mol concentration (C_r) of the rare-earth element in the outermost layer portion, C_R>

C_r, inclusive of C_r=0; and

a mol concentration (C_M) of Mn in the third ceramic layers is greater than a mol concentration (C_m) of Mn in the outermost layer portion, C_M>

C_m (inclusive of C_m=0).

4. The multilayer ceramic capacitor according to claim 3, wherein an entirety of the surface of the ceramic main body contains the perovskite-type compound represented by A′

B′

O₃.

5. A multilayer ceramic capacitor comprising:

a ceramic main body including;

a first outer layer portion including first ceramic layers;

a second outer layer portion including second ceramic layers;

an inner layer portion including third ceramic layers and inner electrodes arranged at a plurality of interfaces between at least some of the third ceramic layers; and

outer electrodes arranged on surfaces of the ceramic main body and electrically connected to the inner electrodes;

wherein

the first outer layer portion and the second outer layer portion are arranged vertically so as to sandwich the inner layer portion therebetween;

the third ceramic layers contain a perovskite-type compound represented by ABO₃, where A contains one or more of Ba, Sr, and Ca;

B contains one or more of Ti, Zr, and Hf; and

O represents oxygen, a rare-earth element, and Mn; and

only the second outer layer portion of the first and second outer layer portions includes each of features (a), (b), (c) and (d);

(a) an outermost layer portion of at least one of the first and the second outer layer portions including a portion of a surface of the ceramic main body contains a perovskite-type compound represented by A′

B′

O₃, where A′

contains one or more of Ba, Sr, and Ca, B′

contains one or more of Ti, Zr, and Hf, and O represents oxygen, and optionally Mn and a rare-earth element that is the same or different than the rare-earth element of the third ceramic layers;

(b) a mol concentration (C_R) of the rare-earth element in the third ceramic layers is greater than a mol concentration (C_r) of the rare-earth element in the outermost layer portion, C_R>

C_r, inclusive of C_r=0; and

(c) a mol concentration (C_M) of Mn in the third ceramic layers is greater than a mol concentration (C_m) of Mn in the outermost layer portion, C_M>

C_m (inclusive of C_m=0); and

(d) an intermediate ceramic layer is arranged between the outermost layer portion and the inner layer portion, and the intermediate ceramic layer has a different composition from the outermost layer portion.

6. The multilayer ceramic capacitor according to claim 5, wherein the first outer layer portion includes any one, two or three of features (a), (b), (c) and (d), and wherein feature (a) is an outermost layer portion of the first outer layer portion including a portion of a surface of the ceramic main body contains a perovskite-type compound represented by A′

B′

O₃, where A′

contains one or more of Ba, Sr, and Ca, B′

contains one or more of Ti, Zr, and Hf, and O represents oxygen, and optionally Mn and a rare-earth element that is the same or different than the rare-earth element of the third ceramic layers.

7. The multilayer ceramic capacitor according to claim 5, wherein an entirety of the surface of the ceramic main body contains the perovskite-type compound represented by A′

B′

O₃.

8. The multilayer ceramic capacitor according to claim 5, wherein the mol concentration (C_r) of the rare-earth element in the outermost layer portion is smaller than a mol concentration of the rare-earth element in the outermost layer portion of the first outer layer portion including the portion of the surface of the ceramic main body.