NMR Analysis of A Core Sample Employing An Open Permanent Magnet Removable from A Core Holder

• US 20150061670A1
• Filed: 05/15/2012
• Published: 03/05/2015
• Est. Priority Date: 05/15/2012
• Status: Active Grant

• Current Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Original Assignee: Schlumberger Technology Corporation (Schlumberger NV)
• Inventors: Mitchell, Jonathan, Fordham, Edmund J.
• Granted Patent: US 9,696,269 B2
• Time in Patent Office: Days
• US Class Current: 324/309
• CPC Class Codes: G01N 1/00 Sampling; Preparing specimens for investigation
• CPC Class Codes: G01N 24/081 Making measurements of geologic samples, e.g. measurements of moisture, pH, porosity, permeability, tortuosity or viscosity
• CPC Class Codes: G01R 33/305 specially adapted for high-pressure applications
• CPC Class Codes: G01R 33/3806 Open magnet assemblies for improved access to the sample, e.g. C-type or U-type magnets
• CPC Class Codes: G01R 33/383 using permanent magnets
• CPC Class Codes: G01V 3/32 operating with electron or nuclear magnetic resonance

Abstract

An apparatus and method for NMR analysis of a plurality of core samples includes a core holder (11) that holds a core sample under pressurized conditions. A radio frequency coil (51) disposed about the core holder (11) generates a pulsed-mode magnetic field component over a sample volume occupied by the core sample. A support structure is removably secured to the respective core holder. A permanent magnet (65A, 65B) has an open configuration such that it is removably disposed into a position within the support structure about the radio frequency coil and the core holder. The open configuration allows the same permanent magnet to be used for NMR analysis of a plurality of core samples without the need for depressurizing the respective core holder and disassembling the core holder and corresponding load frame for each core sample. It also allows multiple core samples to be prepared for NMR analysis while separated from the NMR measurement apparatus.

Claims

1. A method for acquiring nuclear magnetic resonance (NMR) measurements of a plurality of subterranean core samples, the method comprising:

holding a first core sample in a first core holder under pressurized conditions, the first core holder having a first radio frequency coil disposed about a portion of the first core holder, the first radio frequency coil for generating a pulsed-mode magnetic field component over a sample volume occupied by the first core sample;

removably securing a first support structure to the first core holder, the first support structure providing resistance to forces resulting from the pressurized conditions of the first core holder, and the first support structure allowing for access to interior space surrounding the portion of the first core holder and the first radio frequency coil disposed thereabout;

removably disposing a permanent magnet into a position within the first support structure about the first radio frequency coil and the portion of the first core holder without the need for depressurization of the first core holder and detachment of the first support structure from the first core holder, the permanent magnet for applying a static magnetic field component to the sample volume occupied by the first core sample for NMR measurements of the first core sample;

holding a second core sample in a second core holder under pressurized conditions, the second core holder having a second radio frequency coil disposed about a portion of the second core holder, the second radio frequency coil for generating a pulsed-mode magnetic field component over a sample volume occupied by the second core sample;

removably securing a second support structure to the second core holder, the second support structure providing resistance to forces resulting from the pressurized conditions of the second core holder, and the second support structure allowing for access to interior space surrounding the portion of the second core holder and the second radio frequency coil disposed thereabout;

removing the permanent magnet from the position within the first support structure about the first radio frequency coil and the portion of the first core holder without the need for depressurization of the first core holder and detachment of the first support structure from the first core holder; and

after removing the permanent magnet from the position within the first support structure, removably disposing the permanent magnet into a position within the second support structure about the second radio frequency coil and the portion of the second core holder without the need for depressurization of the second core holder and detachment of the second support structure from the second core holder, the permanent magnet for applying a static magnetic field component to the sample volume occupied by the second core sample for NMR measurements of the second core sample.

2. A method according to claim 1, further comprising:

removing the permanent magnet from the position within the second support structure about the second radio frequency coil and the portion of the second core holder without the need for depressurization of the second core holder and detachment of the second support structure from the second core holder; and

after removing the permanent magnet from the position within the second support structure, removably disposing the permanent magnet into a position within at least one additional support structure for NMR measurements of an additional core sample.

3. A method according to claim 1, wherein:

said permanent magnet has an open configuration, the open configuration allowing the permanent magnet to be removably disposed within the first support structure about the first radio frequency coil and the portion of the first core holder without the need for depressurization of the first core holder and detachment of the first support structure from the first core holder, and the open configuration allowing the permanent magnet to be removably disposed within the second support structure about the second radio frequency coil and the portion of the second core holder without the need for depressurization of the second core holder and detachment of the second support structure from the second core holder.

4. A method according to claim 3, wherein:

said permanent magnet includes a U-shaped or C-shaped body that supports two magnet poles, wherein the body defines the open configuration.

5. A method according to claim 4, wherein:

said permanent magnet includes a part that is removably secured to the U-shaped or C-shaped body to reconfigure the permanent magnet in a closed configuration.

6. A method according to claim 3, wherein:

said permanent magnet comprises two cylindrical Halbach-type arrays that are arranged in a concentric configuration during use, said two cylindrical Halbach-type arrays each having two semi-cylindrical portions that are coupled together via a hinge interface, wherein pivoting movement of the two semi-cylindrical portions about the hinge interface permits the two cylindrical Halbach-type arrays to be arranged in the open configuration.

7. A method according to claim 1, further comprising:

positioning at least one first gradient coil within the first support structure about the first radio frequency coil and the portion of the first core holder, said at least one gradient coil for applying a time varying magnetic field gradient component over the sample volume for NMR measurements of the first sample; and

positioning at least one second gradient coil within the second support structure about the second radio frequency coil and the portion of the second core holder, said at least one gradient coil for applying a time varying magnetic field gradient component over the sample volume for NMR measurements of the second sample.

8. A method according to claim 3, wherein:

at least one gradient coil is removably disposed within both the first and second support structures without the need for depressurization of the respective core holder and detachment of the respective support structure from the corresponding core holder.

9. A method according to claim 1, wherein:

said first and second support structures each include at least two beams that extend transverse to the central axis of the respective core holder and at least two rods that extend between the at least two beams in a direction parallel to the central axis of the respective core holder.

10. A method according to claim 1, wherein:

said first and second core holders allow for ageing of oil within the first and second core samples under reservoir conditions for NMR measurements of the first and second core samples under reservoir conditions.

11. An apparatus for acquiring nuclear magnetic resonance (NMR) measurements of a subterranean core sample, the apparatus comprising:

a core holder for holding the core sample under pressurized conditions;

a radio frequency coil disposed about a portion of the core holder, said radio frequency coil for generating a pulsed-mode magnetic field component over a sample volume occupied by the core sample;

a support structure that is removably secured to the core holder, the support structure providing resistance to forces resulting from the pressurized conditions of the core holder, and the support structure allowing for access to interior space that surrounds the portion of the core holder and the radio frequency coil disposed thereabout; and

a permanent magnet for applying a static magnetic field component to the sample volume, the permanent magnet having an open configuration wherein the permanent magnet is removably disposed within the support structure about the radio frequency coil and the portion of the core holder without the need for depressurization of the core holder and detachment of the support structure from the core holder.

12. An apparatus according to claim 11, further comprising:

a connector that is coupled to the radio frequency coil, the connector providing a detachable electrical connection between the radio frequency coil and an NMR measurement apparatus.

13. An apparatus according to claim 11, further comprising:

at least one gradient coil operably disposed within the support structure about the radio frequency coil and the portion of the core holder, the at least one gradient coil for applying a time varying magnetic field gradient component over the sample volume.

14. An apparatus according to claim 13, wherein:

the at least one gradient coil is removably disposed within the support structure about the radio frequency coil and the portion of the core holder without the need for depressurization of the core holder and detachment of the support structure from the core holder.

15. An apparatus according to claim 13, wherein:

the at least one gradient coil is supported on the permanent magnet.

16. An apparatus according to claim 13, further comprising:

a connector that is coupled to the at least one gradient coil, the connector providing a detachable electrical connection between the at least one gradient coil and an NMR measurement apparatus.

17. An apparatus according to claim 11, wherein:

the permanent magnet includes a U-shaped or C-shaped body that supports two magnet poles, wherein the body defines an opening that permits the permanent magnet to be removably disposed in a position within the support structure about the radio frequency coil and the portion of the core holder without the need for depressurization of the core holder and detachment of the support structure from the core holder.

18. An apparatus according to claim 17, wherein:

the permanent magnet includes a part that is removably secured to the C-shaped or U-shaped body to close the opening.

19. An apparatus according to claim 11, wherein:

the permanent magnet comprises two cylindrical Halbach-type arrays that are arranged in a concentric configuration during use, the two cylindrical Halbach-type arrays each having two semi-cylindrical portions that are coupled together via a hinge interface, wherein pivoting movement of the two semi-cylindrical portions about the hinge interface permits the two cylindrical Halbach-type arrays to be to removably disposed in a position within the support structure about the radio frequency coil and the portion of the core holder without the need for depressurization of the core holder and detachment of the support structure from the core holder.

20. An apparatus according to claim 11, wherein:

the support structure comprises at least two beams that extend transverse to the central axis of the core holder and at least two rods that extend between the at least two beams in a direction parallel to the central axis of the core holder, wherein the at least two rods define openings that allow for access to the interior space that surrounds the portion of the core holder and the radio frequency coil disposed thereabout.

21. An apparatus according to claim 11, wherein:

the core holder allows for ageing of oil within the core sample under reservoir conditions for NMR measurements of the core sample under reservoir conditions.